Remarkably enhanced ion-exchange capacity of H2O2-intercalated layered titanate
H2O2-intercalated layered titanate H1.07Ti1.73O4 (H2O2-HTO) exhibits a dramatically enhanced ion-exchange capacity and remarkably improved reaction rate with various divalent cations. The intercalation can increase the negative charge density of the TiO6 octahedral layer and the number of ion-exchan...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-08, Vol.57 (60), p.7394-7397 |
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creator | Wang, Xing Wei, Wei Hu, Jiaqiao Sen, Li Wang, Yong Yin, Lixiong Kong, Xingang Feng, Qi |
description | H2O2-intercalated layered titanate H1.07Ti1.73O4 (H2O2-HTO) exhibits a dramatically enhanced ion-exchange capacity and remarkably improved reaction rate with various divalent cations. The intercalation can increase the negative charge density of the TiO6 octahedral layer and the number of ion-exchangeable H+ by forming a Ti(iv)–O–O–H bond that is the driving force to change the ion exchange performance. |
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The intercalation can increase the negative charge density of the TiO6 octahedral layer and the number of ion-exchangeable H+ by forming a Ti(iv)–O–O–H bond that is the driving force to change the ion exchange performance.</description><subject>Charge density</subject><subject>Divalent cations</subject><subject>Hydrogen bonds</subject><subject>Hydrogen peroxide</subject><subject>Ion exchange</subject><subject>Titanium</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdj09Lw0AQxRdRsFYvfoKAFy-ru7N_e5SirVAISA_eymQz0dR0U5Mt2G_vip58lzdv-DHMY-xaijsp1Oy-liEIqbyrT9hEKqu50f719Gc2M-6UNufsYhy3IksaP2HlC-1w-MCqOxYU3zEGqou2j5y-Qk5vVATcY2jTseibYgkl8DYmGgJ2mDLa4ZGG7KlNGPPmkp012I109edTtn56XM-XfFUunucPK74FD4lj40iF4DxU0GhyujKCEENA5WvbaKwa4xUguAp0ba2QwYECJ4DAyVpN2e3v2f3Qfx5oTJtdOwbqOozUH8YN5NoWZl7ajN78Q7f9YYj5uUwZo6wU0qlvOLRd4Q</recordid><startdate>20210804</startdate><enddate>20210804</enddate><creator>Wang, Xing</creator><creator>Wei, Wei</creator><creator>Hu, Jiaqiao</creator><creator>Sen, Li</creator><creator>Wang, Yong</creator><creator>Yin, Lixiong</creator><creator>Kong, Xingang</creator><creator>Feng, Qi</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20210804</creationdate><title>Remarkably enhanced ion-exchange capacity of H2O2-intercalated layered titanate</title><author>Wang, Xing ; Wei, Wei ; Hu, Jiaqiao ; Sen, Li ; Wang, Yong ; Yin, Lixiong ; Kong, Xingang ; Feng, Qi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j282t-af7e3cc782b2f4e74b50eaacca38d6f4abf5832a27b24d6601c7232702e271d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Charge density</topic><topic>Divalent cations</topic><topic>Hydrogen bonds</topic><topic>Hydrogen peroxide</topic><topic>Ion exchange</topic><topic>Titanium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Xing</creatorcontrib><creatorcontrib>Wei, Wei</creatorcontrib><creatorcontrib>Hu, Jiaqiao</creatorcontrib><creatorcontrib>Sen, Li</creatorcontrib><creatorcontrib>Wang, Yong</creatorcontrib><creatorcontrib>Yin, Lixiong</creatorcontrib><creatorcontrib>Kong, Xingang</creatorcontrib><creatorcontrib>Feng, Qi</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Xing</au><au>Wei, Wei</au><au>Hu, Jiaqiao</au><au>Sen, Li</au><au>Wang, Yong</au><au>Yin, Lixiong</au><au>Kong, Xingang</au><au>Feng, Qi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Remarkably enhanced ion-exchange capacity of H2O2-intercalated layered titanate</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2021-08-04</date><risdate>2021</risdate><volume>57</volume><issue>60</issue><spage>7394</spage><epage>7397</epage><pages>7394-7397</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>H2O2-intercalated layered titanate H1.07Ti1.73O4 (H2O2-HTO) exhibits a dramatically enhanced ion-exchange capacity and remarkably improved reaction rate with various divalent cations. The intercalation can increase the negative charge density of the TiO6 octahedral layer and the number of ion-exchangeable H+ by forming a Ti(iv)–O–O–H bond that is the driving force to change the ion exchange performance.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1cc01387d</doi><tpages>4</tpages></addata></record> |
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subjects | Charge density Divalent cations Hydrogen bonds Hydrogen peroxide Ion exchange Titanium |
title | Remarkably enhanced ion-exchange capacity of H2O2-intercalated layered titanate |
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