Production and properties assessment of biochars from rapeseed and poplar waste biomass for environmental applications in Romania
Biochar obtained by pyrolysis is receiving great research interest as it is perceived to be a renewable resource available for agronomic and environmental applications. Since biochar is a highly heterogeneous material with chemical composition that varies widely depending on feedstock and pyrolysis...
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Veröffentlicht in: | Environmental geochemistry and health 2022-06, Vol.44 (6), p.1683-1696 |
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creator | Gheorghe-Bulmau, Cora Volceanov, Adrian Stanciulescu, Iustina Ionescu, Gabriela Marculescu, Cosmin Radoiu, Marilena |
description | Biochar obtained by pyrolysis is receiving great research interest as it is perceived to be a renewable resource available for agronomic and environmental applications. Since biochar is a highly heterogeneous material with chemical composition that varies widely depending on feedstock and pyrolysis conditions, this study compares the characteristics of biochar produced by pyrolysis at six temperature levels ranging between 300 and 800 °C of two types of biomass,
i.e.
rapeseed straw (RS)—agriculture waste and poplar tree shavings (PP)—forest waste from furniture making. Twelve biochars were generated via pyrolysis under low oxygen conditions of the selected biomasses in an electrically heated batch reactor. To determine how pyrolysis temperature affects the properties of biochars and consequently their possible utilization, physical, chemical, thermal, porosity and EDX analysis were measured for all biochars and for the corresponding feedstocks. SEM images of the biochar revealed that an increase in temperature led to a higher number of pores for PP biochar compared to RS biochar, and that PP biochar pores tended to shrink with temperature. The elemental composition and the pH of biochars were also compared. Based on the experimental results a utilization matrix was designed as to offer indications concerning possible applications of RS and PP biochars in substitution to fossil derived products for soil remediation (
e.g.,
agriculture fertilizers) and in environmental applications (
e.g.,
removal of pollutants).
Graphic abstract |
doi_str_mv | 10.1007/s10653-021-01061-3 |
format | Article |
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i.e.
rapeseed straw (RS)—agriculture waste and poplar tree shavings (PP)—forest waste from furniture making. Twelve biochars were generated via pyrolysis under low oxygen conditions of the selected biomasses in an electrically heated batch reactor. To determine how pyrolysis temperature affects the properties of biochars and consequently their possible utilization, physical, chemical, thermal, porosity and EDX analysis were measured for all biochars and for the corresponding feedstocks. SEM images of the biochar revealed that an increase in temperature led to a higher number of pores for PP biochar compared to RS biochar, and that PP biochar pores tended to shrink with temperature. The elemental composition and the pH of biochars were also compared. Based on the experimental results a utilization matrix was designed as to offer indications concerning possible applications of RS and PP biochars in substitution to fossil derived products for soil remediation (
e.g.,
agriculture fertilizers) and in environmental applications (
e.g.,
removal of pollutants).
Graphic abstract</description><identifier>ISSN: 0269-4042</identifier><identifier>EISSN: 1573-2983</identifier><identifier>DOI: 10.1007/s10653-021-01061-3</identifier><identifier>PMID: 34414519</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Agricultural wastes ; Agriculture ; Agrochemicals ; Batch reactors ; Biomass ; Brassica napus ; Carbon ; Charcoal ; Charcoal - chemistry ; Chemical composition ; Climate change ; Earth and Environmental Science ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental management ; Fertilizers ; Forestry wastes ; Fossils ; Geochemistry ; Original Paper ; Pollutant removal ; Pollutants ; Poplar ; Pores ; Porosity ; Porous materials ; Properties ; Public Health ; Pyrolysis ; Rapeseed ; Raw materials ; Renewable resources ; Resource management ; Romania ; Shavings ; Soil - chemistry ; Soil fertility ; Soil porosity ; Soil remediation ; Soil Science & Conservation ; Temperature ; Terrestrial Pollution ; Thermal utilization</subject><ispartof>Environmental geochemistry and health, 2022-06, Vol.44 (6), p.1683-1696</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021</rights><rights>2021. The Author(s), under exclusive licence to Springer Nature B.V.</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c375t-dc4d92941da67855b555d0485eabddaae1ffae0e6183fce95a322b39a92ea7623</citedby><cites>FETCH-LOGICAL-c375t-dc4d92941da67855b555d0485eabddaae1ffae0e6183fce95a322b39a92ea7623</cites><orcidid>0000-0002-4449-7130 ; 0000-0002-7668-861X ; 0000-0001-9072-2709 ; 0000-0001-5426-4528 ; 0000-0002-3496-5674</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10653-021-01061-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10653-021-01061-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/34414519$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gheorghe-Bulmau, Cora</creatorcontrib><creatorcontrib>Volceanov, Adrian</creatorcontrib><creatorcontrib>Stanciulescu, Iustina</creatorcontrib><creatorcontrib>Ionescu, Gabriela</creatorcontrib><creatorcontrib>Marculescu, Cosmin</creatorcontrib><creatorcontrib>Radoiu, Marilena</creatorcontrib><title>Production and properties assessment of biochars from rapeseed and poplar waste biomass for environmental applications in Romania</title><title>Environmental geochemistry and health</title><addtitle>Environ Geochem Health</addtitle><addtitle>Environ Geochem Health</addtitle><description>Biochar obtained by pyrolysis is receiving great research interest as it is perceived to be a renewable resource available for agronomic and environmental applications. Since biochar is a highly heterogeneous material with chemical composition that varies widely depending on feedstock and pyrolysis conditions, this study compares the characteristics of biochar produced by pyrolysis at six temperature levels ranging between 300 and 800 °C of two types of biomass,
i.e.
rapeseed straw (RS)—agriculture waste and poplar tree shavings (PP)—forest waste from furniture making. Twelve biochars were generated via pyrolysis under low oxygen conditions of the selected biomasses in an electrically heated batch reactor. To determine how pyrolysis temperature affects the properties of biochars and consequently their possible utilization, physical, chemical, thermal, porosity and EDX analysis were measured for all biochars and for the corresponding feedstocks. SEM images of the biochar revealed that an increase in temperature led to a higher number of pores for PP biochar compared to RS biochar, and that PP biochar pores tended to shrink with temperature. The elemental composition and the pH of biochars were also compared. Based on the experimental results a utilization matrix was designed as to offer indications concerning possible applications of RS and PP biochars in substitution to fossil derived products for soil remediation (
e.g.,
agriculture fertilizers) and in environmental applications (
e.g.,
removal of pollutants).
Graphic abstract</description><subject>Agricultural wastes</subject><subject>Agriculture</subject><subject>Agrochemicals</subject><subject>Batch reactors</subject><subject>Biomass</subject><subject>Brassica napus</subject><subject>Carbon</subject><subject>Charcoal</subject><subject>Charcoal - chemistry</subject><subject>Chemical composition</subject><subject>Climate change</subject><subject>Earth and Environmental Science</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental management</subject><subject>Fertilizers</subject><subject>Forestry wastes</subject><subject>Fossils</subject><subject>Geochemistry</subject><subject>Original Paper</subject><subject>Pollutant removal</subject><subject>Pollutants</subject><subject>Poplar</subject><subject>Pores</subject><subject>Porosity</subject><subject>Porous materials</subject><subject>Properties</subject><subject>Public Health</subject><subject>Pyrolysis</subject><subject>Rapeseed</subject><subject>Raw materials</subject><subject>Renewable resources</subject><subject>Resource management</subject><subject>Romania</subject><subject>Shavings</subject><subject>Soil - chemistry</subject><subject>Soil fertility</subject><subject>Soil porosity</subject><subject>Soil remediation</subject><subject>Soil Science & Conservation</subject><subject>Temperature</subject><subject>Terrestrial Pollution</subject><subject>Thermal utilization</subject><issn>0269-4042</issn><issn>1573-2983</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kUuL1jAUhoMozjejf8CFBNy4qebaNksZvAwMKKLrcNqcaoc2qTmt4tJ_bmpHBReuEsjzvifJw9gjKZ5JIZrnJEVtdSWUrETZykrfYSdpG10p1-q77CRU7SojjDpj50Q3QgjXmPY-O9PGSGOlO7Ef73IKW7-OKXKIgS85LZjXEYkDERLNGFeeBt6Nqf8MmfiQ08wzLEiI4cikZYLMvwGtuHNzSfIhZY7x65hT3Ctg4rAs09jDPor4GPn7AsYRHrB7A0yED2_XC_bx1csPl2-q67evry5fXFe9buxahd4Ep5yRAeqmtbaz1gZhWovQhQCAchgABday1UOPzoJWqtMOnEJoaqUv2NOjtzzxy4a0-nmkHqcJIqaNvLK1NsoI7Qr65B_0Jm05ltt5Vddt-WFR60Kpg-pzIso4-CWPM-TvXgq_C_KHIF8E-V-C_B56fFu9dTOGP5HfRgqgD4DKUfyE-e_s_9T-BAJ4nkQ</recordid><startdate>20220601</startdate><enddate>20220601</enddate><creator>Gheorghe-Bulmau, Cora</creator><creator>Volceanov, Adrian</creator><creator>Stanciulescu, Iustina</creator><creator>Ionescu, Gabriela</creator><creator>Marculescu, Cosmin</creator><creator>Radoiu, Marilena</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7ST</scope><scope>7UA</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>H97</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>L.G</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>SOI</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-4449-7130</orcidid><orcidid>https://orcid.org/0000-0002-7668-861X</orcidid><orcidid>https://orcid.org/0000-0001-9072-2709</orcidid><orcidid>https://orcid.org/0000-0001-5426-4528</orcidid><orcidid>https://orcid.org/0000-0002-3496-5674</orcidid></search><sort><creationdate>20220601</creationdate><title>Production and properties assessment of biochars from rapeseed and poplar waste biomass for environmental applications in Romania</title><author>Gheorghe-Bulmau, Cora ; Volceanov, Adrian ; Stanciulescu, Iustina ; Ionescu, Gabriela ; Marculescu, Cosmin ; Radoiu, Marilena</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c375t-dc4d92941da67855b555d0485eabddaae1ffae0e6183fce95a322b39a92ea7623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Agricultural wastes</topic><topic>Agriculture</topic><topic>Agrochemicals</topic><topic>Batch reactors</topic><topic>Biomass</topic><topic>Brassica napus</topic><topic>Carbon</topic><topic>Charcoal</topic><topic>Charcoal - chemistry</topic><topic>Chemical composition</topic><topic>Climate change</topic><topic>Earth and Environmental Science</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental management</topic><topic>Fertilizers</topic><topic>Forestry wastes</topic><topic>Fossils</topic><topic>Geochemistry</topic><topic>Original Paper</topic><topic>Pollutant removal</topic><topic>Pollutants</topic><topic>Poplar</topic><topic>Pores</topic><topic>Porosity</topic><topic>Porous materials</topic><topic>Properties</topic><topic>Public Health</topic><topic>Pyrolysis</topic><topic>Rapeseed</topic><topic>Raw materials</topic><topic>Renewable resources</topic><topic>Resource management</topic><topic>Romania</topic><topic>Shavings</topic><topic>Soil - chemistry</topic><topic>Soil fertility</topic><topic>Soil porosity</topic><topic>Soil remediation</topic><topic>Soil Science & Conservation</topic><topic>Temperature</topic><topic>Terrestrial Pollution</topic><topic>Thermal utilization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gheorghe-Bulmau, Cora</creatorcontrib><creatorcontrib>Volceanov, Adrian</creatorcontrib><creatorcontrib>Stanciulescu, Iustina</creatorcontrib><creatorcontrib>Ionescu, Gabriela</creatorcontrib><creatorcontrib>Marculescu, Cosmin</creatorcontrib><creatorcontrib>Radoiu, Marilena</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Environment Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Public Health Database</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>Environment Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Environmental geochemistry and health</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gheorghe-Bulmau, Cora</au><au>Volceanov, Adrian</au><au>Stanciulescu, Iustina</au><au>Ionescu, Gabriela</au><au>Marculescu, Cosmin</au><au>Radoiu, Marilena</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Production and properties assessment of biochars from rapeseed and poplar waste biomass for environmental applications in Romania</atitle><jtitle>Environmental geochemistry and health</jtitle><stitle>Environ Geochem Health</stitle><addtitle>Environ Geochem Health</addtitle><date>2022-06-01</date><risdate>2022</risdate><volume>44</volume><issue>6</issue><spage>1683</spage><epage>1696</epage><pages>1683-1696</pages><issn>0269-4042</issn><eissn>1573-2983</eissn><abstract>Biochar obtained by pyrolysis is receiving great research interest as it is perceived to be a renewable resource available for agronomic and environmental applications. Since biochar is a highly heterogeneous material with chemical composition that varies widely depending on feedstock and pyrolysis conditions, this study compares the characteristics of biochar produced by pyrolysis at six temperature levels ranging between 300 and 800 °C of two types of biomass,
i.e.
rapeseed straw (RS)—agriculture waste and poplar tree shavings (PP)—forest waste from furniture making. Twelve biochars were generated via pyrolysis under low oxygen conditions of the selected biomasses in an electrically heated batch reactor. To determine how pyrolysis temperature affects the properties of biochars and consequently their possible utilization, physical, chemical, thermal, porosity and EDX analysis were measured for all biochars and for the corresponding feedstocks. SEM images of the biochar revealed that an increase in temperature led to a higher number of pores for PP biochar compared to RS biochar, and that PP biochar pores tended to shrink with temperature. The elemental composition and the pH of biochars were also compared. Based on the experimental results a utilization matrix was designed as to offer indications concerning possible applications of RS and PP biochars in substitution to fossil derived products for soil remediation (
e.g.,
agriculture fertilizers) and in environmental applications (
e.g.,
removal of pollutants).
Graphic abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><pmid>34414519</pmid><doi>10.1007/s10653-021-01061-3</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-4449-7130</orcidid><orcidid>https://orcid.org/0000-0002-7668-861X</orcidid><orcidid>https://orcid.org/0000-0001-9072-2709</orcidid><orcidid>https://orcid.org/0000-0001-5426-4528</orcidid><orcidid>https://orcid.org/0000-0002-3496-5674</orcidid></addata></record> |
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ispartof | Environmental geochemistry and health, 2022-06, Vol.44 (6), p.1683-1696 |
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subjects | Agricultural wastes Agriculture Agrochemicals Batch reactors Biomass Brassica napus Carbon Charcoal Charcoal - chemistry Chemical composition Climate change Earth and Environmental Science Environment Environmental Chemistry Environmental Health Environmental management Fertilizers Forestry wastes Fossils Geochemistry Original Paper Pollutant removal Pollutants Poplar Pores Porosity Porous materials Properties Public Health Pyrolysis Rapeseed Raw materials Renewable resources Resource management Romania Shavings Soil - chemistry Soil fertility Soil porosity Soil remediation Soil Science & Conservation Temperature Terrestrial Pollution Thermal utilization |
title | Production and properties assessment of biochars from rapeseed and poplar waste biomass for environmental applications in Romania |
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