Resolvable polymorphism in an intergrowth of two modifications of tris(diethyldithiocarbamato)antimony
Tris(diethyldithiocarbamato‐κS)antimony(III), [Sb(C5H10NS2)3], is tentatively presumed to comprise a triclinic and a monoclinic polymorph intergrown into each other. The geometry in the triclinic phase is a ψ‐capped octahedron and that in the monoclinic phase is a ψ‐pentagonal bipyramid. The study a...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2021-10, Vol.77 (10), p.610-614 |
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| creator | Ng, Seik Weng |
| description | Tris(diethyldithiocarbamato‐κS)antimony(III), [Sb(C5H10NS2)3], is tentatively presumed to comprise a triclinic and a monoclinic polymorph intergrown into each other. The geometry in the triclinic phase is a ψ‐capped octahedron and that in the monoclinic phase is a ψ‐pentagonal bipyramid. The study also identifies the polyhedral symbols for a reported pair of polymorphs of another SbIII coordination compound, as well as for those of published polymorphic modifications of other BiIII and PbII coordination compounds; the symbols in the pair differ in most of these examples. When differentiating related structures of such classes of coordination compounds, lone‐pair stereochemistry may be another informative variable, as stereochemical activity is not always apparent from bond distances and angles only.
Tris(diethyldithiocarbamato)antimony(III), [Sb(C5H10NS2)3], is tentatively presumed to comprise a triclinic and a monoclinic polymorph intergrown into each other. The geometry in the triclinic phase is a ψ‐capped octahedron and that in the monoclinic phase is a ψ‐pentagonal bipyramid. The study also identifies the polyhedral symbols for a reported pair of polymorphs of another SbIII coordination compound, as well as for those of published polymorphic modifications of other BiIII and PbII coordination compounds. |
| doi_str_mv | 10.1107/S205322962100886X |
| format | Article |
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Tris(diethyldithiocarbamato)antimony(III), [Sb(C5H10NS2)3], is tentatively presumed to comprise a triclinic and a monoclinic polymorph intergrown into each other. The geometry in the triclinic phase is a ψ‐capped octahedron and that in the monoclinic phase is a ψ‐pentagonal bipyramid. The study also identifies the polyhedral symbols for a reported pair of polymorphs of another SbIII coordination compound, as well as for those of published polymorphic modifications of other BiIII and PbII coordination compounds.</description><identifier>ISSN: 2053-2296</identifier><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 2053-2296</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S205322962100886X</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: International Union of Crystallography</publisher><subject>allotwin ; Angles (geometry) ; Antimony ; antimony(III) dithiocarbamate ; bismuth(III) ; Coordination compounds ; crystal structure ; lead(II) ; lone‐pair stereochemistry ; polymorph ; Polymorphism ; Stereochemistry ; Symbols</subject><ispartof>Acta crystallographica. Section C, Crystal structure communications, 2021-10, Vol.77 (10), p.610-614</ispartof><rights>2021 Seik Weng Ng. published by IUCr Journals.</rights><rights>Copyright Wiley Subscription Services, Inc. Oct 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3565-223f0507bfde2d005b5d601c07617d2e48d144182de96817a4a8bb8b34ce76cd3</citedby><cites>FETCH-LOGICAL-c3565-223f0507bfde2d005b5d601c07617d2e48d144182de96817a4a8bb8b34ce76cd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1107%2FS205322962100886X$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1107%2FS205322962100886X$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,27913,27914,45563,45564</link.rule.ids></links><search><creatorcontrib>Ng, Seik Weng</creatorcontrib><title>Resolvable polymorphism in an intergrowth of two modifications of tris(diethyldithiocarbamato)antimony</title><title>Acta crystallographica. Section C, Crystal structure communications</title><description>Tris(diethyldithiocarbamato‐κS)antimony(III), [Sb(C5H10NS2)3], is tentatively presumed to comprise a triclinic and a monoclinic polymorph intergrown into each other. The geometry in the triclinic phase is a ψ‐capped octahedron and that in the monoclinic phase is a ψ‐pentagonal bipyramid. The study also identifies the polyhedral symbols for a reported pair of polymorphs of another SbIII coordination compound, as well as for those of published polymorphic modifications of other BiIII and PbII coordination compounds; the symbols in the pair differ in most of these examples. When differentiating related structures of such classes of coordination compounds, lone‐pair stereochemistry may be another informative variable, as stereochemical activity is not always apparent from bond distances and angles only.
Tris(diethyldithiocarbamato)antimony(III), [Sb(C5H10NS2)3], is tentatively presumed to comprise a triclinic and a monoclinic polymorph intergrown into each other. The geometry in the triclinic phase is a ψ‐capped octahedron and that in the monoclinic phase is a ψ‐pentagonal bipyramid. The study also identifies the polyhedral symbols for a reported pair of polymorphs of another SbIII coordination compound, as well as for those of published polymorphic modifications of other BiIII and PbII coordination compounds.</description><subject>allotwin</subject><subject>Angles (geometry)</subject><subject>Antimony</subject><subject>antimony(III) dithiocarbamate</subject><subject>bismuth(III)</subject><subject>Coordination compounds</subject><subject>crystal structure</subject><subject>lead(II)</subject><subject>lone‐pair stereochemistry</subject><subject>polymorph</subject><subject>Polymorphism</subject><subject>Stereochemistry</subject><subject>Symbols</subject><issn>2053-2296</issn><issn>0108-2701</issn><issn>2053-2296</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkM9LwzAUx4MoOOb-AG8FL_MwfUmapj2O4S8YCOpATyVtUpuRNjXJHP3v7TYPogcv7z2-fL6P73sInWO4whj49TMBRgnJEoIB0jR5PUKjnTTbacc_5lM08X4NABgTxjkeoepJeWs-RWFU1FnTN9Z1tfZNpNtItEMNyr07uw11ZKsobG3UWKkrXYqgbev3otN-KrUKdW-kDrW2pXCFaESwl6INurFtf4ZOKmG8mnz3MVrd3rws7mfLx7uHxXw5KylL2JCRVsCAF5VURAKwgskEcAk8wVwSFacSxzFOiVRZkmIuYpEWRVrQuFQ8KSUdo-lhb-fsx0b5kDfal8oY0Sq78flwdUZToAkd0Itf6NpuXDuk21OAMx7DQOEDVTrrvVNV3jndCNfnGPLd8_M_zx882cGz1Ub1_xvy-duCLFYUc0a_ADM6iHM</recordid><startdate>202110</startdate><enddate>202110</enddate><creator>Ng, Seik Weng</creator><general>International Union of Crystallography</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>202110</creationdate><title>Resolvable polymorphism in an intergrowth of two modifications of tris(diethyldithiocarbamato)antimony</title><author>Ng, Seik Weng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3565-223f0507bfde2d005b5d601c07617d2e48d144182de96817a4a8bb8b34ce76cd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>allotwin</topic><topic>Angles (geometry)</topic><topic>Antimony</topic><topic>antimony(III) dithiocarbamate</topic><topic>bismuth(III)</topic><topic>Coordination compounds</topic><topic>crystal structure</topic><topic>lead(II)</topic><topic>lone‐pair stereochemistry</topic><topic>polymorph</topic><topic>Polymorphism</topic><topic>Stereochemistry</topic><topic>Symbols</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ng, Seik Weng</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ng, Seik Weng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Resolvable polymorphism in an intergrowth of two modifications of tris(diethyldithiocarbamato)antimony</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><date>2021-10</date><risdate>2021</risdate><volume>77</volume><issue>10</issue><spage>610</spage><epage>614</epage><pages>610-614</pages><issn>2053-2296</issn><issn>0108-2701</issn><eissn>2053-2296</eissn><eissn>1600-5759</eissn><abstract>Tris(diethyldithiocarbamato‐κS)antimony(III), [Sb(C5H10NS2)3], is tentatively presumed to comprise a triclinic and a monoclinic polymorph intergrown into each other. The geometry in the triclinic phase is a ψ‐capped octahedron and that in the monoclinic phase is a ψ‐pentagonal bipyramid. The study also identifies the polyhedral symbols for a reported pair of polymorphs of another SbIII coordination compound, as well as for those of published polymorphic modifications of other BiIII and PbII coordination compounds; the symbols in the pair differ in most of these examples. When differentiating related structures of such classes of coordination compounds, lone‐pair stereochemistry may be another informative variable, as stereochemical activity is not always apparent from bond distances and angles only.
Tris(diethyldithiocarbamato)antimony(III), [Sb(C5H10NS2)3], is tentatively presumed to comprise a triclinic and a monoclinic polymorph intergrown into each other. The geometry in the triclinic phase is a ψ‐capped octahedron and that in the monoclinic phase is a ψ‐pentagonal bipyramid. The study also identifies the polyhedral symbols for a reported pair of polymorphs of another SbIII coordination compound, as well as for those of published polymorphic modifications of other BiIII and PbII coordination compounds.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><doi>10.1107/S205322962100886X</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 2053-2296 |
| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2021-10, Vol.77 (10), p.610-614 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete; Alma/SFX Local Collection |
| subjects | allotwin Angles (geometry) Antimony antimony(III) dithiocarbamate bismuth(III) Coordination compounds crystal structure lead(II) lone‐pair stereochemistry polymorph Polymorphism Stereochemistry Symbols |
| title | Resolvable polymorphism in an intergrowth of two modifications of tris(diethyldithiocarbamato)antimony |
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