Production of photoluminescent transparent poly(methyl methacrylate) for smart windows
Photochromic and long‐lasting photoluminescent transparent, rigid, ultraviolet (UV) protective and superhydrophobic poly(methyl methacrylate) (PMMA) plastic able to switch colour beneath UV irradiation was developed. Photoluminescent transparent PMMA plastic was prepared by the simple polymerization...
Gespeichert in:
| Veröffentlicht in: | Luminescence (Chichester, England) England), 2022-01, Vol.37 (1), p.97-107 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 107 |
|---|---|
| container_issue | 1 |
| container_start_page | 97 |
| container_title | Luminescence (Chichester, England) |
| container_volume | 37 |
| creator | El‐Newehy, Mohamed H. Kim, Hak Yong Khattab, Tawfik A. El‐Naggar, Mehrez E. |
| description | Photochromic and long‐lasting photoluminescent transparent, rigid, ultraviolet (UV) protective and superhydrophobic poly(methyl methacrylate) (PMMA) plastic able to switch colour beneath UV irradiation was developed. Photoluminescent transparent PMMA plastic was prepared by the simple polymerization process of methyl methacrylate immobilized with alkaline earth aluminate (AEA) nanoparticles. These colourless PMMA plastic substrates showed a colour switch to greenish underneath UV light as proved using CIELAB screening. The morphology of AEA was evaluated using transmission electron microscopy. Conversely, transparent PMMA samples were evaluated using energy‐dispersive X‐ray spectra, scanning electron microscope, X‐ray fluorescence spectroscopy and for hardness properties. Additionally, the photoluminescence properties were explored by studying excitation and emission spectra. The produced luminescence colourless PMMA plastic substrates displayed excitation band at 370 nm, and three emission peaks at 433, 494 and 513 nm. Photoluminescent PMMA with lower contents of AEA showed fast and reversible photochromism under UV light, while PMMA samples with higher contents of AEA showed long‐lasting luminescence such as a flashlight with the ability to replace electric power. The findings showed that the produced photoluminescence colourless PMMA plastic substrates exhibited enhanced UV shielding and superhydrophobicity.
Photoluminescent transparent polymethyl methacrylate with improved ultraviolet blocking and superhydrophobicity was developed for potential smart windows. Photochromism and persistent phosphorescence were achieved relying on the total content of alkaline earth aluminate nanoparticles. Reversible photochromic response to ultraviolet light was reported without fatigue demonstrating a color change from colorless under visible light to greenish under ultraviolet light |
| doi_str_mv | 10.1002/bio.4150 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2590121633</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2590121633</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3490-8a3376aa7aa77251cb5efc3f76b41446e41262b16b12ce7571dd138317f310743</originalsourceid><addsrcrecordid>eNp1kE1Lw0AQhhdRbK2Cv0ACXuohdWc_26MWv6BQD-p12SQbmpJk425Cyb93a2sRQRh45_DwMPMidAl4AhiT26SwEwYcH6EhcEJiSRg9PuyUD9CZ92uMsRBidooGlEmgnNMh-nh1NuvStrB1ZPOoWdnWll1V1Manpm6j1unaN9pt98aW_bgy7aovo23o1PWlbs1NlFsX-Uq7NtoUdWY3_hyd5Lr05mKfI_T--PA2f44Xy6eX-d0iTimb4XiqKZVCaxlGEg5pwk2e0lyKhAFjwjAggiQgEiCpkVxClgGdUpA5BSwZHaHxzts4-9kZ36qqCIeXpa6N7bwifIaBgKA0oNd_0LXtXB2uU0QAnwoA8UuYOuu9M7lqXBE-6xVgte1aha7VtuuAXu2FXVKZ7AD-lBuAeAdsitL0_4rU_cvyW_gFe1eHWA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2615861164</pqid></control><display><type>article</type><title>Production of photoluminescent transparent poly(methyl methacrylate) for smart windows</title><source>Wiley Online Library - AutoHoldings Journals</source><source>MEDLINE</source><creator>El‐Newehy, Mohamed H. ; Kim, Hak Yong ; Khattab, Tawfik A. ; El‐Naggar, Mehrez E.</creator><creatorcontrib>El‐Newehy, Mohamed H. ; Kim, Hak Yong ; Khattab, Tawfik A. ; El‐Naggar, Mehrez E.</creatorcontrib><description>Photochromic and long‐lasting photoluminescent transparent, rigid, ultraviolet (UV) protective and superhydrophobic poly(methyl methacrylate) (PMMA) plastic able to switch colour beneath UV irradiation was developed. Photoluminescent transparent PMMA plastic was prepared by the simple polymerization process of methyl methacrylate immobilized with alkaline earth aluminate (AEA) nanoparticles. These colourless PMMA plastic substrates showed a colour switch to greenish underneath UV light as proved using CIELAB screening. The morphology of AEA was evaluated using transmission electron microscopy. Conversely, transparent PMMA samples were evaluated using energy‐dispersive X‐ray spectra, scanning electron microscope, X‐ray fluorescence spectroscopy and for hardness properties. Additionally, the photoluminescence properties were explored by studying excitation and emission spectra. The produced luminescence colourless PMMA plastic substrates displayed excitation band at 370 nm, and three emission peaks at 433, 494 and 513 nm. Photoluminescent PMMA with lower contents of AEA showed fast and reversible photochromism under UV light, while PMMA samples with higher contents of AEA showed long‐lasting luminescence such as a flashlight with the ability to replace electric power. The findings showed that the produced photoluminescence colourless PMMA plastic substrates exhibited enhanced UV shielding and superhydrophobicity.
Photoluminescent transparent polymethyl methacrylate with improved ultraviolet blocking and superhydrophobicity was developed for potential smart windows. Photochromism and persistent phosphorescence were achieved relying on the total content of alkaline earth aluminate nanoparticles. Reversible photochromic response to ultraviolet light was reported without fatigue demonstrating a color change from colorless under visible light to greenish under ultraviolet light</description><identifier>ISSN: 1522-7235</identifier><identifier>EISSN: 1522-7243</identifier><identifier>DOI: 10.1002/bio.4150</identifier><identifier>PMID: 34713553</identifier><language>eng</language><publisher>England: Wiley Subscription Services, Inc</publisher><subject>alkaline earth aluminate ; Analytical methods ; Color ; Colour ; Electric power ; Electric power sources ; Electron microscopy ; Emission analysis ; Emission spectra ; Excitation ; Excitation spectra ; Fluorescence ; Fluorescence spectroscopy ; Hydrophobic surfaces ; Hydrophobicity ; Irradiation ; Luminescence ; Nanoparticles ; Photochromism ; Photoluminescence ; Photons ; Plastics ; poly(methyl methacrylate) ; Polymerization ; Polymethyl Methacrylate ; Polymethylmethacrylate ; Properties ; Scanning electron microscopy ; Shielding ; Smart materials ; Spectra ; Spectrum analysis ; Substrates ; superhydrophobic ; Transmission electron microscopy ; Ultraviolet radiation ; Water hardness ; Windows (apertures)</subject><ispartof>Luminescence (Chichester, England), 2022-01, Vol.37 (1), p.97-107</ispartof><rights>2021 John Wiley & Sons, Ltd.</rights><rights>2022 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3490-8a3376aa7aa77251cb5efc3f76b41446e41262b16b12ce7571dd138317f310743</citedby><cites>FETCH-LOGICAL-c3490-8a3376aa7aa77251cb5efc3f76b41446e41262b16b12ce7571dd138317f310743</cites><orcidid>0000-0002-4265-0701 ; 0000-0001-7834-4952 ; 0000-0003-2556-3048</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fbio.4150$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fbio.4150$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/34713553$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>El‐Newehy, Mohamed H.</creatorcontrib><creatorcontrib>Kim, Hak Yong</creatorcontrib><creatorcontrib>Khattab, Tawfik A.</creatorcontrib><creatorcontrib>El‐Naggar, Mehrez E.</creatorcontrib><title>Production of photoluminescent transparent poly(methyl methacrylate) for smart windows</title><title>Luminescence (Chichester, England)</title><addtitle>Luminescence</addtitle><description>Photochromic and long‐lasting photoluminescent transparent, rigid, ultraviolet (UV) protective and superhydrophobic poly(methyl methacrylate) (PMMA) plastic able to switch colour beneath UV irradiation was developed. Photoluminescent transparent PMMA plastic was prepared by the simple polymerization process of methyl methacrylate immobilized with alkaline earth aluminate (AEA) nanoparticles. These colourless PMMA plastic substrates showed a colour switch to greenish underneath UV light as proved using CIELAB screening. The morphology of AEA was evaluated using transmission electron microscopy. Conversely, transparent PMMA samples were evaluated using energy‐dispersive X‐ray spectra, scanning electron microscope, X‐ray fluorescence spectroscopy and for hardness properties. Additionally, the photoluminescence properties were explored by studying excitation and emission spectra. The produced luminescence colourless PMMA plastic substrates displayed excitation band at 370 nm, and three emission peaks at 433, 494 and 513 nm. Photoluminescent PMMA with lower contents of AEA showed fast and reversible photochromism under UV light, while PMMA samples with higher contents of AEA showed long‐lasting luminescence such as a flashlight with the ability to replace electric power. The findings showed that the produced photoluminescence colourless PMMA plastic substrates exhibited enhanced UV shielding and superhydrophobicity.
Photoluminescent transparent polymethyl methacrylate with improved ultraviolet blocking and superhydrophobicity was developed for potential smart windows. Photochromism and persistent phosphorescence were achieved relying on the total content of alkaline earth aluminate nanoparticles. Reversible photochromic response to ultraviolet light was reported without fatigue demonstrating a color change from colorless under visible light to greenish under ultraviolet light</description><subject>alkaline earth aluminate</subject><subject>Analytical methods</subject><subject>Color</subject><subject>Colour</subject><subject>Electric power</subject><subject>Electric power sources</subject><subject>Electron microscopy</subject><subject>Emission analysis</subject><subject>Emission spectra</subject><subject>Excitation</subject><subject>Excitation spectra</subject><subject>Fluorescence</subject><subject>Fluorescence spectroscopy</subject><subject>Hydrophobic surfaces</subject><subject>Hydrophobicity</subject><subject>Irradiation</subject><subject>Luminescence</subject><subject>Nanoparticles</subject><subject>Photochromism</subject><subject>Photoluminescence</subject><subject>Photons</subject><subject>Plastics</subject><subject>poly(methyl methacrylate)</subject><subject>Polymerization</subject><subject>Polymethyl Methacrylate</subject><subject>Polymethylmethacrylate</subject><subject>Properties</subject><subject>Scanning electron microscopy</subject><subject>Shielding</subject><subject>Smart materials</subject><subject>Spectra</subject><subject>Spectrum analysis</subject><subject>Substrates</subject><subject>superhydrophobic</subject><subject>Transmission electron microscopy</subject><subject>Ultraviolet radiation</subject><subject>Water hardness</subject><subject>Windows (apertures)</subject><issn>1522-7235</issn><issn>1522-7243</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp1kE1Lw0AQhhdRbK2Cv0ACXuohdWc_26MWv6BQD-p12SQbmpJk425Cyb93a2sRQRh45_DwMPMidAl4AhiT26SwEwYcH6EhcEJiSRg9PuyUD9CZ92uMsRBidooGlEmgnNMh-nh1NuvStrB1ZPOoWdnWll1V1Manpm6j1unaN9pt98aW_bgy7aovo23o1PWlbs1NlFsX-Uq7NtoUdWY3_hyd5Lr05mKfI_T--PA2f44Xy6eX-d0iTimb4XiqKZVCaxlGEg5pwk2e0lyKhAFjwjAggiQgEiCpkVxClgGdUpA5BSwZHaHxzts4-9kZ36qqCIeXpa6N7bwifIaBgKA0oNd_0LXtXB2uU0QAnwoA8UuYOuu9M7lqXBE-6xVgte1aha7VtuuAXu2FXVKZ7AD-lBuAeAdsitL0_4rU_cvyW_gFe1eHWA</recordid><startdate>202201</startdate><enddate>202201</enddate><creator>El‐Newehy, Mohamed H.</creator><creator>Kim, Hak Yong</creator><creator>Khattab, Tawfik A.</creator><creator>El‐Naggar, Mehrez E.</creator><general>Wiley Subscription Services, Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QP</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>7U7</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H95</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L.G</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-4265-0701</orcidid><orcidid>https://orcid.org/0000-0001-7834-4952</orcidid><orcidid>https://orcid.org/0000-0003-2556-3048</orcidid></search><sort><creationdate>202201</creationdate><title>Production of photoluminescent transparent poly(methyl methacrylate) for smart windows</title><author>El‐Newehy, Mohamed H. ; Kim, Hak Yong ; Khattab, Tawfik A. ; El‐Naggar, Mehrez E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3490-8a3376aa7aa77251cb5efc3f76b41446e41262b16b12ce7571dd138317f310743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>alkaline earth aluminate</topic><topic>Analytical methods</topic><topic>Color</topic><topic>Colour</topic><topic>Electric power</topic><topic>Electric power sources</topic><topic>Electron microscopy</topic><topic>Emission analysis</topic><topic>Emission spectra</topic><topic>Excitation</topic><topic>Excitation spectra</topic><topic>Fluorescence</topic><topic>Fluorescence spectroscopy</topic><topic>Hydrophobic surfaces</topic><topic>Hydrophobicity</topic><topic>Irradiation</topic><topic>Luminescence</topic><topic>Nanoparticles</topic><topic>Photochromism</topic><topic>Photoluminescence</topic><topic>Photons</topic><topic>Plastics</topic><topic>poly(methyl methacrylate)</topic><topic>Polymerization</topic><topic>Polymethyl Methacrylate</topic><topic>Polymethylmethacrylate</topic><topic>Properties</topic><topic>Scanning electron microscopy</topic><topic>Shielding</topic><topic>Smart materials</topic><topic>Spectra</topic><topic>Spectrum analysis</topic><topic>Substrates</topic><topic>superhydrophobic</topic><topic>Transmission electron microscopy</topic><topic>Ultraviolet radiation</topic><topic>Water hardness</topic><topic>Windows (apertures)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>El‐Newehy, Mohamed H.</creatorcontrib><creatorcontrib>Kim, Hak Yong</creatorcontrib><creatorcontrib>Khattab, Tawfik A.</creatorcontrib><creatorcontrib>El‐Naggar, Mehrez E.</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Calcium & Calcified Tissue Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 1: Biological Sciences & Living Resources</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Luminescence (Chichester, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>El‐Newehy, Mohamed H.</au><au>Kim, Hak Yong</au><au>Khattab, Tawfik A.</au><au>El‐Naggar, Mehrez E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Production of photoluminescent transparent poly(methyl methacrylate) for smart windows</atitle><jtitle>Luminescence (Chichester, England)</jtitle><addtitle>Luminescence</addtitle><date>2022-01</date><risdate>2022</risdate><volume>37</volume><issue>1</issue><spage>97</spage><epage>107</epage><pages>97-107</pages><issn>1522-7235</issn><eissn>1522-7243</eissn><abstract>Photochromic and long‐lasting photoluminescent transparent, rigid, ultraviolet (UV) protective and superhydrophobic poly(methyl methacrylate) (PMMA) plastic able to switch colour beneath UV irradiation was developed. Photoluminescent transparent PMMA plastic was prepared by the simple polymerization process of methyl methacrylate immobilized with alkaline earth aluminate (AEA) nanoparticles. These colourless PMMA plastic substrates showed a colour switch to greenish underneath UV light as proved using CIELAB screening. The morphology of AEA was evaluated using transmission electron microscopy. Conversely, transparent PMMA samples were evaluated using energy‐dispersive X‐ray spectra, scanning electron microscope, X‐ray fluorescence spectroscopy and for hardness properties. Additionally, the photoluminescence properties were explored by studying excitation and emission spectra. The produced luminescence colourless PMMA plastic substrates displayed excitation band at 370 nm, and three emission peaks at 433, 494 and 513 nm. Photoluminescent PMMA with lower contents of AEA showed fast and reversible photochromism under UV light, while PMMA samples with higher contents of AEA showed long‐lasting luminescence such as a flashlight with the ability to replace electric power. The findings showed that the produced photoluminescence colourless PMMA plastic substrates exhibited enhanced UV shielding and superhydrophobicity.
Photoluminescent transparent polymethyl methacrylate with improved ultraviolet blocking and superhydrophobicity was developed for potential smart windows. Photochromism and persistent phosphorescence were achieved relying on the total content of alkaline earth aluminate nanoparticles. Reversible photochromic response to ultraviolet light was reported without fatigue demonstrating a color change from colorless under visible light to greenish under ultraviolet light</abstract><cop>England</cop><pub>Wiley Subscription Services, Inc</pub><pmid>34713553</pmid><doi>10.1002/bio.4150</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-4265-0701</orcidid><orcidid>https://orcid.org/0000-0001-7834-4952</orcidid><orcidid>https://orcid.org/0000-0003-2556-3048</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1522-7235 |
| ispartof | Luminescence (Chichester, England), 2022-01, Vol.37 (1), p.97-107 |
| issn | 1522-7235 1522-7243 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2590121633 |
| source | Wiley Online Library - AutoHoldings Journals; MEDLINE |
| subjects | alkaline earth aluminate Analytical methods Color Colour Electric power Electric power sources Electron microscopy Emission analysis Emission spectra Excitation Excitation spectra Fluorescence Fluorescence spectroscopy Hydrophobic surfaces Hydrophobicity Irradiation Luminescence Nanoparticles Photochromism Photoluminescence Photons Plastics poly(methyl methacrylate) Polymerization Polymethyl Methacrylate Polymethylmethacrylate Properties Scanning electron microscopy Shielding Smart materials Spectra Spectrum analysis Substrates superhydrophobic Transmission electron microscopy Ultraviolet radiation Water hardness Windows (apertures) |
| title | Production of photoluminescent transparent poly(methyl methacrylate) for smart windows |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-05T20%3A13%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Production%20of%20photoluminescent%20transparent%20poly(methyl%20methacrylate)%20for%20smart%20windows&rft.jtitle=Luminescence%20(Chichester,%20England)&rft.au=El%E2%80%90Newehy,%20Mohamed%20H.&rft.date=2022-01&rft.volume=37&rft.issue=1&rft.spage=97&rft.epage=107&rft.pages=97-107&rft.issn=1522-7235&rft.eissn=1522-7243&rft_id=info:doi/10.1002/bio.4150&rft_dat=%3Cproquest_cross%3E2590121633%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2615861164&rft_id=info:pmid/34713553&rfr_iscdi=true |