Tunable Synchronicity of Molecular Valence Tautomerism with Macroscopic Solid‐Liquid Transition by Molecular Lattice Engineering

The combination of a cobalt‐dioxolene core that exhibits valence tautomerism (VT) with pyridine‐3,5‐dicarboxylic acid functionalized with chains bearing two, four, or six oxyethylene units led to new complexes ConEGEspy (n = 2, 4, and 6). These complexes commonly form violet crystals of the low‐spin...

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Veröffentlicht in:	Chemistry : a European journal 2021-11, Vol.27 (66), p.16354-16366
Hauptverfasser:	Chida, Mayumi, Takahashi, Satoru, Konishi, Ryunosuke, Matsumoto, Takeshi, Nakada, Akinobu, Wakizaka, Masanori, Kosaka, Wataru, Miyasaka, Hitoshi, Chang, Ho‐Chol
Format:	Artikel
Sprache:	eng
Schlagworte:	cobalt crystal engineering N,O ligands phase transitions valence isomerization
Online-Zugang:	Volltext
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