Supercritical Debinding of Injection Molded Ceramics
Extraction of organic additives from extrusion‐molded cylinders of alumina by a supercritical fluid is investigated. Hildebrand parameters alone are not adequate to predict conditions for optimal polymer extraction with supercritical CO2. The results obtained with two models developed for the kineti...
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Veröffentlicht in: | Journal of the American Ceramic Society 1995-07, Vol.78 (7), p.1787-1792 |
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container_title | Journal of the American Ceramic Society |
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creator | Chartier, Thierry Ferrato, Marc Baumard, Jean F. |
description | Extraction of organic additives from extrusion‐molded cylinders of alumina by a supercritical fluid is investigated. Hildebrand parameters alone are not adequate to predict conditions for optimal polymer extraction with supercritical CO2. The results obtained with two models developed for the kinetics of binder extraction suggest that polymer extraction from green samples is controlled by diffusion without development of a reaction front. The solubility and diffusivity of polymers both affect the extraction rate, with opposite pressure and temperature dependencies. |
doi_str_mv | 10.1111/j.1151-2916.1995.tb08890.x |
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Hildebrand parameters alone are not adequate to predict conditions for optimal polymer extraction with supercritical CO2. The results obtained with two models developed for the kinetics of binder extraction suggest that polymer extraction from green samples is controlled by diffusion without development of a reaction front. The solubility and diffusivity of polymers both affect the extraction rate, with opposite pressure and temperature dependencies.</description><subject>Applied sciences</subject><subject>Building materials. Ceramics. Glasses</subject><subject>Ceramic industries</subject><subject>Chemical industry and chemicals</subject><subject>Exact sciences and technology</subject><subject>General studies</subject><subject>Technical ceramics</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><recordid>eNqVkMtOwzAQRS0EEqXwDxFC7BJsJ45tVlSl9KFSFjy6tBzHQS5pUuxUtH-Po1Rdgzcja-6cGR0ArhGMkH93K18ICjFHaYQ4J1GTQcY4jHYnoIfIoXUKehBCHFKG4Tm4cG7lv4izpAeS1-1GW2VNY5Qsg0edmSo31WdQF8G0WmnVmLoKnusy13kw1FaujXKX4KyQpdNXh9oH70-jt-EknL-Mp8PBPFQEYRoimSEJC0QyTTlJWI79yYylcZxkikKKC8IypWLNU-YnNFcqk2lOeKaKmOki7oPbjrux9fdWu0asjVO6LGWl660TmHBGk5T9KYhRin3wvgsqWztndSE21qyl3QsERWtUrERrVLTaRGtUHIyKnR--OWyRzssqrKyUcUdCTDhhqD3moYv9mFLv_7FAzAbDEaKMekTYIYxr9O6IkPZLpDSmRCwXY_GxmMz4eOkp8S8vl5ln</recordid><startdate>199507</startdate><enddate>199507</enddate><creator>Chartier, Thierry</creator><creator>Ferrato, Marc</creator><creator>Baumard, Jean F.</creator><general>Blackwell Publishing Ltd</general><general>Blackwell</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7QQ</scope></search><sort><creationdate>199507</creationdate><title>Supercritical Debinding of Injection Molded Ceramics</title><author>Chartier, Thierry ; Ferrato, Marc ; Baumard, Jean F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5127-1ab1a0f15be79548d2111886334bc7072f58bcc3e968c51e9ccba6d59bcf38ef3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1995</creationdate><topic>Applied sciences</topic><topic>Building materials. 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Glasses</topic><topic>Ceramic industries</topic><topic>Chemical industry and chemicals</topic><topic>Exact sciences and technology</topic><topic>General studies</topic><topic>Technical ceramics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chartier, Thierry</creatorcontrib><creatorcontrib>Ferrato, Marc</creatorcontrib><creatorcontrib>Baumard, Jean F.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Ceramic Abstracts</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chartier, Thierry</au><au>Ferrato, Marc</au><au>Baumard, Jean F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supercritical Debinding of Injection Molded Ceramics</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>1995-07</date><risdate>1995</risdate><volume>78</volume><issue>7</issue><spage>1787</spage><epage>1792</epage><pages>1787-1792</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><coden>JACTAW</coden><abstract>Extraction of organic additives from extrusion‐molded cylinders of alumina by a supercritical fluid is investigated. Hildebrand parameters alone are not adequate to predict conditions for optimal polymer extraction with supercritical CO2. The results obtained with two models developed for the kinetics of binder extraction suggest that polymer extraction from green samples is controlled by diffusion without development of a reaction front. The solubility and diffusivity of polymers both affect the extraction rate, with opposite pressure and temperature dependencies.</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1151-2916.1995.tb08890.x</doi><tpages>6</tpages></addata></record> |
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subjects | Applied sciences Building materials. Ceramics. Glasses Ceramic industries Chemical industry and chemicals Exact sciences and technology General studies Technical ceramics |
title | Supercritical Debinding of Injection Molded Ceramics |
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