Recent Advances in Plasmonic Photocatalysis Based on TiO2 and Noble Metal Nanoparticles for Energy Conversion, Environmental Remediation, and Organic Synthesis

Plasmonic photocatalysis has emerged as a prominent and growing field. It enables the efficient use of sunlight as an abundant and renewable energy source to drive a myriad of chemical reactions. For instance, plasmonic photocatalysis in materials comprising TiO2 and plasmonic nanoparticles (NPs) enables effective charge carrier separation and the tuning of optical response to longer wavelength regions (visible and near infrared). In fact, TiO2‐based materials and plasmonic effects are at the forefront of heterogeneous photocatalysis, having applications in energy conversion, production of liquid fuels, wastewater treatment, nitrogen fixation, and organic synthesis. This review aims to comprehensively summarize the fundamentals and to provide the guidelines for future work in the field of TiO2‐based plasmonic photocatalysis comprising the above‐mentioned applications. The concepts and state‐of‐the‐art description of important parameters including the formation of Schottky junctions, hot electron generation and transfer, near field electromagnetic enhancement, plasmon resonance energy transfer, scattering, and photothermal heating effects have been covered in this review. Synthetic approaches and the effect of various physicochemical parameters in plasmon‐mediated TiO2‐based materials on performances are discussed. It is envisioned that this review may inspire and provide insights into the rational development of the next generation of TiO2‐based plasmonic photocatalysts with target performances and enhanced selectivities. While photocatalysis has been focused on TiO2‐based materials, the harvesting of plasmonic effects has emerged as an efficient strategy to enhance photocatalytic performances. Therefore, the combination of TiO2 with plasmonic nanoparticles has attracted massive attention. This review covers the fundamentals, recent advances, and representative examples, and provides future guidelines in the field of TiO2‐based plasmonic photocatalysis toward various important molecular transformations.