Selective Reduction of CO2 to a Tantalum Formate Complex and Release of Methyl Formate from the Tantalum(V) Center
A cyclometalated NHC-coordinated hydrido tantalum alkoxide was found to selectively react with CO2 to afford the genuine tantalum formate (NHC)(HCOO)Ta(ORF)3 with ORF = OC(CF3)2CH3. In the solid state, the presence of a κ2-O,O-formate moiety was established by single-crystal X-ray diffraction an...
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| Veröffentlicht in: | Inorganic chemistry 2021-12, Vol.60 (23), p.18291-18295 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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