Peculiar Spin-Crossover Behavior in the 2D Polymer K[FeIII(5Cl-thsa)2]

A potassium salt of the N2S2O2-coordination Fe­(III) anion K­[Fe­(5Cl-thsa)2] (1) (5Cl-thsa − 5-chlorosalicylaldehyde thiosemicarbazone) is synthesized and characterized structurally and magnetically over a wide temperature range. Two polymorphs of salt 1 characterized by the common 2D polymer natur...

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Veröffentlicht in:	Inorganic chemistry 2021-12, Vol.60 (23), p.17462-17479
Hauptverfasser:	Spitsyna, Nataliya G, Blagov, Maxim A, Lazarenko, Vladimir A, Svetogorov, Roman D, Zubavichus, Yan V, Zorina, Leokadiya V, Maximova, Olga, Yaroslavtsev, Sergey A, Rusakov, Vyacheslav S, Raganyan, Grigory V, Yagubskii, Eduard B, Vasiliev, Alexander N
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
Online-Zugang:	Volltext
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