Phase separation in poly(methyl methacrylate)/polycarbonate blends
This paper deals with the compatibility of a chlorine-containing polycarbonate with poly(methyl methacrylate) (PMMA). The polymer-polymer interaction parameter, χ, has been determined from the experimental phase diagram by means of the Flory-Huggins theory. The interfacial tension, interfacial thick...
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| Veröffentlicht in: | Polymer (Guilford) 1993, Vol.34 (7), p.1528-1532 |
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| container_end_page | 1532 |
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| container_title | Polymer (Guilford) |
| container_volume | 34 |
| creator | Sakellariou, P. Eastmond, G.C. |
| description | This paper deals with the compatibility of a chlorine-containing polycarbonate with poly(methyl methacrylate) (PMMA). The polymer-polymer interaction parameter, χ, has been determined from the experimental phase diagram by means of the Flory-Huggins theory. The interfacial tension, interfacial thickness and interfacial density profile have also been calculated from the experimental value of χ by means of Helfand's mean-field treatment. The calculated interfacial thickness has been compared to experimental data from optical, transmission and scanning electron microscopy. |
| doi_str_mv | 10.1016/0032-3861(93)90873-9 |
| format | Article |
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The polymer-polymer interaction parameter, χ, has been determined from the experimental phase diagram by means of the Flory-Huggins theory. The interfacial tension, interfacial thickness and interfacial density profile have also been calculated from the experimental value of χ by means of Helfand's mean-field treatment. The calculated interfacial thickness has been compared to experimental data from optical, transmission and scanning electron microscopy.</description><subject>Applied sciences</subject><subject>blends</subject><subject>Exact sciences and technology</subject><subject>interaction parameter</subject><subject>interfaces</subject><subject>Organic polymers</subject><subject>phase separation</subject><subject>Physicochemistry of polymers</subject><subject>PMMA</subject><subject>polycarbonate</subject><subject>Properties and characterization</subject><subject>Thermal and thermodynamic properties</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNp9kDtPwzAUhS0EEqXwDxgyIESHUD9iO16QoOIlVYIBZst1rlUjNwl2ipR_T0KrjkzHR_587vVB6JLgW4KJmGPMaM5KQW4UmylcSparIzQh44FSRY7R5ICcorOUvjDGlNNigh7e1yZBlqA10XS-qTNfZ20T-psNdOs-ZKMYG_tgOpjNxxtr4qqpB5utAtRVOkcnzoQEF3udos-nx4_FS758e35d3C9zy4TocilBcuEGUzJOeeEqKbGxyhVSYF7SYUGwDPMVZdxBBQrAlcZSqRQvB8um6HqX28bmewup0xufLIRgami2SVNBOCVFMYDFDrSxSSmC0230GxN7TbAeC9NjG3psQyum_wrTY_7VPt8ka4KLprY-Hd4WQnJZsgG722Ew_PXHQ9TJeqgtVD6C7XTV-P_n_AJOyn6n</recordid><startdate>1993</startdate><enddate>1993</enddate><creator>Sakellariou, P.</creator><creator>Eastmond, G.C.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>1993</creationdate><title>Phase separation in poly(methyl methacrylate)/polycarbonate blends</title><author>Sakellariou, P. ; Eastmond, G.C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c366t-77e756fc36835254fd770ac9f4760582032ec305b235fede9eef8ac279958de93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Applied sciences</topic><topic>blends</topic><topic>Exact sciences and technology</topic><topic>interaction parameter</topic><topic>interfaces</topic><topic>Organic polymers</topic><topic>phase separation</topic><topic>Physicochemistry of polymers</topic><topic>PMMA</topic><topic>polycarbonate</topic><topic>Properties and characterization</topic><topic>Thermal and thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sakellariou, P.</creatorcontrib><creatorcontrib>Eastmond, G.C.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sakellariou, P.</au><au>Eastmond, G.C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Phase separation in poly(methyl methacrylate)/polycarbonate blends</atitle><jtitle>Polymer (Guilford)</jtitle><date>1993</date><risdate>1993</risdate><volume>34</volume><issue>7</issue><spage>1528</spage><epage>1532</epage><pages>1528-1532</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>This paper deals with the compatibility of a chlorine-containing polycarbonate with poly(methyl methacrylate) (PMMA). 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| fulltext | fulltext |
| identifier | ISSN: 0032-3861 |
| ispartof | Polymer (Guilford), 1993, Vol.34 (7), p.1528-1532 |
| issn | 0032-3861 1873-2291 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_26152144 |
| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences blends Exact sciences and technology interaction parameter interfaces Organic polymers phase separation Physicochemistry of polymers PMMA polycarbonate Properties and characterization Thermal and thermodynamic properties |
| title | Phase separation in poly(methyl methacrylate)/polycarbonate blends |
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