A photoelectrochemical aptasensor of ciprofloxacin based on Bi24O31Cl10/BiOCl heterojunction

A photoelectrochemical (PEC) aptasensor was designed and constructed by Bi 24 O 31 Cl 10 /BiOCl heterojunction as a photoelectric active material for realizing the determination of trace ciprofloxacin (CIP) in water. Compared with Bi 24 O 31 Cl 10 , Bi 24 O 31 Cl 10 /BiOCl heterojunction possessed t...

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Veröffentlicht in:Mikrochimica acta (1966) 2021-09, Vol.188 (9), p.289-289, Article 289
Hauptverfasser: Yang, Mengying, Chen, Yun, Yan, Pengcheng, Dong, Jintao, Duan, Wei, Xu, Li, Li, Henan
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container_end_page 289
container_issue 9
container_start_page 289
container_title Mikrochimica acta (1966)
container_volume 188
creator Yang, Mengying
Chen, Yun
Yan, Pengcheng
Dong, Jintao
Duan, Wei
Xu, Li
Li, Henan
description A photoelectrochemical (PEC) aptasensor was designed and constructed by Bi 24 O 31 Cl 10 /BiOCl heterojunction as a photoelectric active material for realizing the determination of trace ciprofloxacin (CIP) in water. Compared with Bi 24 O 31 Cl 10 , Bi 24 O 31 Cl 10 /BiOCl heterojunction possessed the improvement of light harvesting and the enhancement of photocurrent signal. The formation of heterojunction between Bi 24 O 31 Cl 10 and BiOCl can accelerate the transportation efficiency and inhibit the recombination rate of photoinduced carriers. Based on the excellent PEC performance, CIP aptamer was introduced on the modified Bi 24 O 31 Cl 10 /BiOCl/indium tin oxide (ITO) electrode for fabricating a PEC aptasensor. Owing to the combination between aptamer and CIP, CIP-aptamer complex can block the transfer of charge, leading to the reduction of photocurrent response. The PEC aptasensor possessed high sensitivity with a wide detection range (5.0~1.0 × 10 4  ng L −1 ) and a low detection limit (1.67 ng L −1 , S/ N  = 3). The PEC aptasensor with good selectivity and reproducibility has been applied to the determination of CIP in water. Graphical abstract
doi_str_mv 10.1007/s00604-021-04952-5
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Compared with Bi 24 O 31 Cl 10 , Bi 24 O 31 Cl 10 /BiOCl heterojunction possessed the improvement of light harvesting and the enhancement of photocurrent signal. The formation of heterojunction between Bi 24 O 31 Cl 10 and BiOCl can accelerate the transportation efficiency and inhibit the recombination rate of photoinduced carriers. Based on the excellent PEC performance, CIP aptamer was introduced on the modified Bi 24 O 31 Cl 10 /BiOCl/indium tin oxide (ITO) electrode for fabricating a PEC aptasensor. Owing to the combination between aptamer and CIP, CIP-aptamer complex can block the transfer of charge, leading to the reduction of photocurrent response. The PEC aptasensor possessed high sensitivity with a wide detection range (5.0~1.0 × 10 4  ng L −1 ) and a low detection limit (1.67 ng L −1 , S/ N  = 3). The PEC aptasensor with good selectivity and reproducibility has been applied to the determination of CIP in water. 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Compared with Bi 24 O 31 Cl 10 , Bi 24 O 31 Cl 10 /BiOCl heterojunction possessed the improvement of light harvesting and the enhancement of photocurrent signal. The formation of heterojunction between Bi 24 O 31 Cl 10 and BiOCl can accelerate the transportation efficiency and inhibit the recombination rate of photoinduced carriers. Based on the excellent PEC performance, CIP aptamer was introduced on the modified Bi 24 O 31 Cl 10 /BiOCl/indium tin oxide (ITO) electrode for fabricating a PEC aptasensor. Owing to the combination between aptamer and CIP, CIP-aptamer complex can block the transfer of charge, leading to the reduction of photocurrent response. The PEC aptasensor possessed high sensitivity with a wide detection range (5.0~1.0 × 10 4  ng L −1 ) and a low detection limit (1.67 ng L −1 , S/ N  = 3). The PEC aptasensor with good selectivity and reproducibility has been applied to the determination of CIP in water. 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subjects Analytical Chemistry
Antibiotics
Characterization and Evaluation of Materials
Charge transfer
Chemistry
Chemistry and Materials Science
Heterojunctions
Indium tin oxides
Microengineering
Nanochemistry
Nanotechnology
Original Paper
Photoelectric effect
Photoelectric emission
Photoelectricity
Selectivity
title A photoelectrochemical aptasensor of ciprofloxacin based on Bi24O31Cl10/BiOCl heterojunction
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