Dangling Carboxylic Group That Participates in O–O Bond Formation Reaction to Promote Water Oxidation Catalyzed by a Ruthenium Complex: Experimental Evidence of an Oxide Relay Pathway

Two mononuclear ruthenium­(II) complexes of the types [Ru­(trpy)­(HL1)­(OH2)]2+ (1 Aq ) and [Ru­(trpy)­(L2-κ-N2O)] (2) [where trpy = 2,2′:6′,2″-terpyridine, HL1 = 2-(2-pyridyl)­benzimidazole, H2L2 = 2-(pyridin-2-yl)-1H-benzo­[d]­imidazole-4-carboxylic acid] have been synthesized and thoroughly chara...

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Veröffentlicht in:	Inorganic chemistry 2022-01, Vol.61 (3), p.1426-1437
Hauptverfasser:	Kundu, Animesh, Barman, Suman K, Mandal, Sukanta
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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