Strategic Construction of Sulfur-Bridged BODIPY Dimers and Oligomers as Heavy-Atom-Free Photosensitizers

Strategic Construction of Sulfur-Bridged BODIPY Dimers and Oligomers as Heavy-Atom-Free Photosensitizers

An efficient strategy for building sulfur-bridged oligo-BODIPYs based on the SNAr reaction is described. These oligo-BODIPYs showed broadband and strong visible-near-infrared (NIR) light absorption, strong intramolecular exciton coupling, and efficient intersystem crossing (ISC). Generation of 1O2 a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2021-09, Vol.23 (18), p.7220-7225
Hauptverfasser: Gong, Qingbao, Wu, Qinghua, Guo, Xing, Li, Wanwan, Wang, Long, Hao, Erhong, Jiao, Lijuan
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 7225
container_issue 18
container_start_page 7220
container_title Organic letters
container_volume 23
creator Gong, Qingbao
Wu, Qinghua
Guo, Xing
Li, Wanwan
Wang, Long
Hao, Erhong
Jiao, Lijuan
description An efficient strategy for building sulfur-bridged oligo-BODIPYs based on the SNAr reaction is described. These oligo-BODIPYs showed broadband and strong visible-near-infrared (NIR) light absorption, strong intramolecular exciton coupling, and efficient intersystem crossing (ISC). Generation of 1O2 as well as O2 •– under irradiation was found to give high reactive oxygen species generation efficiencies for those oligomers.
doi_str_mv 10.1021/acs.orglett.1c02622
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2567983058</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2567983058</sourcerecordid><originalsourceid>FETCH-LOGICAL-a322t-7b586362b2951a3ac2b274f9796d3aea31c480fc9cf1a17d57ab9f0d63c9aedc3</originalsourceid><addsrcrecordid>eNp9kMtOwzAQRS0EEqXwBWy8ZJPWj-bhZR-UVqrUSoUFK8t17NRVEhfbQSpfT6pELFnNnZl7R5oDwDNGI4wIHgvpR9YVpQphhCUiCSE3YIBjQqMUxeT2TyfoHjx4f0IItxM2AMd9cCKowkg4t7UPrpHB2BpaDfdNqRsXzZzJC5XD2Xax3n3ChamU81DUOdyWprBd5-FKie9LNA22ipZOKbg72mC9qr0J5qf1PII7LUqvnvo6BB_L1_f5Ktps39bz6SYSlJAQpYc4S2hCDoTFWFAhW5VONEtZklOhBMVykiEtmdRY4DSPU3FgGuUJlUyoXNIheOnunp39apQPvDJeqrIUtbKN5yROUpZRFGetlXZW6az3Tml-dqYS7sIx4leuvOXKe66859qmxl3qujzZxtXtO_8mfgET44BE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2567983058</pqid></control><display><type>article</type><title>Strategic Construction of Sulfur-Bridged BODIPY Dimers and Oligomers as Heavy-Atom-Free Photosensitizers</title><source>ACS Publications</source><creator>Gong, Qingbao ; Wu, Qinghua ; Guo, Xing ; Li, Wanwan ; Wang, Long ; Hao, Erhong ; Jiao, Lijuan</creator><creatorcontrib>Gong, Qingbao ; Wu, Qinghua ; Guo, Xing ; Li, Wanwan ; Wang, Long ; Hao, Erhong ; Jiao, Lijuan</creatorcontrib><description>An efficient strategy for building sulfur-bridged oligo-BODIPYs based on the SNAr reaction is described. These oligo-BODIPYs showed broadband and strong visible-near-infrared (NIR) light absorption, strong intramolecular exciton coupling, and efficient intersystem crossing (ISC). Generation of 1O2 as well as O2 •– under irradiation was found to give high reactive oxygen species generation efficiencies for those oligomers.</description><identifier>ISSN: 1523-7060</identifier><identifier>EISSN: 1523-7052</identifier><identifier>DOI: 10.1021/acs.orglett.1c02622</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Organic letters, 2021-09, Vol.23 (18), p.7220-7225</ispartof><rights>2021 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a322t-7b586362b2951a3ac2b274f9796d3aea31c480fc9cf1a17d57ab9f0d63c9aedc3</citedby><cites>FETCH-LOGICAL-a322t-7b586362b2951a3ac2b274f9796d3aea31c480fc9cf1a17d57ab9f0d63c9aedc3</cites><orcidid>0000-0001-7234-4994 ; 0000-0002-3895-9642</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.orglett.1c02622$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.orglett.1c02622$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Gong, Qingbao</creatorcontrib><creatorcontrib>Wu, Qinghua</creatorcontrib><creatorcontrib>Guo, Xing</creatorcontrib><creatorcontrib>Li, Wanwan</creatorcontrib><creatorcontrib>Wang, Long</creatorcontrib><creatorcontrib>Hao, Erhong</creatorcontrib><creatorcontrib>Jiao, Lijuan</creatorcontrib><title>Strategic Construction of Sulfur-Bridged BODIPY Dimers and Oligomers as Heavy-Atom-Free Photosensitizers</title><title>Organic letters</title><addtitle>Org. Lett</addtitle><description>An efficient strategy for building sulfur-bridged oligo-BODIPYs based on the SNAr reaction is described. These oligo-BODIPYs showed broadband and strong visible-near-infrared (NIR) light absorption, strong intramolecular exciton coupling, and efficient intersystem crossing (ISC). Generation of 1O2 as well as O2 •– under irradiation was found to give high reactive oxygen species generation efficiencies for those oligomers.</description><issn>1523-7060</issn><issn>1523-7052</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EEqXwBWy8ZJPWj-bhZR-UVqrUSoUFK8t17NRVEhfbQSpfT6pELFnNnZl7R5oDwDNGI4wIHgvpR9YVpQphhCUiCSE3YIBjQqMUxeT2TyfoHjx4f0IItxM2AMd9cCKowkg4t7UPrpHB2BpaDfdNqRsXzZzJC5XD2Xax3n3ChamU81DUOdyWprBd5-FKie9LNA22ipZOKbg72mC9qr0J5qf1PII7LUqvnvo6BB_L1_f5Ktps39bz6SYSlJAQpYc4S2hCDoTFWFAhW5VONEtZklOhBMVykiEtmdRY4DSPU3FgGuUJlUyoXNIheOnunp39apQPvDJeqrIUtbKN5yROUpZRFGetlXZW6az3Tml-dqYS7sIx4leuvOXKe66859qmxl3qujzZxtXtO_8mfgET44BE</recordid><startdate>20210917</startdate><enddate>20210917</enddate><creator>Gong, Qingbao</creator><creator>Wu, Qinghua</creator><creator>Guo, Xing</creator><creator>Li, Wanwan</creator><creator>Wang, Long</creator><creator>Hao, Erhong</creator><creator>Jiao, Lijuan</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-7234-4994</orcidid><orcidid>https://orcid.org/0000-0002-3895-9642</orcidid></search><sort><creationdate>20210917</creationdate><title>Strategic Construction of Sulfur-Bridged BODIPY Dimers and Oligomers as Heavy-Atom-Free Photosensitizers</title><author>Gong, Qingbao ; Wu, Qinghua ; Guo, Xing ; Li, Wanwan ; Wang, Long ; Hao, Erhong ; Jiao, Lijuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a322t-7b586362b2951a3ac2b274f9796d3aea31c480fc9cf1a17d57ab9f0d63c9aedc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gong, Qingbao</creatorcontrib><creatorcontrib>Wu, Qinghua</creatorcontrib><creatorcontrib>Guo, Xing</creatorcontrib><creatorcontrib>Li, Wanwan</creatorcontrib><creatorcontrib>Wang, Long</creatorcontrib><creatorcontrib>Hao, Erhong</creatorcontrib><creatorcontrib>Jiao, Lijuan</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Organic letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gong, Qingbao</au><au>Wu, Qinghua</au><au>Guo, Xing</au><au>Li, Wanwan</au><au>Wang, Long</au><au>Hao, Erhong</au><au>Jiao, Lijuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Strategic Construction of Sulfur-Bridged BODIPY Dimers and Oligomers as Heavy-Atom-Free Photosensitizers</atitle><jtitle>Organic letters</jtitle><addtitle>Org. Lett</addtitle><date>2021-09-17</date><risdate>2021</risdate><volume>23</volume><issue>18</issue><spage>7220</spage><epage>7225</epage><pages>7220-7225</pages><issn>1523-7060</issn><eissn>1523-7052</eissn><abstract>An efficient strategy for building sulfur-bridged oligo-BODIPYs based on the SNAr reaction is described. These oligo-BODIPYs showed broadband and strong visible-near-infrared (NIR) light absorption, strong intramolecular exciton coupling, and efficient intersystem crossing (ISC). Generation of 1O2 as well as O2 •– under irradiation was found to give high reactive oxygen species generation efficiencies for those oligomers.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.orglett.1c02622</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-7234-4994</orcidid><orcidid>https://orcid.org/0000-0002-3895-9642</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1523-7060
ispartof Organic letters, 2021-09, Vol.23 (18), p.7220-7225
issn 1523-7060
1523-7052
language eng
recordid cdi_proquest_miscellaneous_2567983058
source ACS Publications
title Strategic Construction of Sulfur-Bridged BODIPY Dimers and Oligomers as Heavy-Atom-Free Photosensitizers
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T12%3A44%3A25IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Strategic%20Construction%20of%20Sulfur-Bridged%20BODIPY%20Dimers%20and%20Oligomers%20as%20Heavy-Atom-Free%20Photosensitizers&rft.jtitle=Organic%20letters&rft.au=Gong,%20Qingbao&rft.date=2021-09-17&rft.volume=23&rft.issue=18&rft.spage=7220&rft.epage=7225&rft.pages=7220-7225&rft.issn=1523-7060&rft.eissn=1523-7052&rft_id=info:doi/10.1021/acs.orglett.1c02622&rft_dat=%3Cproquest_cross%3E2567983058%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2567983058&rft_id=info:pmid/&rfr_iscdi=true