Switching between mono and doubly reduced odd alternant hydrocarbon: designing a redox catalyst

Since the early Hückel molecular orbital (HMO) calculations in 1950, it has been well known that the odd alternant hydrocarbon (OAH), the phenalenyl (PLY) system, can exist in three redox states: closed shell cation (12π e − ), mono-reduced open shell neutral radical (13π e − ) and doubly reduced cl...

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Veröffentlicht in:	Chemical science (Cambridge) 2021-03, Vol.12 (8), p.339-349
Hauptverfasser:	Ahmed, Jasimuddin, Datta, Paramita, Das, Arpan, Jomy, Stephy, Mandal, Swadhin K
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemistry Crystallography Disproportionation Hydrocarbons Molecular orbitals Switching Transition metals
Online-Zugang:	Volltext
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