Chain conformations and locations of parts of a block polymer in a lamellar structure

The chain conformation and location of parts of a block polymer in a lamellar structure of diblock copolymers of styrene and 2-vinylpyridine were studied by small-angle neutron scattering. It was found that the chain adjacent to the junction between the two blocks is located near the boundary betwee...

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Veröffentlicht in:Macromolecules 1990-10, Vol.23 (20), p.4387-4391
Hauptverfasser: Matsushita, Yushu, Mori, Katsuaki, Saguchi, Ryuichi, Noda, Ichiro, Nagasawa, Mitsuru, Chang, Taihyun, Glinka, Charles J, Han, Charles C
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container_end_page 4391
container_issue 20
container_start_page 4387
container_title Macromolecules
container_volume 23
creator Matsushita, Yushu
Mori, Katsuaki
Saguchi, Ryuichi
Noda, Ichiro
Nagasawa, Mitsuru
Chang, Taihyun
Glinka, Charles J
Han, Charles C
description The chain conformation and location of parts of a block polymer in a lamellar structure of diblock copolymers of styrene and 2-vinylpyridine were studied by small-angle neutron scattering. It was found that the chain adjacent to the junction between the two blocks is located near the boundary between domains and is contracted along the direction parallel to the lamellae to the same extent as a whole block chain with the same molecular weight, while the chain at the free end of the block polymer is located in the middle of domain and is unperturbed. Graphs. 17 ref.--AA
doi_str_mv 10.1021/ma00222a010
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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Structure, morphology and analysis
title Chain conformations and locations of parts of a block polymer in a lamellar structure
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