Ni-Catalyzed Enantioselective Allylic Alkylation of H‑Phosphinates

The asymmetric synthesis of P-stereogenic phosphinates through allylic alkylation of H-phosphinates has been developed. With H-phosphinates and allylic acetates as the starting materials, a variety of allylic P-chiral phosphinates were accessed in high enantioselectivities of up to 92% ee and genera...

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Veröffentlicht in:	Organic letters 2021-11, Vol.23 (22), p.8683-8687
Hauptverfasser:	Zhang, Qing, Liu, Xu-Teng, Wu, Yue, Zhang, Qing-Wei
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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