Structural and optical study of silicate glasses for nonlinear optical devices
Nonlinear optical glasses with fast response times and very low absorption coefficients are promising materials for use in ultra-fast (picosecond) all-optical switches. We have recently reported a relatively high third-order optical nonlinearity in equimolar TiO 2· B 2 O 3· Na 2 O· SiO 2 glass. The...
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| Veröffentlicht in: | Journal of non-crystalline solids 1989, Vol.107 (2), p.244-250 |
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| container_end_page | 250 |
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| container_title | Journal of non-crystalline solids |
| container_volume | 107 |
| creator | Vogel, E.M. Kosinski, S.G. Krol, D.M. Jackel, J.L. Friberg, S.R. Oliver, M.K. Powers, J.D. |
| description | Nonlinear optical glasses with fast response times and very low absorption coefficients are promising materials for use in ultra-fast (picosecond) all-optical switches. We have recently reported a relatively high third-order optical nonlinearity in equimolar
TiO
2·
B
2
O
3·
Na
2
O·
SiO
2 glass. The nonlinear index coefficient
n
2 for this glass composition was found to be 4 × 10
−19 m
2/W. In order to determine the relationship of the various physical properties to the structure and/or composition in these glasses, we have synthesized series of glasses in the four-component
TiO
2·
Nb
2
O
5·
Na
2
O·
SiO
2 system. Their structures have been studied by Raman spectroscopy, and their linear refractive indices and nonlinear index coefficients were measured. The data show that the linear refractive index is mainly determined by the total concentration of
Ti +
Nb, whereas the nonlinear index coefficient is much larger for Ti than for Nb doping. The combined presence of Ti and Nb extends the glass forming region in this system. |
| doi_str_mv | 10.1016/0022-3093(89)90469-9 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_25468748</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>0022309389904699</els_id><sourcerecordid>25468748</sourcerecordid><originalsourceid>FETCH-LOGICAL-c430t-67655ba5abd5f929418c505fb56b6cbad597cdd813bb051fe504fd0f62506f763</originalsourceid><addsrcrecordid>eNp9kEtLAzEQgIMoWKv_wMMeRPSwmuwm2eQiSPEFRQ_qOWTzkMh2UzO7hf57U1t6dC4zDN_MMB9C5wTfEEz4LcZVVdZY1ldCXktMuSzlAZoQ0dQlFaQ6RJM9coxOAL5xjqYWE_T6PqTRDGPSXaF7W8TlEEyuYRjtuoi-gNDlxuCKr04DOCh8TEUf-y70Tqc9b90qGAen6MjrDtzZLk_R5-PDx-y5nL89vczu56WhNR5K3nDGWs10a5mXlaREGIaZbxlvuWm1ZbIx1gpSty1mxDuGqbfY84ph7hteT9Hldu8yxZ_RwaAWAYzrOt27OIKqGOWioSKDdAuaFAGS82qZwkKntSJYbeSpjRm1MaOEVH_ylMxjF7v9GvJ7PuneBNjPNlXWJ6uM3W0xl39dBZcUmOB642xIzgzKxvD_nV_uCIOB</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>25468748</pqid></control><display><type>article</type><title>Structural and optical study of silicate glasses for nonlinear optical devices</title><source>Elsevier ScienceDirect Journals Complete - AutoHoldings</source><creator>Vogel, E.M. ; Kosinski, S.G. ; Krol, D.M. ; Jackel, J.L. ; Friberg, S.R. ; Oliver, M.K. ; Powers, J.D.</creator><creatorcontrib>Vogel, E.M. ; Kosinski, S.G. ; Krol, D.M. ; Jackel, J.L. ; Friberg, S.R. ; Oliver, M.K. ; Powers, J.D.</creatorcontrib><description>Nonlinear optical glasses with fast response times and very low absorption coefficients are promising materials for use in ultra-fast (picosecond) all-optical switches. We have recently reported a relatively high third-order optical nonlinearity in equimolar
TiO
2·
B
2
O
3·
Na
2
O·
SiO
2 glass. The nonlinear index coefficient
n
2 for this glass composition was found to be 4 × 10
−19 m
2/W. In order to determine the relationship of the various physical properties to the structure and/or composition in these glasses, we have synthesized series of glasses in the four-component
TiO
2·
Nb
2
O
5·
Na
2
O·
SiO
2 system. Their structures have been studied by Raman spectroscopy, and their linear refractive indices and nonlinear index coefficients were measured. The data show that the linear refractive index is mainly determined by the total concentration of
Ti +
Nb, whereas the nonlinear index coefficient is much larger for Ti than for Nb doping. The combined presence of Ti and Nb extends the glass forming region in this system.</description><identifier>ISSN: 0022-3093</identifier><identifier>EISSN: 1873-4812</identifier><identifier>DOI: 10.1016/0022-3093(89)90469-9</identifier><identifier>CODEN: JNCSBJ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Building materials. Ceramics. Glasses ; Chemical industry and chemicals ; Exact sciences and technology ; Glasses ; Structure, analysis, properties</subject><ispartof>Journal of non-crystalline solids, 1989, Vol.107 (2), p.244-250</ispartof><rights>1989</rights><rights>1989 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c430t-67655ba5abd5f929418c505fb56b6cbad597cdd813bb051fe504fd0f62506f763</citedby><cites>FETCH-LOGICAL-c430t-67655ba5abd5f929418c505fb56b6cbad597cdd813bb051fe504fd0f62506f763</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0022-3093(89)90469-9$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3549,4023,27922,27923,27924,45994</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7200792$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Vogel, E.M.</creatorcontrib><creatorcontrib>Kosinski, S.G.</creatorcontrib><creatorcontrib>Krol, D.M.</creatorcontrib><creatorcontrib>Jackel, J.L.</creatorcontrib><creatorcontrib>Friberg, S.R.</creatorcontrib><creatorcontrib>Oliver, M.K.</creatorcontrib><creatorcontrib>Powers, J.D.</creatorcontrib><title>Structural and optical study of silicate glasses for nonlinear optical devices</title><title>Journal of non-crystalline solids</title><description>Nonlinear optical glasses with fast response times and very low absorption coefficients are promising materials for use in ultra-fast (picosecond) all-optical switches. We have recently reported a relatively high third-order optical nonlinearity in equimolar
TiO
2·
B
2
O
3·
Na
2
O·
SiO
2 glass. The nonlinear index coefficient
n
2 for this glass composition was found to be 4 × 10
−19 m
2/W. In order to determine the relationship of the various physical properties to the structure and/or composition in these glasses, we have synthesized series of glasses in the four-component
TiO
2·
Nb
2
O
5·
Na
2
O·
SiO
2 system. Their structures have been studied by Raman spectroscopy, and their linear refractive indices and nonlinear index coefficients were measured. The data show that the linear refractive index is mainly determined by the total concentration of
Ti +
Nb, whereas the nonlinear index coefficient is much larger for Ti than for Nb doping. The combined presence of Ti and Nb extends the glass forming region in this system.</description><subject>Applied sciences</subject><subject>Building materials. Ceramics. Glasses</subject><subject>Chemical industry and chemicals</subject><subject>Exact sciences and technology</subject><subject>Glasses</subject><subject>Structure, analysis, properties</subject><issn>0022-3093</issn><issn>1873-4812</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEQgIMoWKv_wMMeRPSwmuwm2eQiSPEFRQ_qOWTzkMh2UzO7hf57U1t6dC4zDN_MMB9C5wTfEEz4LcZVVdZY1ldCXktMuSzlAZoQ0dQlFaQ6RJM9coxOAL5xjqYWE_T6PqTRDGPSXaF7W8TlEEyuYRjtuoi-gNDlxuCKr04DOCh8TEUf-y70Tqc9b90qGAen6MjrDtzZLk_R5-PDx-y5nL89vczu56WhNR5K3nDGWs10a5mXlaREGIaZbxlvuWm1ZbIx1gpSty1mxDuGqbfY84ph7hteT9Hldu8yxZ_RwaAWAYzrOt27OIKqGOWioSKDdAuaFAGS82qZwkKntSJYbeSpjRm1MaOEVH_ylMxjF7v9GvJ7PuneBNjPNlXWJ6uM3W0xl39dBZcUmOB642xIzgzKxvD_nV_uCIOB</recordid><startdate>1989</startdate><enddate>1989</enddate><creator>Vogel, E.M.</creator><creator>Kosinski, S.G.</creator><creator>Krol, D.M.</creator><creator>Jackel, J.L.</creator><creator>Friberg, S.R.</creator><creator>Oliver, M.K.</creator><creator>Powers, J.D.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>1989</creationdate><title>Structural and optical study of silicate glasses for nonlinear optical devices</title><author>Vogel, E.M. ; Kosinski, S.G. ; Krol, D.M. ; Jackel, J.L. ; Friberg, S.R. ; Oliver, M.K. ; Powers, J.D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c430t-67655ba5abd5f929418c505fb56b6cbad597cdd813bb051fe504fd0f62506f763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>Applied sciences</topic><topic>Building materials. Ceramics. Glasses</topic><topic>Chemical industry and chemicals</topic><topic>Exact sciences and technology</topic><topic>Glasses</topic><topic>Structure, analysis, properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vogel, E.M.</creatorcontrib><creatorcontrib>Kosinski, S.G.</creatorcontrib><creatorcontrib>Krol, D.M.</creatorcontrib><creatorcontrib>Jackel, J.L.</creatorcontrib><creatorcontrib>Friberg, S.R.</creatorcontrib><creatorcontrib>Oliver, M.K.</creatorcontrib><creatorcontrib>Powers, J.D.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of non-crystalline solids</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vogel, E.M.</au><au>Kosinski, S.G.</au><au>Krol, D.M.</au><au>Jackel, J.L.</au><au>Friberg, S.R.</au><au>Oliver, M.K.</au><au>Powers, J.D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural and optical study of silicate glasses for nonlinear optical devices</atitle><jtitle>Journal of non-crystalline solids</jtitle><date>1989</date><risdate>1989</risdate><volume>107</volume><issue>2</issue><spage>244</spage><epage>250</epage><pages>244-250</pages><issn>0022-3093</issn><eissn>1873-4812</eissn><coden>JNCSBJ</coden><abstract>Nonlinear optical glasses with fast response times and very low absorption coefficients are promising materials for use in ultra-fast (picosecond) all-optical switches. We have recently reported a relatively high third-order optical nonlinearity in equimolar
TiO
2·
B
2
O
3·
Na
2
O·
SiO
2 glass. The nonlinear index coefficient
n
2 for this glass composition was found to be 4 × 10
−19 m
2/W. In order to determine the relationship of the various physical properties to the structure and/or composition in these glasses, we have synthesized series of glasses in the four-component
TiO
2·
Nb
2
O
5·
Na
2
O·
SiO
2 system. Their structures have been studied by Raman spectroscopy, and their linear refractive indices and nonlinear index coefficients were measured. The data show that the linear refractive index is mainly determined by the total concentration of
Ti +
Nb, whereas the nonlinear index coefficient is much larger for Ti than for Nb doping. The combined presence of Ti and Nb extends the glass forming region in this system.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/0022-3093(89)90469-9</doi><tpages>7</tpages></addata></record> |
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| ispartof | Journal of non-crystalline solids, 1989, Vol.107 (2), p.244-250 |
| issn | 0022-3093 1873-4812 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_25468748 |
| source | Elsevier ScienceDirect Journals Complete - AutoHoldings |
| subjects | Applied sciences Building materials. Ceramics. Glasses Chemical industry and chemicals Exact sciences and technology Glasses Structure, analysis, properties |
| title | Structural and optical study of silicate glasses for nonlinear optical devices |
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