Poly(2,6-dimethyl-1,4-phenylene oxide)-poly(methyl methacrylate) interpenetrating polymer networks
Two-component simultaneous interpenetrating polymer networks (SINs)of brominated poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) cross-linked with ethylenediamine (EDA) and poly(methyl methacrylate) (PMMA) cross-linked with ethylene glycol dimethacrylate (EGDMA) were prepared. The estimated molecular w...
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| Veröffentlicht in: | Macromolecules 1990-03, Vol.23 (2), p.375-377 |
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| creator | Singh, Sunita Frisch, Harry L Ghiradella, Helen |
| description | Two-component simultaneous interpenetrating polymer networks (SINs)of brominated poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) cross-linked with ethylenediamine (EDA) and poly(methyl methacrylate) (PMMA) cross-linked with ethylene glycol dimethacrylate (EGDMA) were prepared. The estimated molecular weights between cross-links (M sub e ) from the stoichiometry of the PPO and PMMA networks were 6000 and 7900, respectively. Differential scanning calorimetry (DSC) measurements show that the IPNs have a single glass transition (T sub g ) intermediate in temperature to the T sub g s of the component networks. Transmission electron micrographs also are consistent with a single-phase morphology. A maximum in tensile strength significantly higher than the tensile strengths of a component network occurred at an intermediate composition, just as has been observed for the PPO/polystyrene IPNs. . 8 ref.--AA |
| doi_str_mv | 10.1021/ma00204a003 |
| format | Article |
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The estimated molecular weights between cross-links (M sub e ) from the stoichiometry of the PPO and PMMA networks were 6000 and 7900, respectively. Differential scanning calorimetry (DSC) measurements show that the IPNs have a single glass transition (T sub g ) intermediate in temperature to the T sub g s of the component networks. Transmission electron micrographs also are consistent with a single-phase morphology. 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The estimated molecular weights between cross-links (M sub e ) from the stoichiometry of the PPO and PMMA networks were 6000 and 7900, respectively. Differential scanning calorimetry (DSC) measurements show that the IPNs have a single glass transition (T sub g ) intermediate in temperature to the T sub g s of the component networks. Transmission electron micrographs also are consistent with a single-phase morphology. A maximum in tensile strength significantly higher than the tensile strengths of a component network occurred at an intermediate composition, just as has been observed for the PPO/polystyrene IPNs. . 8 ref.--AA</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular structures</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0024-9297</issn><issn>1520-5835</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNpt0E1P3DAQBmCrKhJb6Ik_kEPVFhVTjx3H2WOFCkVCYrW7B27W4ExKIF_YWZX8exxlhXrg4pHGj19ZL2MnIM5BSPjZoBBSpPFUH9gCtBRc50p_ZIu4T_lSLs0h-xTCoxAAOlULdr_q6vG7PMt4UTU0PIw1h7OU9w_UjjW1lHQvVUGnvJ_YDJJpoPNjjQOdJlU7kO8jHTwOVfs3mWhDPombf51_CsfsoMQ60Of9PGLby9_biz_85vbq-uLXDUeVwcALBENGZxKc0UXqMlMoUEvURuVaGJk6FEahE87p-7IsMZcOqJCFECk5VEfs6xzb--55R2GwTRUc1TW21O2ClToHIyGN8McMne9C8FTa3lcN-tGCsFON9r8ao_6yj8XgsC49tq4Kb0-yGAqQR8ZnVoWBXt6u0T_ZzCij7Xa1sXfb9eZOXa7tFPtt9uiCfex2vo3VvPuBV5Lbjm8</recordid><startdate>19900301</startdate><enddate>19900301</enddate><creator>Singh, Sunita</creator><creator>Frisch, Harry L</creator><creator>Ghiradella, Helen</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19900301</creationdate><title>Poly(2,6-dimethyl-1,4-phenylene oxide)-poly(methyl methacrylate) interpenetrating polymer networks</title><author>Singh, Sunita ; Frisch, Harry L ; Ghiradella, Helen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a361t-da17e75621c75d4c67d3139a573850724ca073ac0cc5bfffa82c1ed2d004eca3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular structures</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Singh, Sunita</creatorcontrib><creatorcontrib>Frisch, Harry L</creatorcontrib><creatorcontrib>Ghiradella, Helen</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Singh, Sunita</au><au>Frisch, Harry L</au><au>Ghiradella, Helen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Poly(2,6-dimethyl-1,4-phenylene oxide)-poly(methyl methacrylate) interpenetrating polymer networks</atitle><jtitle>Macromolecules</jtitle><addtitle>Macromolecules</addtitle><date>1990-03-01</date><risdate>1990</risdate><volume>23</volume><issue>2</issue><spage>375</spage><epage>377</epage><pages>375-377</pages><issn>0024-9297</issn><eissn>1520-5835</eissn><coden>MAMOBX</coden><abstract>Two-component simultaneous interpenetrating polymer networks (SINs)of brominated poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) cross-linked with ethylenediamine (EDA) and poly(methyl methacrylate) (PMMA) cross-linked with ethylene glycol dimethacrylate (EGDMA) were prepared. The estimated molecular weights between cross-links (M sub e ) from the stoichiometry of the PPO and PMMA networks were 6000 and 7900, respectively. Differential scanning calorimetry (DSC) measurements show that the IPNs have a single glass transition (T sub g ) intermediate in temperature to the T sub g s of the component networks. Transmission electron micrographs also are consistent with a single-phase morphology. A maximum in tensile strength significantly higher than the tensile strengths of a component network occurred at an intermediate composition, just as has been observed for the PPO/polystyrene IPNs. . 8 ref.--AA</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ma00204a003</doi><tpages>3</tpages></addata></record> |
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| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymers with particular structures Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Poly(2,6-dimethyl-1,4-phenylene oxide)-poly(methyl methacrylate) interpenetrating polymer networks |
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