Molecular Transition Metal Oxide Electrocatalysts for the Reversible Carbon Dioxide–Carbon Monoxide Transformation

Carbon monoxide dehydrogenase (CODH) enzymes are active for the reversible CO oxidation–CO2 reduction reaction and are of interest in the context of CO2 abatement and carbon‐neutral solar fuels. Bioinspired by the active‐site composition of the CODHs, polyoxometalates triply substituted with first‐r...

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Veröffentlicht in:	Angewandte Chemie International Edition 2022-01, Vol.61 (5), p.e202112915-n/a
Hauptverfasser:	Azaiza‐Dabbah, Dima, Vogt, Charlotte, Wang, Fei, Masip‐Sánchez, Albert, Graaf, Coen, Poblet, Josep M., Haviv, Eynat, Neumann, Ronny
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Carbon monoxide Carbon monoxide dehydrogenase Chemical reduction CO oxidation CO2 reduction d-block metals electrocatalysis Electrocatalysts Electrolysis Iron compounds Nickel compounds Oxidation Polyanions Polyelectrolytes polyoxometalates Polyoxometallates Reduction (electrolytic) Selectivity Transition metal oxides Transition metals
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