A Hydrogen‐Bonded Ravel Assembled by Anion Coordination
Anion‐coordination‐driven assembly (ACDA) is showing increasing power in the construction of anionic supramolecular architectures. Herein, by expanding the anion centers from oxoanion (phosphate or sulfate) to organic tris‐carboxylates, an Archimedean solid (truncated tetrahedron) and a highly entan...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2022-02, Vol.61 (6), p.e202115042-n/a |
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| creator | Zhao, Xiaotong Wang, Heng Li, Boyang Zhang, Wenyao Li, Xiaopeng Zhao, Wei Janiak, Christoph Heard, Andrew W. Yang, Xiao‐Juan Wu, Biao |
| description | Anion‐coordination‐driven assembly (ACDA) is showing increasing power in the construction of anionic supramolecular architectures. Herein, by expanding the anion centers from oxoanion (phosphate or sulfate) to organic tris‐carboxylates, an Archimedean solid (truncated tetrahedron) and a highly entangled, double‐walled tetrahedron featuring a ravel topology have been assembled with tris‐bis(urea) ligands. The results demonstrate the promising ability of tris‐carboxylates as new anion coordination centers in constructing novel topologies with increasing complexity and diversity compared to phosphate or sulfate ions on account of the modifiable size and easy functionalization character of these organic anions.
Anion‐coordination‐driven assembly (ACDA) between organic tris‐carboxylates and tris‐bis(urea) ligands afforded an Archimedean solid (truncated tetrahedron) and a double‐walled tetrahedron featuring a ravel topology. The results demonstrate the promising ability of tris‐carboxylates as new anion coordination centers in constructing novel topologies on account of the modifiable size and function of these organic anions. |
| doi_str_mv | 10.1002/anie.202115042 |
| format | Article |
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Anion‐coordination‐driven assembly (ACDA) between organic tris‐carboxylates and tris‐bis(urea) ligands afforded an Archimedean solid (truncated tetrahedron) and a double‐walled tetrahedron featuring a ravel topology. The results demonstrate the promising ability of tris‐carboxylates as new anion coordination centers in constructing novel topologies on account of the modifiable size and function of these organic anions.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202115042</identifier><identifier>PMID: 34850515</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>anion-coordination-driven assembly ; Anions ; Carboxylates ; Coordination ; ravel architecture ; Sulfates ; supramolecular chemistry ; Tetrahedra ; Topology ; Urea ; urea ligands</subject><ispartof>Angewandte Chemie International Edition, 2022-02, Vol.61 (6), p.e202115042-n/a</ispartof><rights>2021 Wiley‐VCH GmbH</rights><rights>2021 Wiley-VCH GmbH.</rights><rights>2022 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4392-769b8734ff942cdad8948053b115416ff67452cc3ce662de1eb08868c4d1c7053</citedby><cites>FETCH-LOGICAL-c4392-769b8734ff942cdad8948053b115416ff67452cc3ce662de1eb08868c4d1c7053</cites><orcidid>0000-0002-0724-4150</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202115042$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202115042$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/34850515$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhao, Xiaotong</creatorcontrib><creatorcontrib>Wang, Heng</creatorcontrib><creatorcontrib>Li, Boyang</creatorcontrib><creatorcontrib>Zhang, Wenyao</creatorcontrib><creatorcontrib>Li, Xiaopeng</creatorcontrib><creatorcontrib>Zhao, Wei</creatorcontrib><creatorcontrib>Janiak, Christoph</creatorcontrib><creatorcontrib>Heard, Andrew W.</creatorcontrib><creatorcontrib>Yang, Xiao‐Juan</creatorcontrib><creatorcontrib>Wu, Biao</creatorcontrib><title>A Hydrogen‐Bonded Ravel Assembled by Anion Coordination</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>Anion‐coordination‐driven assembly (ACDA) is showing increasing power in the construction of anionic supramolecular architectures. Herein, by expanding the anion centers from oxoanion (phosphate or sulfate) to organic tris‐carboxylates, an Archimedean solid (truncated tetrahedron) and a highly entangled, double‐walled tetrahedron featuring a ravel topology have been assembled with tris‐bis(urea) ligands. The results demonstrate the promising ability of tris‐carboxylates as new anion coordination centers in constructing novel topologies with increasing complexity and diversity compared to phosphate or sulfate ions on account of the modifiable size and easy functionalization character of these organic anions.
Anion‐coordination‐driven assembly (ACDA) between organic tris‐carboxylates and tris‐bis(urea) ligands afforded an Archimedean solid (truncated tetrahedron) and a double‐walled tetrahedron featuring a ravel topology. The results demonstrate the promising ability of tris‐carboxylates as new anion coordination centers in constructing novel topologies on account of the modifiable size and function of these organic anions.</description><subject>anion-coordination-driven assembly</subject><subject>Anions</subject><subject>Carboxylates</subject><subject>Coordination</subject><subject>ravel architecture</subject><subject>Sulfates</subject><subject>supramolecular chemistry</subject><subject>Tetrahedra</subject><subject>Topology</subject><subject>Urea</subject><subject>urea ligands</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqF0E9LwzAYBvAgipvTq0cpePHSmf9Nj3VMNxgKoufSJql0tMlMVqU3P4Kf0U9ixuYEL56SF37vw8sDwDmCYwQhvi5MrccYYoQYpPgADBHDKCZJQg7DnxISJ4KhATjxfhm8EJAfgwGhgkGG2BCkWTTrlbMv2nx9fN5Yo7SKHos33USZ97otmzCXfZSZ2ppoYq1TtSnWYTgFR1XReH22e0fg-Xb6NJnFi4e7-SRbxJKSFMcJT0uREFpVKcVSFUqkVEBGynAxRbyqeEIZlpJIzTlWGukSCsGFpArJJMARuNrmrpx97bRf523tpW6awmjb-RxzyDBBFJJAL__Qpe2cCdcFhTHFaSJ4UOOtks5673SVr1zdFq7PEcw3peabUvN9qWHhYhfbla1We_7TYgDpFrzXje7_icuz-_n0N_wbyKyBHA</recordid><startdate>20220201</startdate><enddate>20220201</enddate><creator>Zhao, Xiaotong</creator><creator>Wang, Heng</creator><creator>Li, Boyang</creator><creator>Zhang, Wenyao</creator><creator>Li, Xiaopeng</creator><creator>Zhao, Wei</creator><creator>Janiak, Christoph</creator><creator>Heard, Andrew W.</creator><creator>Yang, Xiao‐Juan</creator><creator>Wu, Biao</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-0724-4150</orcidid></search><sort><creationdate>20220201</creationdate><title>A Hydrogen‐Bonded Ravel Assembled by Anion Coordination</title><author>Zhao, Xiaotong ; Wang, Heng ; Li, Boyang ; Zhang, Wenyao ; Li, Xiaopeng ; Zhao, Wei ; Janiak, Christoph ; Heard, Andrew W. ; Yang, Xiao‐Juan ; Wu, Biao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4392-769b8734ff942cdad8948053b115416ff67452cc3ce662de1eb08868c4d1c7053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>anion-coordination-driven assembly</topic><topic>Anions</topic><topic>Carboxylates</topic><topic>Coordination</topic><topic>ravel architecture</topic><topic>Sulfates</topic><topic>supramolecular chemistry</topic><topic>Tetrahedra</topic><topic>Topology</topic><topic>Urea</topic><topic>urea ligands</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Xiaotong</creatorcontrib><creatorcontrib>Wang, Heng</creatorcontrib><creatorcontrib>Li, Boyang</creatorcontrib><creatorcontrib>Zhang, Wenyao</creatorcontrib><creatorcontrib>Li, Xiaopeng</creatorcontrib><creatorcontrib>Zhao, Wei</creatorcontrib><creatorcontrib>Janiak, Christoph</creatorcontrib><creatorcontrib>Heard, Andrew W.</creatorcontrib><creatorcontrib>Yang, Xiao‐Juan</creatorcontrib><creatorcontrib>Wu, Biao</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Xiaotong</au><au>Wang, Heng</au><au>Li, Boyang</au><au>Zhang, Wenyao</au><au>Li, Xiaopeng</au><au>Zhao, Wei</au><au>Janiak, Christoph</au><au>Heard, Andrew W.</au><au>Yang, Xiao‐Juan</au><au>Wu, Biao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Hydrogen‐Bonded Ravel Assembled by Anion Coordination</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2022-02-01</date><risdate>2022</risdate><volume>61</volume><issue>6</issue><spage>e202115042</spage><epage>n/a</epage><pages>e202115042-n/a</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Anion‐coordination‐driven assembly (ACDA) is showing increasing power in the construction of anionic supramolecular architectures. Herein, by expanding the anion centers from oxoanion (phosphate or sulfate) to organic tris‐carboxylates, an Archimedean solid (truncated tetrahedron) and a highly entangled, double‐walled tetrahedron featuring a ravel topology have been assembled with tris‐bis(urea) ligands. The results demonstrate the promising ability of tris‐carboxylates as new anion coordination centers in constructing novel topologies with increasing complexity and diversity compared to phosphate or sulfate ions on account of the modifiable size and easy functionalization character of these organic anions.
Anion‐coordination‐driven assembly (ACDA) between organic tris‐carboxylates and tris‐bis(urea) ligands afforded an Archimedean solid (truncated tetrahedron) and a double‐walled tetrahedron featuring a ravel topology. The results demonstrate the promising ability of tris‐carboxylates as new anion coordination centers in constructing novel topologies on account of the modifiable size and function of these organic anions.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>34850515</pmid><doi>10.1002/anie.202115042</doi><tpages>7</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-0724-4150</orcidid></addata></record> |
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| subjects | anion-coordination-driven assembly Anions Carboxylates Coordination ravel architecture Sulfates supramolecular chemistry Tetrahedra Topology Urea urea ligands |
| title | A Hydrogen‐Bonded Ravel Assembled by Anion Coordination |
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