Relative fluorescence-quenching measurements of atomic hydrogen in subatmospheric H2/O2/N2 flames with photoionization controlled-loss spectroscopy
Photoionization controlled-loss spectroscopy (PICLS) is developed to obtain relative changes in the fluorescence transition probability (A + Q) under conditions where conventional measurements of the fluorescence lifetime are not feasible. Using PICLS, vertical profiles of relative changes in the tr...
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Veröffentlicht in: | Journal of quantitative spectroscopy & radiative transfer 1990-02, Vol.43 (2), p.155-162 |
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creator | THADDEUS SALMON, J LAURENDEAU, N. M |
description | Photoionization controlled-loss spectroscopy (PICLS) is developed to obtain relative changes in the fluorescence transition probability (A + Q) under conditions where conventional measurements of the fluorescence lifetime are not feasible. Using PICLS, vertical profiles of relative changes in the transition probability have been measured in 20-torr premixed flat H2/O2/N2 flames under stoichiometric and fuel-rich conditions. These profiles are compared with predictions from kinetic theory, and the implications of this comparison for quantitative fluorescence measurements of atomic hydrogen in flames are discussed. (Author) |
doi_str_mv | 10.1016/0022-4073(90)90044-7 |
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(Author)</description><subject>Atomic and molecular physics</subject><subject>Atomic properties and interactions with photons</subject><subject>Exact sciences and technology</subject><subject>Intensities and shapes of atomic spectral lines</subject><subject>Physics</subject><issn>0022-4073</issn><issn>1879-1352</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNo9UcuO1TAMrRBIXAb-gEUWCMGi3DzaJlmiETBII0ZCsI7S1J0GpUmJU9DlN_hhcpnRrCzb5xzbx03zktF3jLLhSCnnbUeleKPpW01p17XyUXNgSuqWiZ4_bg4PkKfNM8QflFIh2HBo_n6FYIv_BWQOe8qADqKD9udew-LjLVnB4p5hhViQpJnYklbvyHKacrqFSHwkuI-2rAm3BXJtXfHjDT9-4VXRroDkty8L2ZZUkk_R_6nTUiQuxZJTCDC1ISES3MDVArq0nZ43T2YbEF7cx4vm-8cP3y6v2uubT58v31-3TlBd2pEN4KQcZ0Yn6HsYO9cNtmZDpyUHbtWorFRODaofJsu0mq1QPZ-skLofQVw0r-90t5zqwVjM6uv9IdgIaUfDe6WEVLQCuzugqxtihtls2a82nwyj5vwBc7bXnO01mpr_HzCy0l7d61t0NszZRufxgTso0UulxT-v-4pN</recordid><startdate>19900201</startdate><enddate>19900201</enddate><creator>THADDEUS SALMON, J</creator><creator>LAURENDEAU, N. 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M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Relative fluorescence-quenching measurements of atomic hydrogen in subatmospheric H2/O2/N2 flames with photoionization controlled-loss spectroscopy</atitle><jtitle>Journal of quantitative spectroscopy & radiative transfer</jtitle><date>1990-02-01</date><risdate>1990</risdate><volume>43</volume><issue>2</issue><spage>155</spage><epage>162</epage><pages>155-162</pages><issn>0022-4073</issn><eissn>1879-1352</eissn><coden>JQSRAE</coden><abstract>Photoionization controlled-loss spectroscopy (PICLS) is developed to obtain relative changes in the fluorescence transition probability (A + Q) under conditions where conventional measurements of the fluorescence lifetime are not feasible. Using PICLS, vertical profiles of relative changes in the transition probability have been measured in 20-torr premixed flat H2/O2/N2 flames under stoichiometric and fuel-rich conditions. 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subjects | Atomic and molecular physics Atomic properties and interactions with photons Exact sciences and technology Intensities and shapes of atomic spectral lines Physics |
title | Relative fluorescence-quenching measurements of atomic hydrogen in subatmospheric H2/O2/N2 flames with photoionization controlled-loss spectroscopy |
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