A novel yttrium-based metal-organic framework for the efficient solvent-free catalytic synthesis of cyanohydrin silyl ethers
A new porous metal-organic framework (MOF) with the chemical formula [Y 5 L 6 (OH) 3 (DMF) 3 ]·5H 2 O ( 1 ) (where L = 3-amino-4-hydroxybenzoate) has been prepared by a solvothermal procedure. The structural characterization reveals that this material consists of a robust three-dimensional metal-org...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2021-09, Vol.5 (34), p.1172-11724 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Echenique-Errandonea, Estitxu Pérez, Juana M Rojas, Sara Cepeda, Javier Seco, José M Fernández, Ignacio Rodríguez-Diéguez, Antonio |
| description | A new porous metal-organic framework (MOF) with the chemical formula [Y
5
L
6
(OH)
3
(DMF)
3
]·5H
2
O (
1
) (where L = 3-amino-4-hydroxybenzoate) has been prepared by a solvothermal procedure. The structural characterization reveals that this material consists of a robust three-dimensional metal-organic framework (MOF) grown with clusters formed by Y(
iii
) and hydroxide anions joined to one another by the ligand, giving rise to an open structure with interconnected microchannels with variable dimensions. This assembled set has shown to possess a fascinating catalytic activity for the cyanosilylation of a broad range of aldehydes and ketones with exceptional recyclability, a solvent-free medium, and one order of magnitude lower catalyst loading compared to all related lanthanide-based MOFs described so far in the literature.
A novel MOF has been synthesized, characterized, and applied in the cyanosilylation of aldehydes and ketones being the first example of an yttrium MOF able to catalyze this reaction. |
| doi_str_mv | 10.1039/d1dt01953h |
| format | Article |
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5
L
6
(OH)
3
(DMF)
3
]·5H
2
O (
1
) (where L = 3-amino-4-hydroxybenzoate) has been prepared by a solvothermal procedure. The structural characterization reveals that this material consists of a robust three-dimensional metal-organic framework (MOF) grown with clusters formed by Y(
iii
) and hydroxide anions joined to one another by the ligand, giving rise to an open structure with interconnected microchannels with variable dimensions. This assembled set has shown to possess a fascinating catalytic activity for the cyanosilylation of a broad range of aldehydes and ketones with exceptional recyclability, a solvent-free medium, and one order of magnitude lower catalyst loading compared to all related lanthanide-based MOFs described so far in the literature.
A novel MOF has been synthesized, characterized, and applied in the cyanosilylation of aldehydes and ketones being the first example of an yttrium MOF able to catalyze this reaction.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d1dt01953h</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Aldehydes ; Catalytic activity ; Chemical synthesis ; Crystallography ; Ethers ; Ketones ; Metal-organic frameworks ; Microchannels ; Recyclability ; Solvents ; Structural analysis ; Yttrium</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2021-09, Vol.5 (34), p.1172-11724</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c314t-4d83bdea07e065db976418f0ae85e3bda2c5a6af7ff5c28c9c7a9595ec34d23b3</citedby><cites>FETCH-LOGICAL-c314t-4d83bdea07e065db976418f0ae85e3bda2c5a6af7ff5c28c9c7a9595ec34d23b3</cites><orcidid>0000-0002-5131-6764 ; 0000-0001-8355-580X ; 0000-0002-0147-1360 ; 0000-0002-6495-2591 ; 0000-0003-3198-5378</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Echenique-Errandonea, Estitxu</creatorcontrib><creatorcontrib>Pérez, Juana M</creatorcontrib><creatorcontrib>Rojas, Sara</creatorcontrib><creatorcontrib>Cepeda, Javier</creatorcontrib><creatorcontrib>Seco, José M</creatorcontrib><creatorcontrib>Fernández, Ignacio</creatorcontrib><creatorcontrib>Rodríguez-Diéguez, Antonio</creatorcontrib><title>A novel yttrium-based metal-organic framework for the efficient solvent-free catalytic synthesis of cyanohydrin silyl ethers</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>A new porous metal-organic framework (MOF) with the chemical formula [Y
5
L
6
(OH)
3
(DMF)
3
]·5H
2
O (
1
) (where L = 3-amino-4-hydroxybenzoate) has been prepared by a solvothermal procedure. The structural characterization reveals that this material consists of a robust three-dimensional metal-organic framework (MOF) grown with clusters formed by Y(
iii
) and hydroxide anions joined to one another by the ligand, giving rise to an open structure with interconnected microchannels with variable dimensions. This assembled set has shown to possess a fascinating catalytic activity for the cyanosilylation of a broad range of aldehydes and ketones with exceptional recyclability, a solvent-free medium, and one order of magnitude lower catalyst loading compared to all related lanthanide-based MOFs described so far in the literature.
A novel MOF has been synthesized, characterized, and applied in the cyanosilylation of aldehydes and ketones being the first example of an yttrium MOF able to catalyze this reaction.</description><subject>Aldehydes</subject><subject>Catalytic activity</subject><subject>Chemical synthesis</subject><subject>Crystallography</subject><subject>Ethers</subject><subject>Ketones</subject><subject>Metal-organic frameworks</subject><subject>Microchannels</subject><subject>Recyclability</subject><subject>Solvents</subject><subject>Structural analysis</subject><subject>Yttrium</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpd0c9LwzAUB_AiCs7pxbsQ8CJCNT-atjkOp04YeJnnkqYvLrNtZpJNCv7xRicTPL3A-7z3At8kOSf4hmAmbhvSBEwEZ8uDZESyokgFZdnh_k3z4-TE-xXGlGJOR8nnBPV2Cy0aQnBm06W19NCgDoJsU-teZW8U0k528GHdG9LWobAEBFobZaAPyNt2G2uqHQBSMo4NIY74oY_OG4-sRmqQvV0OjTM98qYdWgSx6fxpcqRl6-Hst46Tl4f7xd0snT8_Pt1N5qliJAtp1pSsbkDiAnDOm1oUeUZKjSWUHGJHUsVlLnWhNVe0VEIVUnDBQbGsoaxm4-Rqt3ft7PsGfKg64xW0rezBbnxFeSFyykoiIr38R1d24_r4u6jynOI8Ho_qeqeUs9470NXamU66oSK4-g6impLp4ieIWcQXO-y82ru_oNgXLk-IHw</recordid><startdate>20210914</startdate><enddate>20210914</enddate><creator>Echenique-Errandonea, Estitxu</creator><creator>Pérez, Juana M</creator><creator>Rojas, Sara</creator><creator>Cepeda, Javier</creator><creator>Seco, José M</creator><creator>Fernández, Ignacio</creator><creator>Rodríguez-Diéguez, Antonio</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-5131-6764</orcidid><orcidid>https://orcid.org/0000-0001-8355-580X</orcidid><orcidid>https://orcid.org/0000-0002-0147-1360</orcidid><orcidid>https://orcid.org/0000-0002-6495-2591</orcidid><orcidid>https://orcid.org/0000-0003-3198-5378</orcidid></search><sort><creationdate>20210914</creationdate><title>A novel yttrium-based metal-organic framework for the efficient solvent-free catalytic synthesis of cyanohydrin silyl ethers</title><author>Echenique-Errandonea, Estitxu ; Pérez, Juana M ; Rojas, Sara ; Cepeda, Javier ; Seco, José M ; Fernández, Ignacio ; Rodríguez-Diéguez, Antonio</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c314t-4d83bdea07e065db976418f0ae85e3bda2c5a6af7ff5c28c9c7a9595ec34d23b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aldehydes</topic><topic>Catalytic activity</topic><topic>Chemical synthesis</topic><topic>Crystallography</topic><topic>Ethers</topic><topic>Ketones</topic><topic>Metal-organic frameworks</topic><topic>Microchannels</topic><topic>Recyclability</topic><topic>Solvents</topic><topic>Structural analysis</topic><topic>Yttrium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Echenique-Errandonea, Estitxu</creatorcontrib><creatorcontrib>Pérez, Juana M</creatorcontrib><creatorcontrib>Rojas, Sara</creatorcontrib><creatorcontrib>Cepeda, Javier</creatorcontrib><creatorcontrib>Seco, José M</creatorcontrib><creatorcontrib>Fernández, Ignacio</creatorcontrib><creatorcontrib>Rodríguez-Diéguez, Antonio</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Echenique-Errandonea, Estitxu</au><au>Pérez, Juana M</au><au>Rojas, Sara</au><au>Cepeda, Javier</au><au>Seco, José M</au><au>Fernández, Ignacio</au><au>Rodríguez-Diéguez, Antonio</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A novel yttrium-based metal-organic framework for the efficient solvent-free catalytic synthesis of cyanohydrin silyl ethers</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2021-09-14</date><risdate>2021</risdate><volume>5</volume><issue>34</issue><spage>1172</spage><epage>11724</epage><pages>1172-11724</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A new porous metal-organic framework (MOF) with the chemical formula [Y
5
L
6
(OH)
3
(DMF)
3
]·5H
2
O (
1
) (where L = 3-amino-4-hydroxybenzoate) has been prepared by a solvothermal procedure. The structural characterization reveals that this material consists of a robust three-dimensional metal-organic framework (MOF) grown with clusters formed by Y(
iii
) and hydroxide anions joined to one another by the ligand, giving rise to an open structure with interconnected microchannels with variable dimensions. This assembled set has shown to possess a fascinating catalytic activity for the cyanosilylation of a broad range of aldehydes and ketones with exceptional recyclability, a solvent-free medium, and one order of magnitude lower catalyst loading compared to all related lanthanide-based MOFs described so far in the literature.
A novel MOF has been synthesized, characterized, and applied in the cyanosilylation of aldehydes and ketones being the first example of an yttrium MOF able to catalyze this reaction.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1dt01953h</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-5131-6764</orcidid><orcidid>https://orcid.org/0000-0001-8355-580X</orcidid><orcidid>https://orcid.org/0000-0002-0147-1360</orcidid><orcidid>https://orcid.org/0000-0002-6495-2591</orcidid><orcidid>https://orcid.org/0000-0003-3198-5378</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2021-09, Vol.5 (34), p.1172-11724 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Aldehydes Catalytic activity Chemical synthesis Crystallography Ethers Ketones Metal-organic frameworks Microchannels Recyclability Solvents Structural analysis Yttrium |
| title | A novel yttrium-based metal-organic framework for the efficient solvent-free catalytic synthesis of cyanohydrin silyl ethers |
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