Crystal structure of 1,1'-(pyridine-2,6-di-yl)bis-N-(pyridin-2-ylmeth-yl)methanaminium dichloride dihydrate

In the title compound, C19H23N5 2+·2Cl-·2H2O, the two pyridine side arms are not coplanar, with the terminal pyridine rings subtending a dihedral angle of 26.45 (6)°. In the crystal, hydrogen bonds, inter-molecular C-H⋯Cl contacts and a weak C-H⋯O inter-action connect the mol-ecule with neighbouring...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2021-12, Vol.77 (Pt 12), p.1296
Hauptverfasser: Merabet, Layachi, Tassé, Marine, Mallet-Ladeira, Sonia, Kaboub, Lakhemici, Malfant, Isabelle
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, C19H23N5 2+·2Cl-·2H2O, the two pyridine side arms are not coplanar, with the terminal pyridine rings subtending a dihedral angle of 26.45 (6)°. In the crystal, hydrogen bonds, inter-molecular C-H⋯Cl contacts and a weak C-H⋯O inter-action connect the mol-ecule with neighbouring chloride counter-anions and lattice water mol-ecules. The crystal packing also features by π-π inter-actions with centroid-centroid distances of 3.4864 (12) and 3.5129 (13) Å.In the title compound, C19H23N5 2+·2Cl-·2H2O, the two pyridine side arms are not coplanar, with the terminal pyridine rings subtending a dihedral angle of 26.45 (6)°. In the crystal, hydrogen bonds, inter-molecular C-H⋯Cl contacts and a weak C-H⋯O inter-action connect the mol-ecule with neighbouring chloride counter-anions and lattice water mol-ecules. The crystal packing also features by π-π inter-actions with centroid-centroid distances of 3.4864 (12) and 3.5129 (13) Å.
ISSN:2056-9890
2056-9890
DOI:10.1107/S205698902101183X