The Formation of P–C Bonds Utilizing Organozinc Reagents for the Synthesis of Aryl- and Heteroaryl-Dichlorophosphines

Aryl- and heteroaryl-dichlorophosphines are mildly and selectively made in a one-pot synthesis in moderate to good yields starting from the respective aryl bromides or five-membered heterocycles, following lithiation with nBuLi, transmetalation with ZnCl2, and subsequently the reaction with PCl3. Se...

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Veröffentlicht in:	Journal of organic chemistry 2021-12, Vol.86 (23), p.17337-17343
Hauptverfasser:	Kirst, Christin, Tietze, Jonathan, Ebeling, Marian, Horndasch, Lukas, Karaghiosoff, Konstantin
Format:	Artikel
Sprache:	eng
Schlagworte:	Bromides Indicators and Reagents
Online-Zugang:	Volltext
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