Do germanium-based photoinitiators have the potential to replace the well-established acylphosphine oxides?

In the last few decades, there has been an increasing demand for photoinitiators with growing requirements. Nowadays, photoinitiators need to fulfill several requirements such as a low level of toxicity, biocompatibility, fast polymerization rates, high activities, good photobleaching and much more...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2021-09, Vol.5 (36), p.12392-12398
Hauptverfasser: Wiesner, Tanja, Haas, Michael
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description In the last few decades, there has been an increasing demand for photoinitiators with growing requirements. Nowadays, photoinitiators need to fulfill several requirements such as a low level of toxicity, biocompatibility, fast polymerization rates, high activities, good photobleaching and much more in order to remain competitive on the market. Accordingly, we compare acylphosphine oxides and acylgermanes, two common classes of photoinitiators, with respect to their various synthetic pathways, toxicity, availability and performance. This frontier article highlights the importance of recently developed germanium-based photoinitiators in comparison with acylphosphine oxides. Their synthesis, performance, toxicity and availability are presented with advantages and drawbacks.
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Biocompatibility
Chemistry
Germanium
Low level
Photoinitiators
Toxicity
title Do germanium-based photoinitiators have the potential to replace the well-established acylphosphine oxides?
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