Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer
The diverse morphing behaviors of living creatures arise from their unlimited pathways. In contrast, the equilibrium‐driven morphing pathways of common synthetic shape‐shifting materials are very limited. For a shape‐memory polymer (SMP), its recovery from the temporary shape(s) to the permanent sha...
Gespeichert in:
Veröffentlicht in: | Advanced materials (Weinheim) 2021-08, Vol.33 (34), p.e2102473-n/a |
---|---|
Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | n/a |
---|---|
container_issue | 34 |
container_start_page | e2102473 |
container_title | Advanced materials (Weinheim) |
container_volume | 33 |
creator | Peng, Wenjun Zhang, Guogao Zhao, Qian Xie, Tao |
description | The diverse morphing behaviors of living creatures arise from their unlimited pathways. In contrast, the equilibrium‐driven morphing pathways of common synthetic shape‐shifting materials are very limited. For a shape‐memory polymer (SMP), its recovery from the temporary shape(s) to the permanent shape typically requires external stimulation and follows a single fixed route. Herein, a covalently crosslinked SMP is designed with ample ureidopyrimidinone (UPy) supramolecular moieties in the network. The UPy units endow the SMP with strong time–temperature dependency, which is explored as a mechanism for spatio‐temporal programming of autonomous shape‐shifting pathways. In particular, the use of digitally controlled photothermal heating provides versatility in control via an off‐equilibrium mechanism. In addition, cooling/heating across its glass transition introduces a locking/unlocking mechanism for its temporal morphing. The benefits of these unique features are demonstrated by multi‐shape‐transformation, an “invisible”‐color‐based clock, a time–temperature indicator, and sequence‐programmable 4D printing.
Highly designable autonomous morphing behaviors are achieved in a supramolecular shape‐memory polymer with strong time–temperature dependency. To prove the advantages of the molecular design, the benefits of the spatio‐temporal programming are demonstrated by off‐equilibrium multi‐shape‐transformation, self‐evolving sequence‐programmable 4D printing, an “invisible”‐color‐based clock, and a time–temperature indicator. |
doi_str_mv | 10.1002/adma.202102473 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2553234132</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2553234132</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3733-4f6260aba17cdd2bd6c2ec2a8b1d081b3c8a6060099412b2b535de297c532c373</originalsourceid><addsrcrecordid>eNqFkLtOwzAUhi0EoqWwMiJLLCwpvuQ6RlAuUqtWKgxMkeM4NFUcp3atKhuPwDPyJLhqKRILy_Hyne_8_gG4xGiIESK3rJBsSBDBiPgRPQJ9HBDs-SgJjkEfJTTwktCPe-DMmCVCKAlReAp61CdRHBLaB2-pXatGSWUNnJbl18fnaGWrusp1ZSWcKN0uquYdzth6sWGdgaqEDM5tq5lUteC2ZhrOF6wVbnMipNIdnKm6k0Kfg5OS1UZc7N8BeH0Yvdw9eePp4_NdOvY4jSj1_DIkIWI5wxEvCpIXISeCExbnuEAxzimPmQvtoic-JjnJAxoUgiQRDyjZKgbgZudttVpZYdaZrAwXdc0a4X6VkcCB1MduDMD1H3SprG5cOkeFvruBk9hRwx3FtTJGizJrdSWZ7jKMsm3p2bb07FC6W7jaa20uRXHAf1p2QLIDNlUtun90WXo_SX_l37jhj3Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2564009198</pqid></control><display><type>article</type><title>Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer</title><source>MEDLINE</source><source>Wiley Online Library Journals Frontfile Complete</source><creator>Peng, Wenjun ; Zhang, Guogao ; Zhao, Qian ; Xie, Tao</creator><creatorcontrib>Peng, Wenjun ; Zhang, Guogao ; Zhao, Qian ; Xie, Tao</creatorcontrib><description>The diverse morphing behaviors of living creatures arise from their unlimited pathways. In contrast, the equilibrium‐driven morphing pathways of common synthetic shape‐shifting materials are very limited. For a shape‐memory polymer (SMP), its recovery from the temporary shape(s) to the permanent shape typically requires external stimulation and follows a single fixed route. Herein, a covalently crosslinked SMP is designed with ample ureidopyrimidinone (UPy) supramolecular moieties in the network. The UPy units endow the SMP with strong time–temperature dependency, which is explored as a mechanism for spatio‐temporal programming of autonomous shape‐shifting pathways. In particular, the use of digitally controlled photothermal heating provides versatility in control via an off‐equilibrium mechanism. In addition, cooling/heating across its glass transition introduces a locking/unlocking mechanism for its temporal morphing. The benefits of these unique features are demonstrated by multi‐shape‐transformation, an “invisible”‐color‐based clock, a time–temperature indicator, and sequence‐programmable 4D printing.
Highly designable autonomous morphing behaviors are achieved in a supramolecular shape‐memory polymer with strong time–temperature dependency. To prove the advantages of the molecular design, the benefits of the spatio‐temporal programming are demonstrated by off‐equilibrium multi‐shape‐transformation, self‐evolving sequence‐programmable 4D printing, an “invisible”‐color‐based clock, and a time–temperature indicator.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.202102473</identifier><identifier>PMID: 34278623</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>4D printing ; Cross-Linking Reagents - chemistry ; Equilibrium ; Glass transition ; Heating ; Hydrogen - chemistry ; Infrared Rays ; Kinetics ; Locking ; Magnetic Resonance Spectroscopy ; Materials science ; Materials Testing ; Morphing ; Phase Transition ; Polymers ; Polymers - chemistry ; Printing, Three-Dimensional ; Shape memory ; shape‐memory polymers ; Smart Materials ; Spectrophotometry ; Stress, Mechanical ; supramolecular bonds ; Temperature ; Temperature dependence ; Tensile Strength ; Time dependence ; Time Factors ; time–temperature indicators ; ureidopyrimidinone</subject><ispartof>Advanced materials (Weinheim), 2021-08, Vol.33 (34), p.e2102473-n/a</ispartof><rights>2021 Wiley‐VCH GmbH</rights><rights>2021 Wiley-VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3733-4f6260aba17cdd2bd6c2ec2a8b1d081b3c8a6060099412b2b535de297c532c373</citedby><cites>FETCH-LOGICAL-c3733-4f6260aba17cdd2bd6c2ec2a8b1d081b3c8a6060099412b2b535de297c532c373</cites><orcidid>0000-0003-0222-9717</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadma.202102473$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadma.202102473$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/34278623$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Peng, Wenjun</creatorcontrib><creatorcontrib>Zhang, Guogao</creatorcontrib><creatorcontrib>Zhao, Qian</creatorcontrib><creatorcontrib>Xie, Tao</creatorcontrib><title>Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer</title><title>Advanced materials (Weinheim)</title><addtitle>Adv Mater</addtitle><description>The diverse morphing behaviors of living creatures arise from their unlimited pathways. In contrast, the equilibrium‐driven morphing pathways of common synthetic shape‐shifting materials are very limited. For a shape‐memory polymer (SMP), its recovery from the temporary shape(s) to the permanent shape typically requires external stimulation and follows a single fixed route. Herein, a covalently crosslinked SMP is designed with ample ureidopyrimidinone (UPy) supramolecular moieties in the network. The UPy units endow the SMP with strong time–temperature dependency, which is explored as a mechanism for spatio‐temporal programming of autonomous shape‐shifting pathways. In particular, the use of digitally controlled photothermal heating provides versatility in control via an off‐equilibrium mechanism. In addition, cooling/heating across its glass transition introduces a locking/unlocking mechanism for its temporal morphing. The benefits of these unique features are demonstrated by multi‐shape‐transformation, an “invisible”‐color‐based clock, a time–temperature indicator, and sequence‐programmable 4D printing.
Highly designable autonomous morphing behaviors are achieved in a supramolecular shape‐memory polymer with strong time–temperature dependency. To prove the advantages of the molecular design, the benefits of the spatio‐temporal programming are demonstrated by off‐equilibrium multi‐shape‐transformation, self‐evolving sequence‐programmable 4D printing, an “invisible”‐color‐based clock, and a time–temperature indicator.</description><subject>4D printing</subject><subject>Cross-Linking Reagents - chemistry</subject><subject>Equilibrium</subject><subject>Glass transition</subject><subject>Heating</subject><subject>Hydrogen - chemistry</subject><subject>Infrared Rays</subject><subject>Kinetics</subject><subject>Locking</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Materials science</subject><subject>Materials Testing</subject><subject>Morphing</subject><subject>Phase Transition</subject><subject>Polymers</subject><subject>Polymers - chemistry</subject><subject>Printing, Three-Dimensional</subject><subject>Shape memory</subject><subject>shape‐memory polymers</subject><subject>Smart Materials</subject><subject>Spectrophotometry</subject><subject>Stress, Mechanical</subject><subject>supramolecular bonds</subject><subject>Temperature</subject><subject>Temperature dependence</subject><subject>Tensile Strength</subject><subject>Time dependence</subject><subject>Time Factors</subject><subject>time–temperature indicators</subject><subject>ureidopyrimidinone</subject><issn>0935-9648</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkLtOwzAUhi0EoqWwMiJLLCwpvuQ6RlAuUqtWKgxMkeM4NFUcp3atKhuPwDPyJLhqKRILy_Hyne_8_gG4xGiIESK3rJBsSBDBiPgRPQJ9HBDs-SgJjkEfJTTwktCPe-DMmCVCKAlReAp61CdRHBLaB2-pXatGSWUNnJbl18fnaGWrusp1ZSWcKN0uquYdzth6sWGdgaqEDM5tq5lUteC2ZhrOF6wVbnMipNIdnKm6k0Kfg5OS1UZc7N8BeH0Yvdw9eePp4_NdOvY4jSj1_DIkIWI5wxEvCpIXISeCExbnuEAxzimPmQvtoic-JjnJAxoUgiQRDyjZKgbgZudttVpZYdaZrAwXdc0a4X6VkcCB1MduDMD1H3SprG5cOkeFvruBk9hRwx3FtTJGizJrdSWZ7jKMsm3p2bb07FC6W7jaa20uRXHAf1p2QLIDNlUtun90WXo_SX_l37jhj3Q</recordid><startdate>20210801</startdate><enddate>20210801</enddate><creator>Peng, Wenjun</creator><creator>Zhang, Guogao</creator><creator>Zhao, Qian</creator><creator>Xie, Tao</creator><general>Wiley Subscription Services, Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-0222-9717</orcidid></search><sort><creationdate>20210801</creationdate><title>Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer</title><author>Peng, Wenjun ; Zhang, Guogao ; Zhao, Qian ; Xie, Tao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3733-4f6260aba17cdd2bd6c2ec2a8b1d081b3c8a6060099412b2b535de297c532c373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>4D printing</topic><topic>Cross-Linking Reagents - chemistry</topic><topic>Equilibrium</topic><topic>Glass transition</topic><topic>Heating</topic><topic>Hydrogen - chemistry</topic><topic>Infrared Rays</topic><topic>Kinetics</topic><topic>Locking</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Materials science</topic><topic>Materials Testing</topic><topic>Morphing</topic><topic>Phase Transition</topic><topic>Polymers</topic><topic>Polymers - chemistry</topic><topic>Printing, Three-Dimensional</topic><topic>Shape memory</topic><topic>shape‐memory polymers</topic><topic>Smart Materials</topic><topic>Spectrophotometry</topic><topic>Stress, Mechanical</topic><topic>supramolecular bonds</topic><topic>Temperature</topic><topic>Temperature dependence</topic><topic>Tensile Strength</topic><topic>Time dependence</topic><topic>Time Factors</topic><topic>time–temperature indicators</topic><topic>ureidopyrimidinone</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Peng, Wenjun</creatorcontrib><creatorcontrib>Zhang, Guogao</creatorcontrib><creatorcontrib>Zhao, Qian</creatorcontrib><creatorcontrib>Xie, Tao</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Advanced materials (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Peng, Wenjun</au><au>Zhang, Guogao</au><au>Zhao, Qian</au><au>Xie, Tao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer</atitle><jtitle>Advanced materials (Weinheim)</jtitle><addtitle>Adv Mater</addtitle><date>2021-08-01</date><risdate>2021</risdate><volume>33</volume><issue>34</issue><spage>e2102473</spage><epage>n/a</epage><pages>e2102473-n/a</pages><issn>0935-9648</issn><eissn>1521-4095</eissn><abstract>The diverse morphing behaviors of living creatures arise from their unlimited pathways. In contrast, the equilibrium‐driven morphing pathways of common synthetic shape‐shifting materials are very limited. For a shape‐memory polymer (SMP), its recovery from the temporary shape(s) to the permanent shape typically requires external stimulation and follows a single fixed route. Herein, a covalently crosslinked SMP is designed with ample ureidopyrimidinone (UPy) supramolecular moieties in the network. The UPy units endow the SMP with strong time–temperature dependency, which is explored as a mechanism for spatio‐temporal programming of autonomous shape‐shifting pathways. In particular, the use of digitally controlled photothermal heating provides versatility in control via an off‐equilibrium mechanism. In addition, cooling/heating across its glass transition introduces a locking/unlocking mechanism for its temporal morphing. The benefits of these unique features are demonstrated by multi‐shape‐transformation, an “invisible”‐color‐based clock, a time–temperature indicator, and sequence‐programmable 4D printing.
Highly designable autonomous morphing behaviors are achieved in a supramolecular shape‐memory polymer with strong time–temperature dependency. To prove the advantages of the molecular design, the benefits of the spatio‐temporal programming are demonstrated by off‐equilibrium multi‐shape‐transformation, self‐evolving sequence‐programmable 4D printing, an “invisible”‐color‐based clock, and a time–temperature indicator.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>34278623</pmid><doi>10.1002/adma.202102473</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-0222-9717</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0935-9648 |
ispartof | Advanced materials (Weinheim), 2021-08, Vol.33 (34), p.e2102473-n/a |
issn | 0935-9648 1521-4095 |
language | eng |
recordid | cdi_proquest_miscellaneous_2553234132 |
source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
subjects | 4D printing Cross-Linking Reagents - chemistry Equilibrium Glass transition Heating Hydrogen - chemistry Infrared Rays Kinetics Locking Magnetic Resonance Spectroscopy Materials science Materials Testing Morphing Phase Transition Polymers Polymers - chemistry Printing, Three-Dimensional Shape memory shape‐memory polymers Smart Materials Spectrophotometry Stress, Mechanical supramolecular bonds Temperature Temperature dependence Tensile Strength Time dependence Time Factors time–temperature indicators ureidopyrimidinone |
title | Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-18T12%3A40%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Autonomous%20Off%E2%80%90Equilibrium%20Morphing%20Pathways%20of%20a%20Supramolecular%20Shape%E2%80%90Memory%20Polymer&rft.jtitle=Advanced%20materials%20(Weinheim)&rft.au=Peng,%20Wenjun&rft.date=2021-08-01&rft.volume=33&rft.issue=34&rft.spage=e2102473&rft.epage=n/a&rft.pages=e2102473-n/a&rft.issn=0935-9648&rft.eissn=1521-4095&rft_id=info:doi/10.1002/adma.202102473&rft_dat=%3Cproquest_cross%3E2553234132%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2564009198&rft_id=info:pmid/34278623&rfr_iscdi=true |