Benchtop-Stable Hypervalent Bromine(III) Compounds: Versatile Strategy and Platform for Air- and Moisture-Stable λ3‑Bromanes

We present the first synthesis of air/moisture-stable λ3-bromanes (9 and 10) by using a cyclic 1,2-benzbromoxol-3-one (BBX) strategy. X-ray crystallography and NMR and IR spectroscopy of N-triflylimino-λ3-bromane (12) revealed that the bromine­(III) center is effectively stabilized by intramolecular...

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Veröffentlicht in:	Journal of the American Chemical Society 2021-06, Vol.143 (25), p.9327-9331
Hauptverfasser:	Miyamoto, Kazunori, Saito, Motomichi, Tsuji, Shunsuke, Takagi, Taisei, Shiro, Motoo, Uchiyama, Masanobu, Ochiai, Masahito
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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