Hydrothermal deposition as a novel method for the preparation of Co–Mn mixed oxide catalysts supported on stainless steel meshes: application to VOC oxidation
The aim of this work was to develop a novel method for the preparation of structured Co–Mn mixed oxide catalysts: deposition on stainless steel meshes by hydrothermal synthesis. The use of meshes enabled the deposition of a thin layer of the active phase, which significantly suppressed the influence...
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| Veröffentlicht in: | Environmental science and pollution research international 2022, Vol.29 (4), p.5172-5183 |
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| creator | Topka, Pavel Jirátová, Květuše Dvořáková, Michaela Balabánová, Jana Koštejn, Martin Kovanda, František |
| description | The aim of this work was to develop a novel method for the preparation of structured Co–Mn mixed oxide catalysts: deposition on stainless steel meshes by hydrothermal synthesis. The use of meshes enabled the deposition of a thin layer of the active phase, which significantly suppressed the influence of internal diffusion. Consequently, the prepared catalysts exhibited from 48 to 114 times higher catalytic activity in ethanol oxidation than the commercial pelleted Co–Mn–Al catalyst. Moreover, we have shown that their catalytic activity correlated with the proportion of surface oxygen vacancies determined by XPS. Finally, the outstanding activity of the catalyst with Co:Mn ratio of 0.5 was ascribed to the mutual effect of high number of oxygen vacancies and exceptional redox properties. |
| doi_str_mv | 10.1007/s11356-021-15906-y |
| format | Article |
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The use of meshes enabled the deposition of a thin layer of the active phase, which significantly suppressed the influence of internal diffusion. Consequently, the prepared catalysts exhibited from 48 to 114 times higher catalytic activity in ethanol oxidation than the commercial pelleted Co–Mn–Al catalyst. Moreover, we have shown that their catalytic activity correlated with the proportion of surface oxygen vacancies determined by XPS. Finally, the outstanding activity of the catalyst with Co:Mn ratio of 0.5 was ascribed to the mutual effect of high number of oxygen vacancies and exceptional redox properties.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-021-15906-y</identifier><identifier>PMID: 34417699</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aluminum ; Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Catalysis ; Catalysts ; Catalytic activity ; Deposition ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental science ; Ethanol ; Manganese ; Oxidation ; Oxidation-Reduction ; Oxides ; Oxygen ; Redox properties ; Research Article ; Stainless Steel ; Stainless steels ; Vacancies ; Volatile Organic Compounds ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Environmental science and pollution research international, 2022, Vol.29 (4), p.5172-5183</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>2021. 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The use of meshes enabled the deposition of a thin layer of the active phase, which significantly suppressed the influence of internal diffusion. Consequently, the prepared catalysts exhibited from 48 to 114 times higher catalytic activity in ethanol oxidation than the commercial pelleted Co–Mn–Al catalyst. Moreover, we have shown that their catalytic activity correlated with the proportion of surface oxygen vacancies determined by XPS. Finally, the outstanding activity of the catalyst with Co:Mn ratio of 0.5 was ascribed to the mutual effect of high number of oxygen vacancies and exceptional redox properties.</description><subject>Aluminum</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Deposition</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental science</subject><subject>Ethanol</subject><subject>Manganese</subject><subject>Oxidation</subject><subject>Oxidation-Reduction</subject><subject>Oxides</subject><subject>Oxygen</subject><subject>Redox properties</subject><subject>Research Article</subject><subject>Stainless Steel</subject><subject>Stainless 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| ispartof | Environmental science and pollution research international, 2022, Vol.29 (4), p.5172-5183 |
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| subjects | Aluminum Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Catalysis Catalysts Catalytic activity Deposition Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Health Environmental science Ethanol Manganese Oxidation Oxidation-Reduction Oxides Oxygen Redox properties Research Article Stainless Steel Stainless steels Vacancies Volatile Organic Compounds Waste Water Technology Water Management Water Pollution Control |
| title | Hydrothermal deposition as a novel method for the preparation of Co–Mn mixed oxide catalysts supported on stainless steel meshes: application to VOC oxidation |
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