Relative fluorescence-quenching measurements of atomic hydrogen in subatmospheric H2/O2/N2 flames with photoionization controlled-loss spectroscopy

Photoionization controlled-loss spectroscopy (PICLS) is developed to obtain relative changes in the fluorescence transition probability (A + Q) under conditions where conventional measurements of the fluorescence lifetime are not feasible. Using PICLS, vertical profiles of relative changes in the tr...

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Veröffentlicht in:Journal of quantitative spectroscopy & radiative transfer 1990-02, Vol.43 (2), p.155-162
Hauptverfasser: THADDEUS SALMON, J, LAURENDEAU, N. M
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LAURENDEAU, N. M
description Photoionization controlled-loss spectroscopy (PICLS) is developed to obtain relative changes in the fluorescence transition probability (A + Q) under conditions where conventional measurements of the fluorescence lifetime are not feasible. Using PICLS, vertical profiles of relative changes in the transition probability have been measured in 20-torr premixed flat H2/O2/N2 flames under stoichiometric and fuel-rich conditions. These profiles are compared with predictions from kinetic theory, and the implications of this comparison for quantitative fluorescence measurements of atomic hydrogen in flames are discussed. (Author)
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subjects Atomic and molecular physics
Atomic properties and interactions with photons
Exact sciences and technology
Intensities and shapes of atomic spectral lines
Physics
title Relative fluorescence-quenching measurements of atomic hydrogen in subatmospheric H2/O2/N2 flames with photoionization controlled-loss spectroscopy
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