Acylhydrazone Subunits as a Proton Cargo Delivery System in 7‐Hydroxyquinoline

The reimagined concept of long‐range tautomeric proton transfer using crane subunits is shown by designing and synthesising two new acylhydrazones containing a 7‐hydroxyquinoline (7‐OHQ) platform. The acylhydrazone subunits attached to the 7‐OHQ at the 8th position act as crane arms for delivering p...

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Veröffentlicht in:	Chemistry : a European journal 2021-08, Vol.27 (45), p.11559-11566
Hauptverfasser:	Nakashima, Kosuke, Petek, Anton, Hori, Yutaro, Georgiev, Anton, Hirashima, Shin‐ichi, Matsushima, Yasuyuki, Yordanov, Dancho, Miura, Tsuyoshi, Antonov, Liudmil
Format:	Artikel
Sprache:	eng
Schlagworte:	acylhydrazones Cargo transportation Chemistry Cranes Crystal structure density functional calculations Hydrogen bonding Hydrogen bonds Hydroxyquinoline Irradiation Isomerization Magnetic resonance spectroscopy molecular switches Nitrogen NMR NMR spectroscopy Nuclear magnetic resonance photochemistry proton transfer Protons Quinoline Shafts (machine elements) Structural analysis Thermal stability Wavelengths
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