Metal‐to‐Ligand Ratio‐Dependent Chemodivergent Asymmetric Synthesis

Chemodivergent asymmetric synthesis was achieved by tuning the metal‐to‐ligand ratio in an organometallic catalytic system. Using N‐(aroyloxy)phthalimide as the precursor of either an oxygen‐centered aroyloxy radical or a nitrogen‐centered phthalimidyl radical, enantioselective oxocyanation or amino...

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