Medium and Large N‑Heterocycle Formation via Allene Hydroamination with a Bimetallic Rh(II) Catalyst

We report the synthesis of a 2-phosphinoimidazole-derived bimetallic Rh(II) complex that enables intramolecular allene hydroamination to form 7- to 10-member rings in high yield. Monometallic Rh complexes, in contrast, fail to achieve any product formation. We demonstrate a broad substrate scope for...

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Veröffentlicht in:	Journal of the American Chemical Society 2022-01, Vol.144 (1), p.63-68
Hauptverfasser:	Forson, Kelton G, Bohman, Benjamin O, Wayment, Coriantumr Z, Owens, Rachel N, McKnight, Caitlyn E, Davis, Rhen C, Stillwell, Lillian R, Smith, Stacey J, Michaelis, David J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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