Reactivity ratios for new copolymerizations relevant to thermosetting resins
Free radical copolymerizations of four new systems, namely (1) methyl methacrylate (MMA) with β‐acryloxypropionic acid (AOPA); (2) MMA with p‐styrene sulphonyl chloride (SSC); (3) 2‐[(phenylamino) carbonyl] oxyethyl methacrylate (PCOMA) with 2‐phenoxyethyl methacrylate (PEMA); and (4) PCOMA with 1‐m...
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| Veröffentlicht in: | Polymer international 1993, Vol.31 (4), p.375-383 |
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| creator | Mao, Runsheng Huglin, Malcolm B. Davis, Thomas P. Overend, Andrew S. |
| description | Free radical copolymerizations of four new systems, namely (1) methyl methacrylate (MMA) with β‐acryloxypropionic acid (AOPA); (2) MMA with p‐styrene sulphonyl chloride (SSC); (3) 2‐[(phenylamino) carbonyl] oxyethyl methacrylate (PCOMA) with 2‐phenoxyethyl methacrylate (PEMA); and (4) PCOMA with 1‐methyl‐2‐phenoxyethyl methacrylate (MPEMA), have been carried out at 60°C for systems 1 and 2 and at 70°C for systems 3 and 4. The copolymer compositions were analysed by acid‐base titration for system 1 and by FTIR for systems 2–4. The monomer reactivity ratios as well as the 95% individual confidence intervals and 95% joint confidence intervals were calculated from the Kelen‐Tüdős method, the Extended Kelen‐Tüdőos method, and from a new iterative linear method by Mao and Huglin. The results show that all these copolymerizations are strictly linear systems describable by the Mayo‐Lewis equation based on the terminal model and that accurate reactivity ratio data can be obtained. The Q‐e values of the monomers AOPA and SSC have been estimated. Some physical properties of AOPA, PEMA and MPEMA are also presented for the first time. |
| doi_str_mv | 10.1002/pi.4990310411 |
| format | Article |
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The copolymer compositions were analysed by acid‐base titration for system 1 and by FTIR for systems 2–4. The monomer reactivity ratios as well as the 95% individual confidence intervals and 95% joint confidence intervals were calculated from the Kelen‐Tüdős method, the Extended Kelen‐Tüdőos method, and from a new iterative linear method by Mao and Huglin. The results show that all these copolymerizations are strictly linear systems describable by the Mayo‐Lewis equation based on the terminal model and that accurate reactivity ratio data can be obtained. The Q‐e values of the monomers AOPA and SSC have been estimated. Some physical properties of AOPA, PEMA and MPEMA are also presented for the first time.</description><identifier>ISSN: 0959-8103</identifier><identifier>EISSN: 1097-0126</identifier><identifier>DOI: 10.1002/pi.4990310411</identifier><language>eng</language><publisher>London: John Wiley & Sons, Ltd</publisher><subject>1-methyl-2-phenoxyethyl methacrylate ; 2-[(phenylamino) carbonyl] oxyethyl methacrylate ; 2-phenoxyethyl methacrylate ; Applied sciences ; Copolymerization ; Exact sciences and technology ; methyl methacrylate ; Organic polymers ; p-styrenesulphonyl chloride ; Physicochemistry of polymers ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; reactivity ratios ; β-acryloxypropionic acid</subject><ispartof>Polymer international, 1993, Vol.31 (4), p.375-383</ispartof><rights>Copyright © 1993 Society of Chemical Industry</rights><rights>1993 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4431-76769ad67191a2e731adced0a5973f1fb34cd7410d987fb4b67abac6ca31a81c3</citedby><cites>FETCH-LOGICAL-c4431-76769ad67191a2e731adced0a5973f1fb34cd7410d987fb4b67abac6ca31a81c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpi.4990310411$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpi.4990310411$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,4022,27922,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4640234$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Mao, Runsheng</creatorcontrib><creatorcontrib>Huglin, Malcolm B.</creatorcontrib><creatorcontrib>Davis, Thomas P.</creatorcontrib><creatorcontrib>Overend, Andrew S.</creatorcontrib><title>Reactivity ratios for new copolymerizations relevant to thermosetting resins</title><title>Polymer international</title><addtitle>Polym. Int</addtitle><description>Free radical copolymerizations of four new systems, namely (1) methyl methacrylate (MMA) with β‐acryloxypropionic acid (AOPA); (2) MMA with p‐styrene sulphonyl chloride (SSC); (3) 2‐[(phenylamino) carbonyl] oxyethyl methacrylate (PCOMA) with 2‐phenoxyethyl methacrylate (PEMA); and (4) PCOMA with 1‐methyl‐2‐phenoxyethyl methacrylate (MPEMA), have been carried out at 60°C for systems 1 and 2 and at 70°C for systems 3 and 4. The copolymer compositions were analysed by acid‐base titration for system 1 and by FTIR for systems 2–4. The monomer reactivity ratios as well as the 95% individual confidence intervals and 95% joint confidence intervals were calculated from the Kelen‐Tüdős method, the Extended Kelen‐Tüdőos method, and from a new iterative linear method by Mao and Huglin. The results show that all these copolymerizations are strictly linear systems describable by the Mayo‐Lewis equation based on the terminal model and that accurate reactivity ratio data can be obtained. The Q‐e values of the monomers AOPA and SSC have been estimated. Some physical properties of AOPA, PEMA and MPEMA are also presented for the first time.</description><subject>1-methyl-2-phenoxyethyl methacrylate</subject><subject>2-[(phenylamino) carbonyl] oxyethyl methacrylate</subject><subject>2-phenoxyethyl methacrylate</subject><subject>Applied sciences</subject><subject>Copolymerization</subject><subject>Exact sciences and technology</subject><subject>methyl methacrylate</subject><subject>Organic polymers</subject><subject>p-styrenesulphonyl chloride</subject><subject>Physicochemistry of polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>reactivity ratios</subject><subject>β-acryloxypropionic acid</subject><issn>0959-8103</issn><issn>1097-0126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNqNkUFvEzEQhS1EJULhyH0PqLdtZ9Zee32sWgiRokILVY_WxOsFw2a92G7a8OubKFFRL9DTHN733hvpMfYO4RgBqpPRHwutgSMIxBdsgqBVCVjJl2wCutZlg8Bfsdcp_QSARms9YfMrRzb7lc_rIlL2IRVdiMXg7gobxtCvly76P1thSEV0vVvRkIscivzDxWVILmc_fN8oyQ_pDTvoqE_u7f4esuuPH76dfSrnn6ezs9N5aYXgWCqppKZWKtRIlVMcqbWuBaq14h12Cy5sqwRCqxvVLcRCKlqQlZY2ZIOWH7KjXe4Yw-9bl7JZ-mRd39Pgwm0ylcSmqnj9PBC1-C-IslairmEDljvQxpBSdJ0Zo19SXBsEs13BjN78XWHDv98HU7LUd5EG69OjSUgBFd_2qx1253u3_nem-TJ7UrB_yKfs7h-dFH8Zqbiqzc3F1FRaiunXy3Mz5w8mx6cR</recordid><startdate>1993</startdate><enddate>1993</enddate><creator>Mao, Runsheng</creator><creator>Huglin, Malcolm B.</creator><creator>Davis, Thomas P.</creator><creator>Overend, Andrew S.</creator><general>John Wiley & Sons, Ltd</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>7SR</scope><scope>JG9</scope></search><sort><creationdate>1993</creationdate><title>Reactivity ratios for new copolymerizations relevant to thermosetting resins</title><author>Mao, Runsheng ; Huglin, Malcolm B. ; Davis, Thomas P. ; Overend, Andrew S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4431-76769ad67191a2e731adced0a5973f1fb34cd7410d987fb4b67abac6ca31a81c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>1-methyl-2-phenoxyethyl methacrylate</topic><topic>2-[(phenylamino) carbonyl] oxyethyl methacrylate</topic><topic>2-phenoxyethyl methacrylate</topic><topic>Applied sciences</topic><topic>Copolymerization</topic><topic>Exact sciences and technology</topic><topic>methyl methacrylate</topic><topic>Organic polymers</topic><topic>p-styrenesulphonyl chloride</topic><topic>Physicochemistry of polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>reactivity ratios</topic><topic>β-acryloxypropionic acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mao, Runsheng</creatorcontrib><creatorcontrib>Huglin, Malcolm B.</creatorcontrib><creatorcontrib>Davis, Thomas P.</creatorcontrib><creatorcontrib>Overend, Andrew S.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Research Database</collection><jtitle>Polymer international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mao, Runsheng</au><au>Huglin, Malcolm B.</au><au>Davis, Thomas P.</au><au>Overend, Andrew S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reactivity ratios for new copolymerizations relevant to thermosetting resins</atitle><jtitle>Polymer international</jtitle><addtitle>Polym. Int</addtitle><date>1993</date><risdate>1993</risdate><volume>31</volume><issue>4</issue><spage>375</spage><epage>383</epage><pages>375-383</pages><issn>0959-8103</issn><eissn>1097-0126</eissn><abstract>Free radical copolymerizations of four new systems, namely (1) methyl methacrylate (MMA) with β‐acryloxypropionic acid (AOPA); (2) MMA with p‐styrene sulphonyl chloride (SSC); (3) 2‐[(phenylamino) carbonyl] oxyethyl methacrylate (PCOMA) with 2‐phenoxyethyl methacrylate (PEMA); and (4) PCOMA with 1‐methyl‐2‐phenoxyethyl methacrylate (MPEMA), have been carried out at 60°C for systems 1 and 2 and at 70°C for systems 3 and 4. The copolymer compositions were analysed by acid‐base titration for system 1 and by FTIR for systems 2–4. The monomer reactivity ratios as well as the 95% individual confidence intervals and 95% joint confidence intervals were calculated from the Kelen‐Tüdős method, the Extended Kelen‐Tüdőos method, and from a new iterative linear method by Mao and Huglin. The results show that all these copolymerizations are strictly linear systems describable by the Mayo‐Lewis equation based on the terminal model and that accurate reactivity ratio data can be obtained. The Q‐e values of the monomers AOPA and SSC have been estimated. Some physical properties of AOPA, PEMA and MPEMA are also presented for the first time.</abstract><cop>London</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/pi.4990310411</doi><tpages>9</tpages></addata></record> |
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| ispartof | Polymer international, 1993, Vol.31 (4), p.375-383 |
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| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | 1-methyl-2-phenoxyethyl methacrylate 2-[(phenylamino) carbonyl] oxyethyl methacrylate 2-phenoxyethyl methacrylate Applied sciences Copolymerization Exact sciences and technology methyl methacrylate Organic polymers p-styrenesulphonyl chloride Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts reactivity ratios β-acryloxypropionic acid |
| title | Reactivity ratios for new copolymerizations relevant to thermosetting resins |
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