Enhancement of Electrochromic Switching Properties with Tröger's Base‐Derived Intrinsic Microporous Polyamide Films
The formation of Tröger's Base (TB) configuration is a useful approach to synthesize polymers of intrinsic microporosity (PIM). Herein, the V‐shaped TB scaffold is incorporated to prepare electrochromic (EC) polyamide with electroactive triphenylamine (TPA) moiety. The presence of intrinsic mic...
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| Veröffentlicht in: | Macromolecular rapid communications. 2021-12, Vol.42 (23), p.e2100492-n/a |
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| creator | Pai, Min‐Hao Hu, Chien‐Chieh Liou, Guey‐Sheng |
| description | The formation of Tröger's Base (TB) configuration is a useful approach to synthesize polymers of intrinsic microporosity (PIM). Herein, the V‐shaped TB scaffold is incorporated to prepare electrochromic (EC) polyamide with electroactive triphenylamine (TPA) moiety. The presence of intrinsic microporosity derived from inefficient packing of TB scaffolds can facilitate the counterions diffusion between electroactive species and electrolytes. Consequently, the resulting TB‐based polyamide exhibits enhanced EC behaviors, such as a lower driving potential, reduced the difference of redox potentials ΔE, and shorter switching response time compared to the corresponding EC counterpart polyamide.
The incorporation of rigid and contorted Tröger's Base scaffolds can restrain polymer chains from close packing and further form intrinsic microporosity in the polymer matrix. With the existence of intrinsic microporosity, the diffusion rate of counterions between the electroactive polymer film and electrolyte can be promoted to reduce the oxidation potential and shorten the switching response time. |
| doi_str_mv | 10.1002/marc.202100492 |
| format | Article |
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The incorporation of rigid and contorted Tröger's Base scaffolds can restrain polymer chains from close packing and further form intrinsic microporosity in the polymer matrix. With the existence of intrinsic microporosity, the diffusion rate of counterions between the electroactive polymer film and electrolyte can be promoted to reduce the oxidation potential and shorten the switching response time.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.202100492</identifier><identifier>PMID: 34553802</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Amines ; electrochromic ; Electrochromism ; Electrolytes ; intrinsic microporosity ; Microporosity ; Nylons ; Polyamide resins ; Polyamides ; Polymers ; response capability ; Response time ; Scaffolds ; Species diffusion ; Switching ; Tröger's base</subject><ispartof>Macromolecular rapid communications., 2021-12, Vol.42 (23), p.e2100492-n/a</ispartof><rights>2021 Wiley‐VCH GmbH</rights><rights>2021 Wiley-VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3732-7c8e8b404cc36c0f9e6a09086945060d14b18a69ebdc9d18a48659c1e98b26153</citedby><cites>FETCH-LOGICAL-c3732-7c8e8b404cc36c0f9e6a09086945060d14b18a69ebdc9d18a48659c1e98b26153</cites><orcidid>0000-0003-3725-3768</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmarc.202100492$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmarc.202100492$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/34553802$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Pai, Min‐Hao</creatorcontrib><creatorcontrib>Hu, Chien‐Chieh</creatorcontrib><creatorcontrib>Liou, Guey‐Sheng</creatorcontrib><title>Enhancement of Electrochromic Switching Properties with Tröger's Base‐Derived Intrinsic Microporous Polyamide Films</title><title>Macromolecular rapid communications.</title><addtitle>Macromol Rapid Commun</addtitle><description>The formation of Tröger's Base (TB) configuration is a useful approach to synthesize polymers of intrinsic microporosity (PIM). Herein, the V‐shaped TB scaffold is incorporated to prepare electrochromic (EC) polyamide with electroactive triphenylamine (TPA) moiety. The presence of intrinsic microporosity derived from inefficient packing of TB scaffolds can facilitate the counterions diffusion between electroactive species and electrolytes. Consequently, the resulting TB‐based polyamide exhibits enhanced EC behaviors, such as a lower driving potential, reduced the difference of redox potentials ΔE, and shorter switching response time compared to the corresponding EC counterpart polyamide.
The incorporation of rigid and contorted Tröger's Base scaffolds can restrain polymer chains from close packing and further form intrinsic microporosity in the polymer matrix. With the existence of intrinsic microporosity, the diffusion rate of counterions between the electroactive polymer film and electrolyte can be promoted to reduce the oxidation potential and shorten the switching response time.</description><subject>Amines</subject><subject>electrochromic</subject><subject>Electrochromism</subject><subject>Electrolytes</subject><subject>intrinsic microporosity</subject><subject>Microporosity</subject><subject>Nylons</subject><subject>Polyamide resins</subject><subject>Polyamides</subject><subject>Polymers</subject><subject>response capability</subject><subject>Response time</subject><subject>Scaffolds</subject><subject>Species diffusion</subject><subject>Switching</subject><subject>Tröger's base</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUFOGzEUhi1URCh02yWy1AXdTHi2Zxx7CSG0SCBQS9fWjOeFOJoZB3sSlF2P0NNwAW7Sk9QoQCU2rPxsff-vZ32EfGYwZAD8qC2DHXLg6ZJrvkV2WcFZJjQffUgzcJ4xIeSAfIxxDgAqB75DBiIvCqGA75LVpJuVncUWu576KZ00aPvg7Sz41ln68971dua6W3od_AJD7zDS9DajN-Hx4RbDYaQnZcS_v_-cYnArrOl51wfXxRS-dDaFfPDLSK99sy5bVyM9c00b98n2tGwifno-98ivs8nN-Ht2cfXtfHx8kVkxEjwbWYWqyiG3VkgLU42yBA1K6rwACTXLK6ZKqbGqra7TmCtZaMtQq4pLVog98nXTuwj-bomxN62LFpum7DCtZXgxKpSQmrGEfnmDzv0ydGk7wyUkioOWiRpuqPS1GANOzSK4JGFtGJgnI-bJiHk1kgIHz7XLqsX6FX9RkAC9Ae5dg-t36szl8Y_x__J_v5yZzA</recordid><startdate>202112</startdate><enddate>202112</enddate><creator>Pai, Min‐Hao</creator><creator>Hu, Chien‐Chieh</creator><creator>Liou, Guey‐Sheng</creator><general>Wiley Subscription Services, Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>JQ2</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-3725-3768</orcidid></search><sort><creationdate>202112</creationdate><title>Enhancement of Electrochromic Switching Properties with Tröger's Base‐Derived Intrinsic Microporous Polyamide Films</title><author>Pai, Min‐Hao ; Hu, Chien‐Chieh ; Liou, Guey‐Sheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3732-7c8e8b404cc36c0f9e6a09086945060d14b18a69ebdc9d18a48659c1e98b26153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Amines</topic><topic>electrochromic</topic><topic>Electrochromism</topic><topic>Electrolytes</topic><topic>intrinsic microporosity</topic><topic>Microporosity</topic><topic>Nylons</topic><topic>Polyamide resins</topic><topic>Polyamides</topic><topic>Polymers</topic><topic>response capability</topic><topic>Response time</topic><topic>Scaffolds</topic><topic>Species diffusion</topic><topic>Switching</topic><topic>Tröger's base</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pai, Min‐Hao</creatorcontrib><creatorcontrib>Hu, Chien‐Chieh</creatorcontrib><creatorcontrib>Liou, Guey‐Sheng</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pai, Min‐Hao</au><au>Hu, Chien‐Chieh</au><au>Liou, Guey‐Sheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhancement of Electrochromic Switching Properties with Tröger's Base‐Derived Intrinsic Microporous Polyamide Films</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol Rapid Commun</addtitle><date>2021-12</date><risdate>2021</risdate><volume>42</volume><issue>23</issue><spage>e2100492</spage><epage>n/a</epage><pages>e2100492-n/a</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>The formation of Tröger's Base (TB) configuration is a useful approach to synthesize polymers of intrinsic microporosity (PIM). Herein, the V‐shaped TB scaffold is incorporated to prepare electrochromic (EC) polyamide with electroactive triphenylamine (TPA) moiety. The presence of intrinsic microporosity derived from inefficient packing of TB scaffolds can facilitate the counterions diffusion between electroactive species and electrolytes. Consequently, the resulting TB‐based polyamide exhibits enhanced EC behaviors, such as a lower driving potential, reduced the difference of redox potentials ΔE, and shorter switching response time compared to the corresponding EC counterpart polyamide.
The incorporation of rigid and contorted Tröger's Base scaffolds can restrain polymer chains from close packing and further form intrinsic microporosity in the polymer matrix. With the existence of intrinsic microporosity, the diffusion rate of counterions between the electroactive polymer film and electrolyte can be promoted to reduce the oxidation potential and shorten the switching response time.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>34553802</pmid><doi>10.1002/marc.202100492</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-3725-3768</orcidid></addata></record> |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Amines electrochromic Electrochromism Electrolytes intrinsic microporosity Microporosity Nylons Polyamide resins Polyamides Polymers response capability Response time Scaffolds Species diffusion Switching Tröger's base |
| title | Enhancement of Electrochromic Switching Properties with Tröger's Base‐Derived Intrinsic Microporous Polyamide Films |
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