The influence of γ-radiation on polyamide 1010 aggregate structures

The influence of γ-radiation on polyamide 1010 aggregate structures and crystal damage were examined by using wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS) techniques. The results revealed that some structural parameters of the aggregated state, the density differences...

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Veröffentlicht in:Polymer degradation and stability 1995, Vol.50 (1), p.71-74
Hauptverfasser: Zhang, H.F., Zhang, L.H., Yang, B.Q., Mo, Z.S.
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container_title Polymer degradation and stability
container_volume 50
creator Zhang, H.F.
Zhang, L.H.
Yang, B.Q.
Mo, Z.S.
description The influence of γ-radiation on polyamide 1010 aggregate structures and crystal damage were examined by using wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS) techniques. The results revealed that some structural parameters of the aggregated state, the density differences and the degree of crystallinity W c,x, essentially decreased with increasing radiation dose, but the specific surface O s increased. Crosslinking and scission of irradiated polyamide 1010 samples occurred mainly in amorphous and interphase regions, and crystal damage and amorphization induced by γ-radiation spread from the interphase and extended into the crystal phase with increasing radiation dose. This result also indicated that the (010) reflection with the hydrogen bond was more susceptible to the action of radiation.
doi_str_mv 10.1016/0141-3910(95)00124-5
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subjects Applied sciences
Crosslinking and degradation
Exact sciences and technology
Physicochemistry of polymers
Polymers and radiations
title The influence of γ-radiation on polyamide 1010 aggregate structures
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