The organocatalytic synthesis of perfluorophenylsulfides via the thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates

The organocatalytic synthesis of perfluorophenylsulfides via the thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates

The organic superbase -Bu-P -catalyzed direct thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates was developed. Yields of perfluorophenylsulfides of up to 97% under catalysis of 5 mol% -Bu-P were achieved. This method was shown to provide an efficient way to construct the perfluoroph...

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Veröffentlicht in:Organic & biomolecular chemistry 2021-11, Vol.19 (42), p.9237-9241
Hauptverfasser: Luo, Jinyun, Lin, Muze, Wu, Leifang, Cai, Zhihua, He, Lin, Du, Guangfen
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Catalysis
Perfluoro compounds
Silanes
Sulfur
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container_issue 42
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container_title Organic & biomolecular chemistry
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creator Luo, Jinyun
Lin, Muze
Wu, Leifang
Cai, Zhihua
He, Lin
Du, Guangfen
description The organic superbase -Bu-P -catalyzed direct thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates was developed. Yields of perfluorophenylsulfides of up to 97% under catalysis of 5 mol% -Bu-P were achieved. This method was shown to provide an efficient way to construct the perfluorophenyl-sulfur bond under mild metal-free reaction conditions.
doi_str_mv 10.1039/d1ob01350e
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Catalysis
Perfluoro compounds
Silanes
Sulfur
title The organocatalytic synthesis of perfluorophenylsulfides via the thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates
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