Arsenic removal characteristics of natural Mn-Fe binary coating on waste filter sand from a water treatment facility

In this study, the arsenic (As) removal characteristics of a Mn–Fe binary coating formed on waste sand filter of an acid mine drainage treatment facility are investigated. Owing to the Mn–Fe binary coating forming on the surfaces of the sand grains, its potential for arsenic removal, particularly As...

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Veröffentlicht in:Environmental science and pollution research international 2022, Vol.29 (2), p.2136-2145
Hauptverfasser: Han, Young-Soo, Kim, Seol-Hee, Jang, Jeong-Yun, Ji, Sangwoo
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Kim, Seol-Hee
Jang, Jeong-Yun
Ji, Sangwoo
description In this study, the arsenic (As) removal characteristics of a Mn–Fe binary coating formed on waste sand filter of an acid mine drainage treatment facility are investigated. Owing to the Mn–Fe binary coating forming on the surfaces of the sand grains, its potential for arsenic removal, particularly As(III), was evaluated and characterized through batch experiments and x-ray absorption spectroscopy. Sorption isotherms reveal that the Mn–Fe binary coating exhibits comparable removal efficiencies for As(III) and As(V) under low initial As concentrations. However, at higher initial As(III) and As(V) concentrations, the As(III) removal efficiency increases because of newly formed active adsorption sites from reductive dissolution of Mn. The oxidation of the As(III) and reduction of the Mn oxide phases are verified through As K-edge and Mn K-edge X-ray absorption near edge fine structure analysis. The outstanding As(III) removal efficiency of the Mn–Fe binary coating suggests synergy of Fe- and Mn-oxides, highlighting a potential application for this coating system. The natural formation of binary coating through acid mine drainage treatment reported in this study indicates that similar coating can form naturally in other environments, thus, providing plausible natural attenuation processes for arsenic immobilization.
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Owing to the Mn–Fe binary coating forming on the surfaces of the sand grains, its potential for arsenic removal, particularly As(III), was evaluated and characterized through batch experiments and x-ray absorption spectroscopy. Sorption isotherms reveal that the Mn–Fe binary coating exhibits comparable removal efficiencies for As(III) and As(V) under low initial As concentrations. However, at higher initial As(III) and As(V) concentrations, the As(III) removal efficiency increases because of newly formed active adsorption sites from reductive dissolution of Mn. The oxidation of the As(III) and reduction of the Mn oxide phases are verified through As K-edge and Mn K-edge X-ray absorption near edge fine structure analysis. The outstanding As(III) removal efficiency of the Mn–Fe binary coating suggests synergy of Fe- and Mn-oxides, highlighting a potential application for this coating system. The natural formation of binary coating through acid mine drainage treatment reported in this study indicates that similar coating can form naturally in other environments, thus, providing plausible natural attenuation processes for arsenic immobilization.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>34363167</pmid><doi>10.1007/s11356-021-15580-0</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-0071-2713</orcidid></addata></record>
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subjects Absorption spectroscopy
Acid mine drainage
Adsorption
Aquatic Pollution
Arsenic
Arsenic removal
Atmospheric Protection/Air Quality Control/Air Pollution
Attenuation
Coating
Coatings
Drainage facilities
Earth and Environmental Science
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Environmental science
Fine structure
Immobilization
Iron
Manganese
Mine drainage
Natural attenuation
Oxidation
Oxidation-Reduction
Oxides
Pollutant removal
Protective coatings
Research Article
Sand
Sand filters
Structural analysis
Ultrastructure
Waste Water Technology
Water Management
Water Pollutants, Chemical - analysis
Water Pollution Control
Water Purification
Water treatment
Water treatment plants
X ray absorption
X-ray absorption spectroscopy
title Arsenic removal characteristics of natural Mn-Fe binary coating on waste filter sand from a water treatment facility
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