Abnormal yields of hydrogen and the mechanism of its evolution during cathodic polarization of aluminium

The yield of hydrogen formed during cathodic polarization of aluminium in neutral salt solutions was measured volumetrically as a function of current density and temperature. It was established that at any current density above 0.5 mA cm −2 and at any temperature the yield is larger than 200%; imply...

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Veröffentlicht in:Electrochimica acta 1990-11, Vol.35 (11), p.1743-1746
Hauptverfasser: DESPIC, A. R, RADOSEVIC, J, DABIC, P, KLISKIC, M
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container_title Electrochimica acta
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creator DESPIC, A. R
RADOSEVIC, J
DABIC, P
KLISKIC, M
description The yield of hydrogen formed during cathodic polarization of aluminium in neutral salt solutions was measured volumetrically as a function of current density and temperature. It was established that at any current density above 0.5 mA cm −2 and at any temperature the yield is larger than 200%; implying that a simultaneous dissolution of aluminium is an inherent part of the cathodic process.
doi_str_mv 10.1016/0013-4686(90)87074-C
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source Elsevier ScienceDirect Journals
subjects Adsorption
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
hydrogen evolution cathodic polarization of aluminium
Study of interfaces
title Abnormal yields of hydrogen and the mechanism of its evolution during cathodic polarization of aluminium
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