Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer

The diverse morphing behaviors of living creatures arise from their unlimited pathways. In contrast, the equilibrium‐driven morphing pathways of common synthetic shape‐shifting materials are very limited. For a shape‐memory polymer (SMP), its recovery from the temporary shape(s) to the permanent sha...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Weinheim) 2021-08, Vol.33 (34), p.e2102473-n/a
Hauptverfasser: Peng, Wenjun, Zhang, Guogao, Zhao, Qian, Xie, Tao
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page n/a
container_issue 34
container_start_page e2102473
container_title Advanced materials (Weinheim)
container_volume 33
creator Peng, Wenjun
Zhang, Guogao
Zhao, Qian
Xie, Tao
description The diverse morphing behaviors of living creatures arise from their unlimited pathways. In contrast, the equilibrium‐driven morphing pathways of common synthetic shape‐shifting materials are very limited. For a shape‐memory polymer (SMP), its recovery from the temporary shape(s) to the permanent shape typically requires external stimulation and follows a single fixed route. Herein, a covalently crosslinked SMP is designed with ample ureidopyrimidinone (UPy) supramolecular moieties in the network. The UPy units endow the SMP with strong time–temperature dependency, which is explored as a mechanism for spatio‐temporal programming of autonomous shape‐shifting pathways. In particular, the use of digitally controlled photothermal heating provides versatility in control via an off‐equilibrium mechanism. In addition, cooling/heating across its glass transition introduces a locking/unlocking mechanism for its temporal morphing. The benefits of these unique features are demonstrated by multi‐shape‐transformation, an “invisible”‐color‐based clock, a time–temperature indicator, and sequence‐programmable 4D printing. Highly designable autonomous morphing behaviors are achieved in a supramolecular shape‐memory polymer with strong time–temperature dependency. To prove the advantages of the molecular design, the benefits of the spatio‐temporal programming are demonstrated by off‐equilibrium multi‐shape‐transformation, self‐evolving sequence‐programmable 4D printing, an “invisible”‐color‐based clock, and a time–temperature indicator.
doi_str_mv 10.1002/adma.202102473
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2553234132</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2553234132</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3733-4f6260aba17cdd2bd6c2ec2a8b1d081b3c8a6060099412b2b535de297c532c373</originalsourceid><addsrcrecordid>eNqFkLtOwzAUhi0EoqWwMiJLLCwpvuQ6RlAuUqtWKgxMkeM4NFUcp3atKhuPwDPyJLhqKRILy_Hyne_8_gG4xGiIESK3rJBsSBDBiPgRPQJ9HBDs-SgJjkEfJTTwktCPe-DMmCVCKAlReAp61CdRHBLaB2-pXatGSWUNnJbl18fnaGWrusp1ZSWcKN0uquYdzth6sWGdgaqEDM5tq5lUteC2ZhrOF6wVbnMipNIdnKm6k0Kfg5OS1UZc7N8BeH0Yvdw9eePp4_NdOvY4jSj1_DIkIWI5wxEvCpIXISeCExbnuEAxzimPmQvtoic-JjnJAxoUgiQRDyjZKgbgZudttVpZYdaZrAwXdc0a4X6VkcCB1MduDMD1H3SprG5cOkeFvruBk9hRwx3FtTJGizJrdSWZ7jKMsm3p2bb07FC6W7jaa20uRXHAf1p2QLIDNlUtun90WXo_SX_l37jhj3Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2564009198</pqid></control><display><type>article</type><title>Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer</title><source>MEDLINE</source><source>Wiley Online Library Journals Frontfile Complete</source><creator>Peng, Wenjun ; Zhang, Guogao ; Zhao, Qian ; Xie, Tao</creator><creatorcontrib>Peng, Wenjun ; Zhang, Guogao ; Zhao, Qian ; Xie, Tao</creatorcontrib><description>The diverse morphing behaviors of living creatures arise from their unlimited pathways. In contrast, the equilibrium‐driven morphing pathways of common synthetic shape‐shifting materials are very limited. For a shape‐memory polymer (SMP), its recovery from the temporary shape(s) to the permanent shape typically requires external stimulation and follows a single fixed route. Herein, a covalently crosslinked SMP is designed with ample ureidopyrimidinone (UPy) supramolecular moieties in the network. The UPy units endow the SMP with strong time–temperature dependency, which is explored as a mechanism for spatio‐temporal programming of autonomous shape‐shifting pathways. In particular, the use of digitally controlled photothermal heating provides versatility in control via an off‐equilibrium mechanism. In addition, cooling/heating across its glass transition introduces a locking/unlocking mechanism for its temporal morphing. The benefits of these unique features are demonstrated by multi‐shape‐transformation, an “invisible”‐color‐based clock, a time–temperature indicator, and sequence‐programmable 4D printing. Highly designable autonomous morphing behaviors are achieved in a supramolecular shape‐memory polymer with strong time–temperature dependency. To prove the advantages of the molecular design, the benefits of the spatio‐temporal programming are demonstrated by off‐equilibrium multi‐shape‐transformation, self‐evolving sequence‐programmable 4D printing, an “invisible”‐color‐based clock, and a time–temperature indicator.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.202102473</identifier><identifier>PMID: 34278623</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>4D printing ; Cross-Linking Reagents - chemistry ; Equilibrium ; Glass transition ; Heating ; Hydrogen - chemistry ; Infrared Rays ; Kinetics ; Locking ; Magnetic Resonance Spectroscopy ; Materials science ; Materials Testing ; Morphing ; Phase Transition ; Polymers ; Polymers - chemistry ; Printing, Three-Dimensional ; Shape memory ; shape‐memory polymers ; Smart Materials ; Spectrophotometry ; Stress, Mechanical ; supramolecular bonds ; Temperature ; Temperature dependence ; Tensile Strength ; Time dependence ; Time Factors ; time–temperature indicators ; ureidopyrimidinone</subject><ispartof>Advanced materials (Weinheim), 2021-08, Vol.33 (34), p.e2102473-n/a</ispartof><rights>2021 Wiley‐VCH GmbH</rights><rights>2021 Wiley-VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3733-4f6260aba17cdd2bd6c2ec2a8b1d081b3c8a6060099412b2b535de297c532c373</citedby><cites>FETCH-LOGICAL-c3733-4f6260aba17cdd2bd6c2ec2a8b1d081b3c8a6060099412b2b535de297c532c373</cites><orcidid>0000-0003-0222-9717</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadma.202102473$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadma.202102473$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/34278623$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Peng, Wenjun</creatorcontrib><creatorcontrib>Zhang, Guogao</creatorcontrib><creatorcontrib>Zhao, Qian</creatorcontrib><creatorcontrib>Xie, Tao</creatorcontrib><title>Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer</title><title>Advanced materials (Weinheim)</title><addtitle>Adv Mater</addtitle><description>The diverse morphing behaviors of living creatures arise from their unlimited pathways. In contrast, the equilibrium‐driven morphing pathways of common synthetic shape‐shifting materials are very limited. For a shape‐memory polymer (SMP), its recovery from the temporary shape(s) to the permanent shape typically requires external stimulation and follows a single fixed route. Herein, a covalently crosslinked SMP is designed with ample ureidopyrimidinone (UPy) supramolecular moieties in the network. The UPy units endow the SMP with strong time–temperature dependency, which is explored as a mechanism for spatio‐temporal programming of autonomous shape‐shifting pathways. In particular, the use of digitally controlled photothermal heating provides versatility in control via an off‐equilibrium mechanism. In addition, cooling/heating across its glass transition introduces a locking/unlocking mechanism for its temporal morphing. The benefits of these unique features are demonstrated by multi‐shape‐transformation, an “invisible”‐color‐based clock, a time–temperature indicator, and sequence‐programmable 4D printing. Highly designable autonomous morphing behaviors are achieved in a supramolecular shape‐memory polymer with strong time–temperature dependency. To prove the advantages of the molecular design, the benefits of the spatio‐temporal programming are demonstrated by off‐equilibrium multi‐shape‐transformation, self‐evolving sequence‐programmable 4D printing, an “invisible”‐color‐based clock, and a time–temperature indicator.</description><subject>4D printing</subject><subject>Cross-Linking Reagents - chemistry</subject><subject>Equilibrium</subject><subject>Glass transition</subject><subject>Heating</subject><subject>Hydrogen - chemistry</subject><subject>Infrared Rays</subject><subject>Kinetics</subject><subject>Locking</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Materials science</subject><subject>Materials Testing</subject><subject>Morphing</subject><subject>Phase Transition</subject><subject>Polymers</subject><subject>Polymers - chemistry</subject><subject>Printing, Three-Dimensional</subject><subject>Shape memory</subject><subject>shape‐memory polymers</subject><subject>Smart Materials</subject><subject>Spectrophotometry</subject><subject>Stress, Mechanical</subject><subject>supramolecular bonds</subject><subject>Temperature</subject><subject>Temperature dependence</subject><subject>Tensile Strength</subject><subject>Time dependence</subject><subject>Time Factors</subject><subject>time–temperature indicators</subject><subject>ureidopyrimidinone</subject><issn>0935-9648</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkLtOwzAUhi0EoqWwMiJLLCwpvuQ6RlAuUqtWKgxMkeM4NFUcp3atKhuPwDPyJLhqKRILy_Hyne_8_gG4xGiIESK3rJBsSBDBiPgRPQJ9HBDs-SgJjkEfJTTwktCPe-DMmCVCKAlReAp61CdRHBLaB2-pXatGSWUNnJbl18fnaGWrusp1ZSWcKN0uquYdzth6sWGdgaqEDM5tq5lUteC2ZhrOF6wVbnMipNIdnKm6k0Kfg5OS1UZc7N8BeH0Yvdw9eePp4_NdOvY4jSj1_DIkIWI5wxEvCpIXISeCExbnuEAxzimPmQvtoic-JjnJAxoUgiQRDyjZKgbgZudttVpZYdaZrAwXdc0a4X6VkcCB1MduDMD1H3SprG5cOkeFvruBk9hRwx3FtTJGizJrdSWZ7jKMsm3p2bb07FC6W7jaa20uRXHAf1p2QLIDNlUtun90WXo_SX_l37jhj3Q</recordid><startdate>20210801</startdate><enddate>20210801</enddate><creator>Peng, Wenjun</creator><creator>Zhang, Guogao</creator><creator>Zhao, Qian</creator><creator>Xie, Tao</creator><general>Wiley Subscription Services, Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-0222-9717</orcidid></search><sort><creationdate>20210801</creationdate><title>Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer</title><author>Peng, Wenjun ; Zhang, Guogao ; Zhao, Qian ; Xie, Tao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3733-4f6260aba17cdd2bd6c2ec2a8b1d081b3c8a6060099412b2b535de297c532c373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>4D printing</topic><topic>Cross-Linking Reagents - chemistry</topic><topic>Equilibrium</topic><topic>Glass transition</topic><topic>Heating</topic><topic>Hydrogen - chemistry</topic><topic>Infrared Rays</topic><topic>Kinetics</topic><topic>Locking</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Materials science</topic><topic>Materials Testing</topic><topic>Morphing</topic><topic>Phase Transition</topic><topic>Polymers</topic><topic>Polymers - chemistry</topic><topic>Printing, Three-Dimensional</topic><topic>Shape memory</topic><topic>shape‐memory polymers</topic><topic>Smart Materials</topic><topic>Spectrophotometry</topic><topic>Stress, Mechanical</topic><topic>supramolecular bonds</topic><topic>Temperature</topic><topic>Temperature dependence</topic><topic>Tensile Strength</topic><topic>Time dependence</topic><topic>Time Factors</topic><topic>time–temperature indicators</topic><topic>ureidopyrimidinone</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Peng, Wenjun</creatorcontrib><creatorcontrib>Zhang, Guogao</creatorcontrib><creatorcontrib>Zhao, Qian</creatorcontrib><creatorcontrib>Xie, Tao</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Advanced materials (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Peng, Wenjun</au><au>Zhang, Guogao</au><au>Zhao, Qian</au><au>Xie, Tao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer</atitle><jtitle>Advanced materials (Weinheim)</jtitle><addtitle>Adv Mater</addtitle><date>2021-08-01</date><risdate>2021</risdate><volume>33</volume><issue>34</issue><spage>e2102473</spage><epage>n/a</epage><pages>e2102473-n/a</pages><issn>0935-9648</issn><eissn>1521-4095</eissn><abstract>The diverse morphing behaviors of living creatures arise from their unlimited pathways. In contrast, the equilibrium‐driven morphing pathways of common synthetic shape‐shifting materials are very limited. For a shape‐memory polymer (SMP), its recovery from the temporary shape(s) to the permanent shape typically requires external stimulation and follows a single fixed route. Herein, a covalently crosslinked SMP is designed with ample ureidopyrimidinone (UPy) supramolecular moieties in the network. The UPy units endow the SMP with strong time–temperature dependency, which is explored as a mechanism for spatio‐temporal programming of autonomous shape‐shifting pathways. In particular, the use of digitally controlled photothermal heating provides versatility in control via an off‐equilibrium mechanism. In addition, cooling/heating across its glass transition introduces a locking/unlocking mechanism for its temporal morphing. The benefits of these unique features are demonstrated by multi‐shape‐transformation, an “invisible”‐color‐based clock, a time–temperature indicator, and sequence‐programmable 4D printing. Highly designable autonomous morphing behaviors are achieved in a supramolecular shape‐memory polymer with strong time–temperature dependency. To prove the advantages of the molecular design, the benefits of the spatio‐temporal programming are demonstrated by off‐equilibrium multi‐shape‐transformation, self‐evolving sequence‐programmable 4D printing, an “invisible”‐color‐based clock, and a time–temperature indicator.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>34278623</pmid><doi>10.1002/adma.202102473</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-0222-9717</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0935-9648
ispartof Advanced materials (Weinheim), 2021-08, Vol.33 (34), p.e2102473-n/a
issn 0935-9648
1521-4095
language eng
recordid cdi_proquest_miscellaneous_2553234132
source MEDLINE; Wiley Online Library Journals Frontfile Complete
subjects 4D printing
Cross-Linking Reagents - chemistry
Equilibrium
Glass transition
Heating
Hydrogen - chemistry
Infrared Rays
Kinetics
Locking
Magnetic Resonance Spectroscopy
Materials science
Materials Testing
Morphing
Phase Transition
Polymers
Polymers - chemistry
Printing, Three-Dimensional
Shape memory
shape‐memory polymers
Smart Materials
Spectrophotometry
Stress, Mechanical
supramolecular bonds
Temperature
Temperature dependence
Tensile Strength
Time dependence
Time Factors
time–temperature indicators
ureidopyrimidinone
title Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-18T12%3A40%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Autonomous%20Off%E2%80%90Equilibrium%20Morphing%20Pathways%20of%20a%20Supramolecular%20Shape%E2%80%90Memory%20Polymer&rft.jtitle=Advanced%20materials%20(Weinheim)&rft.au=Peng,%20Wenjun&rft.date=2021-08-01&rft.volume=33&rft.issue=34&rft.spage=e2102473&rft.epage=n/a&rft.pages=e2102473-n/a&rft.issn=0935-9648&rft.eissn=1521-4095&rft_id=info:doi/10.1002/adma.202102473&rft_dat=%3Cproquest_cross%3E2553234132%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2564009198&rft_id=info:pmid/34278623&rfr_iscdi=true