Quantum Dot Photocatalysts for Organic Transformations

Quantum dots (QDs) with tunable photo-optical properties and colloidal nature are ideal for a wide range of photocatalytic reactions. In particular, QD photocatalysts for organic transformations can provide new and effective synthetic routes to high value-added molecules under mild conditions. In th...

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Veröffentlicht in:The journal of physical chemistry letters 2021-08, Vol.12 (30), p.7180-7193
Hauptverfasser: Yuan, Yucheng, Jin, Na, Saghy, Peter, Dube, Lacie, Zhu, Hua, Chen, Ou
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container_issue 30
container_start_page 7180
container_title The journal of physical chemistry letters
container_volume 12
creator Yuan, Yucheng
Jin, Na
Saghy, Peter
Dube, Lacie
Zhu, Hua
Chen, Ou
description Quantum dots (QDs) with tunable photo-optical properties and colloidal nature are ideal for a wide range of photocatalytic reactions. In particular, QD photocatalysts for organic transformations can provide new and effective synthetic routes to high value-added molecules under mild conditions. In this Perspective, we discuss the advances of employing QDs for visible-light-driven organic transformations categorized into net reductive reactions, net oxidative reactions, and redox neutral reactions. We then provide our outlook for potential future directions in the field: nanostructure engineering to improve charge separation efficiencies, ligand shell engineering to optimize overall catalyst performance, in situ comprehensive studies to delineate underlying reaction mechanisms, and laboratory automation with the assistance of modern computing techniques to revolutionize the reaction optimization process.
doi_str_mv 10.1021/acs.jpclett.1c01717
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