A determination of the rate constant for the reaction of HOCL with O-atoms at room temperature
A discharge fast flow system with mass spectrometric detection was used to determine the rate constant of the title reaction to be k(1) = (1.3±0.2)×10−13 cm3 molecule−1 s−1. This experimental value is roughly a factor of 20 higher than previously recommended. It is suggested that the title reaction...
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| Veröffentlicht in: | Geophysical research letters 1992-10, Vol.19 (19), p.1935-1937 |
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| container_end_page | 1937 |
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| container_issue | 19 |
| container_start_page | 1935 |
| container_title | Geophysical research letters |
| container_volume | 19 |
| creator | Vogt, Rainer Schindler, Ralph N. |
| description | A discharge fast flow system with mass spectrometric detection was used to determine the rate constant of the title reaction to be k(1) = (1.3±0.2)×10−13 cm3 molecule−1 s−1. This experimental value is roughly a factor of 20 higher than previously recommended. It is suggested that the title reaction should be considered as a removal process in modeling stratospheric HOCl. |
| doi_str_mv | 10.1029/92GL02100 |
| format | Article |
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Res. Lett</addtitle><description>A discharge fast flow system with mass spectrometric detection was used to determine the rate constant of the title reaction to be k(1) = (1.3±0.2)×10−13 cm3 molecule−1 s−1. This experimental value is roughly a factor of 20 higher than previously recommended. It is suggested that the title reaction should be considered as a removal process in modeling stratospheric HOCl.</description><subject>Atmospheric composition. 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| fulltext | fulltext |
| identifier | ISSN: 0094-8276 |
| ispartof | Geophysical research letters, 1992-10, Vol.19 (19), p.1935-1937 |
| issn | 0094-8276 1944-8007 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_25619245 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Atmospheric composition. Chemical and photochemical reactions Earth, ocean, space Exact sciences and technology External geophysics Physics of the high neutral atmosphere |
| title | A determination of the rate constant for the reaction of HOCL with O-atoms at room temperature |
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