Molecular Main Group Metal Hydrides

This review serves to document advances in the synthesis, versatile bonding, and reactivity of molecular main group metal hydrides within Groups 1, 2, and 12-16. Particular attention will be given to the emerging use of said hydrides in the rapidly expanding field of Main Group element-mediated cata...

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Veröffentlicht in:Chemical reviews 2021-10, Vol.121 (20), p.12784-12965
Hauptverfasser: Roy, Matthew M D, Omaña, Alvaro A, Wilson, Andrew S S, Hill, Michael S, Aldridge, Simon, Rivard, Eric
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container_issue 20
container_start_page 12784
container_title Chemical reviews
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creator Roy, Matthew M D
Omaña, Alvaro A
Wilson, Andrew S S
Hill, Michael S
Aldridge, Simon
Rivard, Eric
description This review serves to document advances in the synthesis, versatile bonding, and reactivity of molecular main group metal hydrides within Groups 1, 2, and 12-16. Particular attention will be given to the emerging use of said hydrides in the rapidly expanding field of Main Group element-mediated catalysis. While this review is comprehensive in nature, focus will be given to research appearing in the open literature since 2001.
doi_str_mv 10.1021/acs.chemrev.1c00278
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subjects Catalysis
Chemical synthesis
Metal hydrides
Metals
title Molecular Main Group Metal Hydrides
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