Coupled Compositional and Displacive Modulations in KLaMnWO6 Revealed by Atomic Resolution Imaging

Coupled Compositional and Displacive Modulations in KLaMnWO6 Revealed by Atomic Resolution Imaging

Complex compositional and displacive modulations of the crystal structure of KLaMnWO6 are imaged with atomic resolution by means of scanning transmission electron microscopy (STEM). This oxide is stabilized by cation vacancies leading to a La1+x/3K1–x MnWO6 stoichiometry. Compositional modulation on...

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Veröffentlicht in:Journal of the American Chemical Society 2021-11, Vol.143 (45), p.19121-19127
Hauptverfasser: Garcia-Martin, Susana, King, Graham, Urones-Garrote, Esteban, Woodward, Patrick M
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creator Garcia-Martin, Susana
King, Graham
Urones-Garrote, Esteban
Woodward, Patrick M
description Complex compositional and displacive modulations of the crystal structure of KLaMnWO6 are imaged with atomic resolution by means of scanning transmission electron microscopy (STEM). This oxide is stabilized by cation vacancies leading to a La1+x/3K1–x MnWO6 stoichiometry. Compositional modulation on both the K and La layers are revealed in the high-angle annular dark-field STEM (HAADF-STEM) images. The compositional modulation within the La layer is coupled with the modulation of the octahedral tilting, which is exposed by imaging of the anion sublattice in annular bright-field STEM (ABF-STEM) images. These complex modulations are accommodated in a 5√2a p × 5√2a p × 2a p perovskite-type structure.
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title Coupled Compositional and Displacive Modulations in KLaMnWO6 Revealed by Atomic Resolution Imaging
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