Synthesis of natural products containing highly strained trans -fused bicyclo[3.3.0]octane: historical overview and future prospects
Owing to high strain energy, molecules with trans -fused bicyclo[3.3.0]octane ring systems are very difficult to synthesize, and there are very few approaches to access them. Recently, a number of natural products with such ring systems have been made by the synthetic community. However, there has b...
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| Veröffentlicht in: | Chemical Society reviews 2021-09, Vol.50 (17), p.9430-9442 |
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| container_title | Chemical Society reviews |
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| creator | Zhang, Wen Li, Lingzi Li, Chuang-Chuang |
| description | Owing to high strain energy, molecules with
trans
-fused bicyclo[3.3.0]octane ring systems are very difficult to synthesize, and there are very few approaches to access them. Recently, a number of natural products with such ring systems have been made by the synthetic community. However, there has been no review in this field before. This review provides a systematic and comprehensive discussion on the synthesis of natural products containing
trans
-fused bicyclo[3.3.0]octanes and the historical context of this work. The prospects for future research in this field are also discussed. Covering the literature before 2021, this review aims to offer a helpful reference for total synthesis of highly strained natural products containing
trans
-fused bicyclo[3.3.0]octane ring systems. |
| doi_str_mv | 10.1039/d0cs01471k |
| format | Article |
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trans
-fused bicyclo[3.3.0]octane ring systems are very difficult to synthesize, and there are very few approaches to access them. Recently, a number of natural products with such ring systems have been made by the synthetic community. However, there has been no review in this field before. This review provides a systematic and comprehensive discussion on the synthesis of natural products containing
trans
-fused bicyclo[3.3.0]octanes and the historical context of this work. The prospects for future research in this field are also discussed. Covering the literature before 2021, this review aims to offer a helpful reference for total synthesis of highly strained natural products containing
trans
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trans
-fused bicyclo[3.3.0]octane ring systems are very difficult to synthesize, and there are very few approaches to access them. Recently, a number of natural products with such ring systems have been made by the synthetic community. However, there has been no review in this field before. This review provides a systematic and comprehensive discussion on the synthesis of natural products containing
trans
-fused bicyclo[3.3.0]octanes and the historical context of this work. The prospects for future research in this field are also discussed. Covering the literature before 2021, this review aims to offer a helpful reference for total synthesis of highly strained natural products containing
trans
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trans
-fused bicyclo[3.3.0]octane ring systems are very difficult to synthesize, and there are very few approaches to access them. Recently, a number of natural products with such ring systems have been made by the synthetic community. However, there has been no review in this field before. This review provides a systematic and comprehensive discussion on the synthesis of natural products containing
trans
-fused bicyclo[3.3.0]octanes and the historical context of this work. The prospects for future research in this field are also discussed. Covering the literature before 2021, this review aims to offer a helpful reference for total synthesis of highly strained natural products containing
trans
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| ispartof | Chemical Society reviews, 2021-09, Vol.50 (17), p.9430-9442 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Literature reviews Natural products Octanes Synthesis |
| title | Synthesis of natural products containing highly strained trans -fused bicyclo[3.3.0]octane: historical overview and future prospects |
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