ION-MOLECULE REACTIONS IN THE SOURCE OF AN ATMOSPHERIC-PRESSURE IONIZATION MASS-SPECTROMETER
Rate equation analysis is performed for the ion-molecule reactions occurring in the source of a corona discharge atmospheric pressure ionization mass spectrometer for the case of bulk nitrogen. The solutions to these equations, together with the model for the space-charge dominated corona discharge...
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Veröffentlicht in: | Journal of the Electrochemical Society 1992-12, Vol.139 (12), p.3675-3678 |
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creator | KETKAR, SN RIDGEWAY, RG DEPINILLOS, JVM |
description | Rate equation analysis is performed for the ion-molecule reactions occurring in the source of a corona discharge atmospheric pressure ionization mass spectrometer for the case of bulk nitrogen. The solutions to these equations, together with the model for the space-charge dominated corona discharge source, are used to elucidate the interference effects that exist when multiple impurities are present. The effect of the discharge current on the response of the atmospheric pressure ionization mass spectrometer is also calculated and compared with experimental results. |
doi_str_mv | 10.1149/1.2069142 |
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The solutions to these equations, together with the model for the space-charge dominated corona discharge source, are used to elucidate the interference effects that exist when multiple impurities are present. The effect of the discharge current on the response of the atmospheric pressure ionization mass spectrometer is also calculated and compared with experimental results.</abstract><cop>PENNINGTON</cop><pub>Electrochemical Soc Inc</pub><doi>10.1149/1.2069142</doi><tpages>4</tpages></addata></record> |
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subjects | Electrochemistry Exact sciences and technology Instruments, apparatus, components and techniques common to several branches of physics and astronomy Mass spectrometers and related techniques Materials Science Materials Science, Coatings & Films Physical Sciences Physics Science & Technology Technology |
title | ION-MOLECULE REACTIONS IN THE SOURCE OF AN ATMOSPHERIC-PRESSURE IONIZATION MASS-SPECTROMETER |
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