Metallo-carbohedrenes M8C12+: a class of stable molecular cluster ions

Metallo-carbohedrenes M8C12+: a class of stable molecular cluster ions

Findings of magic peaks corresponding to M8C12(+) (M = V, Zr, and Hf) formed from reactions of the respective metals with various small hydrocarbons, in conjuction with recent findings for the titanium system, establish metallocarbohedrenes as a stable general class of molecular cluster ions. A dode...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 1992-04, Vol.256 (5056), p.515
Hauptverfasser: Guo, B.C, Wei, S, Purnell, J, Buzza, S, Castleman, Jr., A.W
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Organometallic chemistry
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container_issue 5056
container_start_page 515
container_title Science (American Association for the Advancement of Science)
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creator Guo, B.C
Wei, S
Purnell, J
Buzza, S
Castleman, Jr., A.W
description Findings of magic peaks corresponding to M8C12(+) (M = V, Zr, and Hf) formed from reactions of the respective metals with various small hydrocarbons, in conjuction with recent findings for the titanium system, establish metallocarbohedrenes as a stable general class of molecular cluster ions. A dodecahedral structure of T sub h point symmetry accounts for the stability of these ionic clusters. (Author)
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subjects Organometallic chemistry
title Metallo-carbohedrenes M8C12+: a class of stable molecular cluster ions
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