A Theoretical Approach to the Fluorophilicity of Ions via the Gibbs Energy of Ion Transfer at the Fluorous Solvent/Water Interface

The non-Bornian solvation model has been applied to a theoretical consideration of the Gibbs free energy for the transfer of fluorinated anions, non-fluorinated cations, and non-fluorinated anions at the 2H,3H-decafluoropentane (DFP)/water (W) and 1,2-dichloroethane (DCE)/W interfaces. According to...

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Veröffentlicht in:	Analytical Sciences 2021/12/10, Vol.37(12), pp.1783-1787
Hauptverfasser:	OSAKAI, Toshiyuki, KATO, Takeshi, EDA, Kazuo, UEMATSU, Kohei, KATANO, Hajime
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical Chemistry Anions Cations Chemistry Dichloroethane energy decomposition Ethylene Dichlorides Fluorination fluorous solvent/water interface Free energy Gibbs free energy Gibbs free energy of ion transfer Interfaces Ions non-Bornian solvation model Solvation Solvents Water
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