Gas Chromatography–Mass Spectrometry Analysis of High-Purity Volatile Inorganic Hydrides
The review is devoted to the capabilities of gas chromatography–mass spectrometry in the analysis of high-purity volatile hydrides of naturally occurring and isotopically enriched compositions. Problems related to experimental techniques, chromatographic separation, identification, and quantitative...
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| Veröffentlicht in: | Journal of analytical chemistry (New York, N.Y.) N.Y.), 2021-05, Vol.76 (5), p.535-545 |
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| container_title | Journal of analytical chemistry (New York, N.Y.) |
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| creator | Sozin, A. Yu Krylov, V. A. Chernova, O. Yu Sorochkina, T. G. Kotkov, A. P. Grishnova, N. D. Skosyrev, A. I. Pushkarev, G. V. |
| description | The review is devoted to the capabilities of gas chromatography–mass spectrometry in the analysis of high-purity volatile hydrides of naturally occurring and isotopically enriched compositions. Problems related to experimental techniques, chromatographic separation, identification, and quantitative determination of impurities are discussed. The application of this method has significantly expanded data coverage on the nature, number, and limiting possibilities of the determination of impurities in volatile inorganic hydrides. The identified impurities are compounds of various classes. Among them are atmospheric gases; saturated, unsaturated, and aromatic C
1
–C
9
hydrocarbons; chlorine- and fluorine-containing C
1
–C
4
hydrocarbons; homologues and alkyl derivatives of hydrides; Si
2
–Si
4
siloxanes; fluorosiloxanes; oxygen-containing hydrocarbons; sulfur-containing substances; and hydrides of other elements. Gas chromatography–mass spectrometry analysis made it possible to detect the presence of impurities in isotopically enriched silicon and germanium hydrides, which are their molecular isobars. The use of gas chromatography–mass spectrometry in the analysis of high-purity inorganic hydrides makes it possible to reach the detection limits of impurities of 10
–8
–10
–5
mol %. |
| doi_str_mv | 10.1134/S1061934821030126 |
| format | Article |
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1
–C
9
hydrocarbons; chlorine- and fluorine-containing C
1
–C
4
hydrocarbons; homologues and alkyl derivatives of hydrides; Si
2
–Si
4
siloxanes; fluorosiloxanes; oxygen-containing hydrocarbons; sulfur-containing substances; and hydrides of other elements. Gas chromatography–mass spectrometry analysis made it possible to detect the presence of impurities in isotopically enriched silicon and germanium hydrides, which are their molecular isobars. The use of gas chromatography–mass spectrometry in the analysis of high-purity inorganic hydrides makes it possible to reach the detection limits of impurities of 10
–8
–10
–5
mol %.</description><identifier>ISSN: 1061-9348</identifier><identifier>EISSN: 1608-3199</identifier><identifier>DOI: 10.1134/S1061934821030126</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Analysis ; Analytical Chemistry ; Chemistry ; Chemistry and Materials Science ; Chlorine ; Chromatography ; Fluorine ; Fluorosiloxanes ; Gas chromatography ; gas chromatography-mass spectrometry ; Gases ; Germanium ; Homology ; Hydrides ; Hydrocarbons ; Impurities ; Ions ; Isobars ; Mass spectrometry ; Purity ; quantitative analysis ; Reviews ; Scientific imaging ; silicon ; Silicon compounds ; Siloxanes ; Spectroscopy ; Sulfur compounds</subject><ispartof>Journal of analytical chemistry (New York, N.Y.), 2021-05, Vol.76 (5), p.535-545</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 1061-9348, Journal of Analytical Chemistry, 2021, Vol. 76, No. 5, pp. 535–545. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Zhurnal Analiticheskoi Khimii, 2021, Vol. 76, No. 5, pp. 387–398.</rights><rights>COPYRIGHT 2021 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c488t-b7376b247488f8f86be62a9c8ab49cf7bc001b253b648a7b74e230c089961ebf3</citedby><cites>FETCH-LOGICAL-c488t-b7376b247488f8f86be62a9c8ab49cf7bc001b253b648a7b74e230c089961ebf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1061934821030126$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1061934821030126$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sozin, A. Yu</creatorcontrib><creatorcontrib>Krylov, V. A.</creatorcontrib><creatorcontrib>Chernova, O. Yu</creatorcontrib><creatorcontrib>Sorochkina, T. G.</creatorcontrib><creatorcontrib>Kotkov, A. P.</creatorcontrib><creatorcontrib>Grishnova, N. D.</creatorcontrib><creatorcontrib>Skosyrev, A. I.</creatorcontrib><creatorcontrib>Pushkarev, G. V.</creatorcontrib><title>Gas Chromatography–Mass Spectrometry Analysis of High-Purity Volatile Inorganic Hydrides</title><title>Journal of analytical chemistry (New York, N.Y.)</title><addtitle>J Anal Chem</addtitle><description>The review is devoted to the capabilities of gas chromatography–mass spectrometry in the analysis of high-purity volatile hydrides of naturally occurring and isotopically enriched compositions. Problems related to experimental techniques, chromatographic separation, identification, and quantitative determination of impurities are discussed. The application of this method has significantly expanded data coverage on the nature, number, and limiting possibilities of the determination of impurities in volatile inorganic hydrides. The identified impurities are compounds of various classes. Among them are atmospheric gases; saturated, unsaturated, and aromatic C
1
–C
9
hydrocarbons; chlorine- and fluorine-containing C
1
–C
4
hydrocarbons; homologues and alkyl derivatives of hydrides; Si
2
–Si
4
siloxanes; fluorosiloxanes; oxygen-containing hydrocarbons; sulfur-containing substances; and hydrides of other elements. Gas chromatography–mass spectrometry analysis made it possible to detect the presence of impurities in isotopically enriched silicon and germanium hydrides, which are their molecular isobars. The use of gas chromatography–mass spectrometry in the analysis of high-purity inorganic hydrides makes it possible to reach the detection limits of impurities of 10
–8
–10
–5
mol %.</description><subject>Analysis</subject><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chlorine</subject><subject>Chromatography</subject><subject>Fluorine</subject><subject>Fluorosiloxanes</subject><subject>Gas chromatography</subject><subject>gas chromatography-mass spectrometry</subject><subject>Gases</subject><subject>Germanium</subject><subject>Homology</subject><subject>Hydrides</subject><subject>Hydrocarbons</subject><subject>Impurities</subject><subject>Ions</subject><subject>Isobars</subject><subject>Mass spectrometry</subject><subject>Purity</subject><subject>quantitative analysis</subject><subject>Reviews</subject><subject>Scientific imaging</subject><subject>silicon</subject><subject>Silicon compounds</subject><subject>Siloxanes</subject><subject>Spectroscopy</subject><subject>Sulfur compounds</subject><issn>1061-9348</issn><issn>1608-3199</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1ksFqGzEQhpfSQNO0D5DbQi_tYVNJq9VKR2Pa2JCSEqc55CIkeXatsF65kha6t7xD3jBPEhkHglOHOcwM__cPzDBZdorRGcYl_b7AiGFRUk4wKhEm7F12jBniRYmFeJ_qJBdb_UP2MYQ7hJDgmB1nt-cq5NOVd2sVXevVZjU-3j_8UiHkiw2YmASIfswnverGYEPumnxm21Xxe_A2jvmN61S0HeTz3vlW9dbks3Hp7RLCp-yoUV2Az8_5JPvz88f1dFZcXJ7Pp5OLwlDOY6Hrsmaa0Dp1TQqmgRElDFeaCtPU2iCENalKzShXta4pkBIZxIVgGHRTnmRfd3M33v0dIES5tsFA16ke3BAkqSosKpE2TuiXV-idG3xabUsRxmlV0fqFalUH0vaNi16Z7VA5YQxzxCqEElUcoFrowavO9dCkq-zzZwf4FEtYW3PQ8G3PkJgI_2KrhhDkfHG1z-Ida7wLwUMjN96ulR8lRnL7IPK_B0kesvOExPYt-JdjvG16AqWwufw</recordid><startdate>20210501</startdate><enddate>20210501</enddate><creator>Sozin, A. Yu</creator><creator>Krylov, V. A.</creator><creator>Chernova, O. Yu</creator><creator>Sorochkina, T. G.</creator><creator>Kotkov, A. P.</creator><creator>Grishnova, N. D.</creator><creator>Skosyrev, A. I.</creator><creator>Pushkarev, G. V.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20210501</creationdate><title>Gas Chromatography–Mass Spectrometry Analysis of High-Purity Volatile Inorganic Hydrides</title><author>Sozin, A. Yu ; Krylov, V. A. ; Chernova, O. Yu ; Sorochkina, T. G. ; Kotkov, A. P. ; Grishnova, N. D. ; Skosyrev, A. I. ; Pushkarev, G. 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Yu</creatorcontrib><creatorcontrib>Krylov, V. A.</creatorcontrib><creatorcontrib>Chernova, O. Yu</creatorcontrib><creatorcontrib>Sorochkina, T. G.</creatorcontrib><creatorcontrib>Kotkov, A. P.</creatorcontrib><creatorcontrib>Grishnova, N. D.</creatorcontrib><creatorcontrib>Skosyrev, A. I.</creatorcontrib><creatorcontrib>Pushkarev, G. V.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sozin, A. Yu</au><au>Krylov, V. A.</au><au>Chernova, O. Yu</au><au>Sorochkina, T. G.</au><au>Kotkov, A. P.</au><au>Grishnova, N. D.</au><au>Skosyrev, A. I.</au><au>Pushkarev, G. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Gas Chromatography–Mass Spectrometry Analysis of High-Purity Volatile Inorganic Hydrides</atitle><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle><stitle>J Anal Chem</stitle><date>2021-05-01</date><risdate>2021</risdate><volume>76</volume><issue>5</issue><spage>535</spage><epage>545</epage><pages>535-545</pages><issn>1061-9348</issn><eissn>1608-3199</eissn><abstract>The review is devoted to the capabilities of gas chromatography–mass spectrometry in the analysis of high-purity volatile hydrides of naturally occurring and isotopically enriched compositions. Problems related to experimental techniques, chromatographic separation, identification, and quantitative determination of impurities are discussed. The application of this method has significantly expanded data coverage on the nature, number, and limiting possibilities of the determination of impurities in volatile inorganic hydrides. The identified impurities are compounds of various classes. Among them are atmospheric gases; saturated, unsaturated, and aromatic C
1
–C
9
hydrocarbons; chlorine- and fluorine-containing C
1
–C
4
hydrocarbons; homologues and alkyl derivatives of hydrides; Si
2
–Si
4
siloxanes; fluorosiloxanes; oxygen-containing hydrocarbons; sulfur-containing substances; and hydrides of other elements. Gas chromatography–mass spectrometry analysis made it possible to detect the presence of impurities in isotopically enriched silicon and germanium hydrides, which are their molecular isobars. The use of gas chromatography–mass spectrometry in the analysis of high-purity inorganic hydrides makes it possible to reach the detection limits of impurities of 10
–8
–10
–5
mol %.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1061934821030126</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1061-9348 |
| ispartof | Journal of analytical chemistry (New York, N.Y.), 2021-05, Vol.76 (5), p.535-545 |
| issn | 1061-9348 1608-3199 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Analysis Analytical Chemistry Chemistry Chemistry and Materials Science Chlorine Chromatography Fluorine Fluorosiloxanes Gas chromatography gas chromatography-mass spectrometry Gases Germanium Homology Hydrides Hydrocarbons Impurities Ions Isobars Mass spectrometry Purity quantitative analysis Reviews Scientific imaging silicon Silicon compounds Siloxanes Spectroscopy Sulfur compounds |
| title | Gas Chromatography–Mass Spectrometry Analysis of High-Purity Volatile Inorganic Hydrides |
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