Contrasting the Mechanism of H2 Activation by Monomeric and Potassium‐Stabilized Dimeric AlI Complexes: Do Potassium Atoms Exert any Cooperative Effect?

Aluminyl anions are low‐valent, anionic, and carbenoid aluminum species commonly found stabilized with potassium cations from the reaction of Al‐halogen precursors and alkali compounds. These systems are very reactive toward the activation of σ‐bonds and in reactions with electrophiles. Various rese...

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Veröffentlicht in:	Chemistry : a European journal 2021-12, Vol.27 (69), p.17369-17378
Hauptverfasser:	Villegas‐Escobar, Nery, Toro‐Labbé, Alejandro, Schaefer, Henry F.
Format:	Artikel
Sprache:	eng
Schlagworte:	aluminium aluminyl anions H2 activation main group elements oxidative addition
Online-Zugang:	Volltext
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