QM calculations predict the energetics and infrared spectra of transient glutamine isomers in LOV photoreceptors

Photosensory receptors containing the flavin-binding light-oxygen-voltage (LOV) domain are modular proteins that fulfil a variety of biological functions ranging from gene expression to phototropism. The LOV photocycle is initiated by blue-light and involves a cascade of intermediate species, includ...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2021-06, Vol.23 (25), p.13934-1395
Hauptverfasser:	Andrikopoulos, Prokopis C, Chaudhari, Aditya S, Liu, Yingliang, Konold, Patrick E, Kennis, John T. M, Schneider, Bohdan, Fuertes, Gustavo
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic energy levels Binding Carbonyls Chains Chemistry Chromophores Covalent bonds Gene expression Glutamine Hydrogen bonds Infrared spectra Isomers Photochemistry Photoreceptors Phototropism Polypeptides Proteins Residues Signal transduction Spectrum analysis Tautomers
Online-Zugang:	Volltext
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