Do germanium-based photoinitiators have the potential to replace the well-established acylphosphine oxides?
In the last few decades, there has been an increasing demand for photoinitiators with growing requirements. Nowadays, photoinitiators need to fulfill several requirements such as a low level of toxicity, biocompatibility, fast polymerization rates, high activities, good photobleaching and much more...
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Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2021-09, Vol.5 (36), p.12392-12398 |
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creator | Wiesner, Tanja Haas, Michael |
description | In the last few decades, there has been an increasing demand for photoinitiators with growing requirements. Nowadays, photoinitiators need to fulfill several requirements such as a low level of toxicity, biocompatibility, fast polymerization rates, high activities, good photobleaching and much more in order to remain competitive on the market. Accordingly, we compare acylphosphine oxides and acylgermanes, two common classes of photoinitiators, with respect to their various synthetic pathways, toxicity, availability and performance.
This frontier article highlights the importance of recently developed germanium-based photoinitiators in comparison with acylphosphine oxides. Their synthesis, performance, toxicity and availability are presented with advantages and drawbacks. |
doi_str_mv | 10.1039/d1dt02308j |
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This frontier article highlights the importance of recently developed germanium-based photoinitiators in comparison with acylphosphine oxides. Their synthesis, performance, toxicity and availability are presented with advantages and drawbacks.</description><subject>Biocompatibility</subject><subject>Chemistry</subject><subject>Germanium</subject><subject>Low level</subject><subject>Photoinitiators</subject><subject>Toxicity</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdkc1v1DAQxS0EoqVw4Y4UiQuqFPB34gsV6vKpSlz2bk2c2cZLEgfbKfS_r8tWi-A0o5mfnt7TI-Qlo28ZFeZdz_pMuaDt_hE5ZbJpasOFfHzcuT4hz1LaU8o5VfwpORFSSdUaekp-bEJ1jXGC2a9T3UHCvlqGkIOfffaQQ0zVADdY5QGrJWScy3WscqgiLiO4w-MXjmONKUM3-jQUCXC3Y5FJy-BnrMJv32O6eE6e7GBM-OJhnpHtp4_byy_11ffPXy8_XNVOUpXrrnHQgda9FKblnUGtnWoApUImFW1axxC1cQ50Q8tBgGm1ZDvZGKEEFWfk_UF2WbsJe1csRxjtEv0E8dYG8Pbfz-wHex1ubCuV0EYUgTcPAjH8XEssO_nkSkSYMazJctUUG1QwWdDX_6H7sMa5pLunpObKcF2o8wPlYkgp4u5ohlF7X6HdsM32T4XfCvzqAMfkjtzfisUdHIeYqw</recordid><startdate>20210921</startdate><enddate>20210921</enddate><creator>Wiesner, Tanja</creator><creator>Haas, Michael</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-9213-940X</orcidid></search><sort><creationdate>20210921</creationdate><title>Do germanium-based photoinitiators have the potential to replace the well-established acylphosphine oxides?</title><author>Wiesner, Tanja ; Haas, Michael</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c405t-b7caba66d43982b9e66c57ae45e145078c1ee69cca6704503a98641f47935303</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Biocompatibility</topic><topic>Chemistry</topic><topic>Germanium</topic><topic>Low level</topic><topic>Photoinitiators</topic><topic>Toxicity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wiesner, Tanja</creatorcontrib><creatorcontrib>Haas, Michael</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wiesner, Tanja</au><au>Haas, Michael</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Do germanium-based photoinitiators have the potential to replace the well-established acylphosphine oxides?</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2021-09-21</date><risdate>2021</risdate><volume>5</volume><issue>36</issue><spage>12392</spage><epage>12398</epage><pages>12392-12398</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>In the last few decades, there has been an increasing demand for photoinitiators with growing requirements. Nowadays, photoinitiators need to fulfill several requirements such as a low level of toxicity, biocompatibility, fast polymerization rates, high activities, good photobleaching and much more in order to remain competitive on the market. Accordingly, we compare acylphosphine oxides and acylgermanes, two common classes of photoinitiators, with respect to their various synthetic pathways, toxicity, availability and performance.
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Biocompatibility Chemistry Germanium Low level Photoinitiators Toxicity |
title | Do germanium-based photoinitiators have the potential to replace the well-established acylphosphine oxides? |
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