Study on the mechanism and kinetics of manganese release from waste manganese ore waste rock under rainfall leaching

Manganese released from the piled manganese ore wastes is a great threat to the local ecosystem and human health. The mechanism and dynamic characteristics of manganese release from the manganese ore wastes were studied based on the static and dynamic experiments. The concentration of manganese in t...

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Veröffentlicht in:Environmental science and pollution research international 2022, Vol.29 (4), p.5541-5551
Hauptverfasser: Wang, Xin, Ren, Bozhi, Zhou, Yingying, Shi, Xiyang
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Ren, Bozhi
Zhou, Yingying
Shi, Xiyang
description Manganese released from the piled manganese ore wastes is a great threat to the local ecosystem and human health. The mechanism and dynamic characteristics of manganese release from the manganese ore wastes were studied based on the static and dynamic experiments. The concentration of manganese in the leaching solution under the intensive state is twice that resulted from the static state; the manganese release from the waste rock increased with the increase of the solid-liquid ratio and reached 922.3 mg/L when the solid-liquid ratio was 1:5. When the particle size of waste rock was less than 180 μm, the release amount of manganese was the largest and reached 491.3 mg/L. When the pH was 7 and the rainfall intensity was 80 mL/h, the increase of leaching time contributed to the rapidly decreased amount of manganese released, and the leaching process reached equilibrium gradually. The cumulative release of manganese increased with the increase of rainfall duration. In the dynamic leaching process, the change of pH and EC of the leachate had nothing to do with the initial pH of leaching agent but has a close relationship with the hydrolysis of minerals in waste. According to the experimental results, it was found that the double constant equation model fitted the kinetic process of release process better. The purpose of this study was to provide a scientific basis for the assessment and control of manganese pollution in soil and groundwater in manganese mining area.
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In the dynamic leaching process, the change of pH and EC of the leachate had nothing to do with the initial pH of leaching agent but has a close relationship with the hydrolysis of minerals in waste. According to the experimental results, it was found that the double constant equation model fitted the kinetic process of release process better. 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In the dynamic leaching process, the change of pH and EC of the leachate had nothing to do with the initial pH of leaching agent but has a close relationship with the hydrolysis of minerals in waste. According to the experimental results, it was found that the double constant equation model fitted the kinetic process of release process better. 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The mechanism and dynamic characteristics of manganese release from the manganese ore wastes were studied based on the static and dynamic experiments. The concentration of manganese in the leaching solution under the intensive state is twice that resulted from the static state; the manganese release from the waste rock increased with the increase of the solid-liquid ratio and reached 922.3 mg/L when the solid-liquid ratio was 1:5. When the particle size of waste rock was less than 180 μm, the release amount of manganese was the largest and reached 491.3 mg/L. When the pH was 7 and the rainfall intensity was 80 mL/h, the increase of leaching time contributed to the rapidly decreased amount of manganese released, and the leaching process reached equilibrium gradually. The cumulative release of manganese increased with the increase of rainfall duration. In the dynamic leaching process, the change of pH and EC of the leachate had nothing to do with the initial pH of leaching agent but has a close relationship with the hydrolysis of minerals in waste. According to the experimental results, it was found that the double constant equation model fitted the kinetic process of release process better. The purpose of this study was to provide a scientific basis for the assessment and control of manganese pollution in soil and groundwater in manganese mining area.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>34424477</pmid><doi>10.1007/s11356-021-16081-w</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-9797-7314</orcidid><oa>free_for_read</oa></addata></record>
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subjects Acid rain
Aquatic Pollution
Atmospheric Protection/Air Quality Control/Air Pollution
Dynamic characteristics
Earth and Environmental Science
Ecosystem
ecosystems
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Environmental science
equations
Experiments
Groundwater
Groundwater mining
human health
Humans
hydrolysis
Kinetics
Laboratories
Leachates
Leaching
Manganese
Manganese ores
Metals
Minerals
Mining
Particle size
pH effects
Pollution control
rain
rain intensity
Rainfall
rainfall duration
Rainfall intensity
Research Article
Rocks
Soil pollution
Waste Water Technology
Wastes
Water Management
Water Pollution Control
title Study on the mechanism and kinetics of manganese release from waste manganese ore waste rock under rainfall leaching
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