Heterobimetallic Pd/Mn and Pd/Co complexes as efficient and stereoselective catalysts for sequential Cu-free Sonogashira coupling-alkyne semi-hydrogenation reactions

A series of heterobimetallic Pd /M complexes (M = Mn, Co) were synthesised and tested as precatalysts for sequential Sonogashira coupling-alkyne semi-hydrogenation reactions to form -aryl alkenes. The carbometalated heterobimetallic Pd /Co complex CoPdL3' demonstrated an apparent cooperative ef...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2022-01, Vol.51 (4), p.1344-1356
Hauptverfasser:	Clauss, Reike, Baweja, Saral, Gelman, Dmitri, Hey-Hawkins, Evamarie
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Alkynes Ammonia Aromatic compounds Bromides Catalysts Chemical synthesis Cobalt Copper Coupling Hydrogenation Palladium Stereoselectivity Substrates
Online-Zugang:	Volltext
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